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Dive into the research topics where R. Sakthivel is active.

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Featured researches published by R. Sakthivel.


Journal of Photochemistry and Photobiology B-biology | 2014

Water disinfection through photoactive modified titania.

Diptipriya Sethi; Ajoy Pal; R. Sakthivel; Sony Pandey; Tapan Dash; Trupti Das; Rohit Kumar

TiO(2), N-TiO(2) and S-TiO(2) samples have been prepared by various chemical methods. These samples were characterized by X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), Laser Raman spectrometer, UV-Visible spectrophotometer, field emission scanning electron microscope (FE-SEM) and transmission electron microscope (TEM). X-ray powder diffraction study reveals that all three samples are single anatase phase of titania and the crystallinity of titania decreases with sulphur doping whereas nitrogen doping does not affect it. UV-Visible (diffuse) reflectance spectra shows that doping of titania with nitrogen and sulphur shift the absorption edge of titania from ultraviolet to visible region. XPS study confirms that both nitrogen and sulphur are well doped in the titania lattice. It is observed that nitrogen occupies at both substitutional and interstitial position in the lattice of titania. FE-SEM and TEM studies demonstrate that the particles are below 50nm range. It is found that S and N doping of titania increased its water disinfection property in the order TiO(2)


Mineral Processing and Extractive Metallurgy Review | 2010

Mineralogy, Microstructure, and Chemical Composition of Goethites in Some Iron Ore Deposits of Orissa, India

S. K. Das; B. Das; R. Sakthivel; B.K. Mishra

The Joda–Barbil region of the Jamda–Koira valley is one of the most important sources of iron ores in India. The mineralogy, texture, and chemical composition of iron ore of the region have been analyzed to understand the presence of different types of goethite and their compositional variation with respect to Fe, Al2O3, SiO2, and P that are essential for upgrading the ores for iron and steel making. The iron ore samples have been investigated by optical microscopy, EPMA, XRD, and TG-DTA. The optical microscopy studies have indicated three dominant textural types of goethite, such as (a) colloform-banded vitreous, (b) massive vitreous, and (c) earthy or ochreous goethite. The vitreous goethite is hard and crystalline, whereas ochreous goethite is clayey and consists of ultrafine crystallites often intimately admixed with kaolinite and gibbsite. EPMA studies indicated that (a) ochreous and colloform-banded goethite contain more alumina compared to massive vitreous goethite and (b) colloform-banded goethite has higher phosphorus contents (P2O5: 0.90–2.25%).


Materials and Manufacturing Processes | 2011

Synthesis of β-SiC Powder from Bamboo Leaf in a DC Extended Thermal Plasma Reactor

Sankar Mohapatra; R. Sakthivel; Gs Roy; Shikha Varma; S. K. Singh; D.K. Mishra

Fine silicon carbide powder was synthesized from bamboo leaf in a DC thermal plasma reactor through a single step process. With an applying current of 300 amp and 50 V voltages, the optimum duration of conversion of silica rich bamboo leaf to silicon carbide is 20 minutes. X-ray diffraction (XRD) results reveal that the final product is identified as β-SiC having lattice parameter a = 4.295 Å, which is in close agreement with the reported value of 4.347 Å. The scanning electron microscope (SEM) micrograph clearly shows the formation of cubical particles of β-SiC. The micro-Raman and X-ray photoelectron spectroscopy (XPS) analysis also confirm the formation of β-SiC phase.


Journal of Photochemistry and Photobiology B-biology | 2017

ZnO/TiO2 composites for photocatalytic inactivation of Escherichia coli

Diptipriya Sethi; R. Sakthivel

ZnO/TiO2 composite was synthesized from zinc nitrate and anatase TiO2 by using the incipient wet impregnation method followed by calcination at 350°C for 3h. These samples were characterized through several characterization techniques. XRD peaks confirms the presence of single anatase phase of titania in the 3 and 6wt% ZnO/TiO2 composite, whereas in all other composites both anatase titania and zinc oxide phases were found. UV-visible (diffuse) reflectance spectra show titania and ZnO absorbs in the ultraviolet (UV) region whereas ZnO/TiO2 absorbs both UV and visible light. The shift in absorbance facilitates ZnO/TiO2 composites to exhibit photocatalytic activity under UV-visible light irradiation. FE-SEM and TEM analysis reveals that the particle size of ZnO is around 0.2μm and its size significantly reduced to 25nm when it is deposited on TiO2 support. The E. coli inactivation study shows that ZnO/TiO2 composites exhibit high inactivation compared to ZnO and titania under UV alone and the combination of both UV-visible. With the increasing loading concentration of ZnO, the photocatalytic inactivation potential of ZnO/TiO2 composites also increases. The E. coli inactivation of ZnO/TiO2 is explained based on the photocatalytically generated ROS, ZnO dissolution and charge carrier separation due to hybrid structures.


Transactions of Nonferrous Metals Society of China | 2013

Synthesis and characterization of fibrous nickel hydroxide obtained from spent nickel catalyst

Pinak Patnaik; Avijit Biswal; B.C. Tripathy; Sangitarani Pradhan; Barsha Dash; R. Sakthivel; T. Subbaiah

The recovery of nickel from spent nickel catalyst for the preparation of nickel hydroxide was studied. Nickel was extracted from the spent catalyst by acid leaching with 1 mol/L sulfuric acid at 90 C. Purified nickel solution was used in the preparation of nickel hydroxide. Three different methods, namely urea hydrolysis, conventional, and hydrothermal methods, of precipitation using NaOH were employed to get various nickel hydroxides samples named as Ni(OH) 2-U, Ni(OH)2-C, and Ni(OH)2-H, respectively. Hydrothermal treatment induced better crystallinity in the Ni(OH)2 compared with conventional method. Both Ni(OH)2-C and Ni(OH) 2-H samples have mixed phases of β-Ni(OH)2 and α*-Ni(OH)2·0.75H2O phases, whereas Ni(OH)2-U has only α*-Ni(OH) 2·0.75H2O. TEM image of Ni(OH)2-U sample shows rod-like Ni(OH)2 structures. Among all, Ni(OH)2-U shows the best electrochemical activity.


Powder Technology | 2010

Synthesis of magnetite powder from iron ore tailings

R. Sakthivel; N. Vasumathi; Dojalisa Sahu; B.K. Mishra


Journal of Alloys and Compounds | 2015

Synthesis of magnetite nanoparticles from mineral waste

Rohit Kumar; R. Sakthivel; Reshma Behura; B.K. Mishra; D. Das


Applied Surface Science | 2009

Gold supported iron oxide-hydroxide derived from iron ore tailings for CO oxidation

R. Sakthivel; B. Das; Biswarup Satpati; B.K. Mishra


Powder Technology | 2013

Gas dispersion characteristics of flotation reagents

V. Ravichandran; Chinthapudi Eswaraiah; R. Sakthivel; S.K. Biswal; P. Manisankar


Advanced Science Letters | 2011

Structural and Magnetic Properties of Zn 1−x Cu x O( 0≤ x ≤ 0 1) Systems

Jyoshnarani Mohapatra; D.K. Mishra; Vivek Berma; Susanta Kumar Kamilla; R. Sakthivel; Birendra Kumar Mohapatra; Saroj K. Singh

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B.K. Mishra

Council of Scientific and Industrial Research

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B. Das

Council of Scientific and Industrial Research

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Chinthapudi Eswaraiah

Council of Scientific and Industrial Research

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D.K. Mishra

Council of Scientific and Industrial Research

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Debadhyan Behera

Council of Scientific and Industrial Research

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Diptipriya Sethi

Academy of Scientific and Innovative Research

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K. Jayasankar

Council of Scientific and Industrial Research

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Rohit Kumar

Council of Scientific and Industrial Research

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Tapan Dash

Council of Scientific and Industrial Research

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Ajoy Pal

Council of Scientific and Industrial Research

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