Ramin Yazdani

Performance of North American Bioreactor Landfills. II: Chemical and Biological Characteristics

The objective of this research was to examine the performance of five North American bioreactor landfills. This paper represents the second of a two-part series and addresses biological and chemical aspects of bioreactor performance including gas production and management, and leachate chemistry. The data support accelerated methane generation at several landfills ( k=0.08–0.21 1/year ) relative to the AP-42 default decay rate ( k=0.04 1/year ) . While the data indicate that gas collection increases at bioreactor landfills, a general relationship between decay rate and moisture added or wet weight water content could not be identified. There was no indication that gas collection increases appreciably when the water content reaches 40%. Most of the leachates at the landfills in this study were commingled from cells operating as a bioreactor and conventionally. Nevertheless, trends in pH and BOD:COD in the bioreactor leachates were consistent with the impacts of enhanced biological activity. Ammonia concent...

Quantifying Factors Limiting Aerobic Degradation During Aerobic Bioreactor Landfilling

A bioreactor landfill cell at Yolo County, California was operated aerobically for six months to quantify the extent of aerobic degradation and mechanisms limiting aerobic activity during air injection and liquid addition. The portion of the solid waste degraded anaerobically was estimated and tracked through time. From an analysis of in situ aerobic respiration and gas tracer data, it was found that a large fraction of the gas-filled pore space was in immobile zones where it was difficult to maintain aerobic conditions, even at relatively moderate landfill cell-average moisture contents of 33-36%. Even with the intentional injection of air, anaerobic activity was never less than 13%, and sometimes exceeded 65%. Analyses of gas tracer and respiration data were used to quantify rates of respiration and rates of mass transfer to immobile gas zones. The similarity of these rates indicated that waste degradation was influenced significantly by rates of oxygen transfer to immobile gas zones, which comprised 32-92% of the gas-filled pore space. Gas tracer tests might be useful for estimating the size of the mobile/immobile gas zones, rates of mass transfer between these regions, and the difficulty of degrading waste aerobically in particular waste bodies.

Performance evaluation of an anaerobic/aerobic landfill-based digester using yard waste for energy and compost production.

The objective of this study was to evaluate a new alternative for yard waste management by constructing, operating and monitoring a landfill-based two-stage batch digester (anaerobic/aerobic) with the recovery of energy and compost. The system was initially operated under anaerobic conditions for 366 days, after which the yard waste was aerated for an additional 191 days. Off gas generated from the aerobic stage was treated by biofilters. Net energy recovery was 84.3MWh, or 46kWh per million metric tons of wet waste (as received), and the biochemical methane potential of the treated waste decreased by 83% during the two-stage operation. The average removal efficiencies of volatile organic compounds and non-methane organic compounds in the biofilters were 96-99% and 68-99%, respectively.

Mitigating methane emissions and air intrusion in heterogeneous landfills with a high permeability layer

Spatially variable refuse gas permeability and landfill gas (LFG) generation rate, cracking of the soil cover, and reduced refuse gas permeability because of liquid addition can all affect CH(4) collection efficiency when intermediate landfill covers are installed. A new gas collection system that includes a near-surface high permeability layer beneath the landfill cover was evaluated for enhancing capture of LFG and mitigating CH(4) emissions. Simulations of gas transport in two-dimensional domains demonstrated that the permeable layer reduces CH(4) emissions up to a factor of 2 for particular spatially variable gas permeability fields. When individual macrocracks formed in the cover soil and the permeable layer was absent, CH(4) emissions increased to as much as 24% of the total CH(4) generated, double the emissions when the permeable layer was installed. CH(4) oxidation in the cover soil was also much more uniform when the permeable layer was present: local percentages of CH(4) oxidized varied between 94% and 100% across the soil cover with the permeable layer, but ranged from 10% to 100% without this layer for some test cases. However, the permeable layer had a minor effect on CH(4) emissions and CH(4) oxidation in the cover soil when the ratio of the gas permeability of the cover soil to the mean refuse gas permeability ≤ 0.05. The modeling approach employed in this study may be used to assess the utility of other LFG collection systems and management practices.

Photoacoustic infrared spectroscopy for conducting gas tracer tests and measuring water saturations in landfills.

Gas tracer tests can be used to determine gas flow patterns within landfills, quantify volatile contaminant residence time, and measure water within refuse. While gas chromatography (GC) has been traditionally used to analyze gas tracers in refuse, photoacoustic spectroscopy (PAS) might allow real-time measurements with reduced personnel costs and greater mobility and ease of use. Laboratory and field experiments were conducted to evaluate the efficacy of PAS for conducting gas tracer tests in landfills. Two tracer gases, difluoromethane (DFM) and sulfur hexafluoride (SF(6)), were measured with a commercial PAS instrument. Relative measurement errors were invariant with tracer concentration but influenced by background gas: errors were 1-3% in landfill gas but 4-5% in air. Two partitioning gas tracer tests were conducted in an aerobic landfill, and limits of detection (LODs) were 3-4 times larger for DFM with PAS versus GC due to temporal changes in background signals. While higher LODs can be compensated by injecting larger tracer mass, changes in background signals increased the uncertainty in measured water saturations by up to 25% over comparable GC methods. PAS has distinct advantages over GC with respect to personnel costs and ease of use, although for field applications GC analyses of select samples are recommended to quantify instrument interferences.

Assessing methods to estimate emissions of non-methane organic compounds from landfills

The non-methane organic compound (NMOC) emission rate is used to assess compliance with landfill gas emission regulations by the United States Environmental Protection Agency (USEPA). A recent USEPA Report (EPA/600/R-11/033) employed a ratio method to estimate speciated NMOC emissions (i.e., individual NMOC emissions): speciated NMOC emissions=measured methane (CH4) emission multiplied by the ratio of individual NMOCs concentration relative to CH4 concentration (C(NMOCs)/C(CH4)) in the landfill header gas. The objectives of this study were to (1) evaluate the efficacy of the ratio method in estimating speciated NMOC flux from landfills; (2) determine for what types of landfills the ratio method may be in error and why, using recent field data to quantify the spatial variation of (C(NMOCs)/C(CH4)) in landfills; and (3) formulate alternative models for estimating NMOC emissions from landfills for cases in which the ratio method results in biased estimates. This study focuses on emissions through landfill covers measured with flux chambers and evaluates the utility of the ratio method for estimating NMOC emission through this pathway. Evaluation of the ratio method was performed using CH4 and speciated NMOC concentration and flux data from 2012/2013 field sampling of four landfills, an unpublished landfill study, and literature data from three landfills. The ratio method worked well for landfills with thin covers (<40 cm), predicting composite NMOC flux (as hexane-C) to within a factor of 10× for 13 out of 15 measurements. However, for thick covers (⩾40 cm) the ratio method overestimated NMOC emissions by ⩾10× for 8 out of 10 measurements. Alternative models were explored incorporating other chemical properties into the ratio method. A molecular weight squared (MW)(2)-modified ratio equation was shown to best address the tendency of the current ratio method to overestimate NMOC fluxes for thick covers. While these analyses were only performed using NMOC fluxes through landfill covers measured with flux chambers, results indicate the current USEPA approach for estimating NMOC emissions may overestimate speciated NMOC emission ⩾10× for many compounds.

Quantifying capture efficiency of gas collection wells with gas tracers.

A new in situ method for directly measuring the gas collection efficiency in the region around a gas extraction well was developed. Thirteen tests were conducted by injecting a small volume of gas tracer sequentially at different locations in the landfill cell, and the gas tracer mass collected from each test was used to assess the collection efficiency at each injection point. For 11 tests the gas collection was excellent, always exceeding 70% with seven tests showing a collection efficiency exceeding 90%. For one test the gas collection efficiency was 8±6%. Here, the poor efficiency was associated with a water-laden refuse or remnant daily cover soil located between the point of tracer injection and the extraction well. The utility of in situ gas tracer tests for quantifying landfill gas capture at particular locations within a landfill cell was demonstrated. While there are certainly limitations to this technology, this method may be a valuable tool to help answer questions related to landfill gas collection efficiency and gas flow within landfills. Quantitative data from tracer tests may help assess the utility and cost-effectiveness of alternative cover systems, well designs and landfill gas collection management practices.

Comparison of thermophilic anaerobic and aerobic treatment processes for stabilization of green and food wastes and production of soil amendments

The management of organic wastes is an environmental and social priority. Aerobic digestion (AED) or composting and anaerobic digestion (AD) are two organic waste management practices that produce a value-added final product. Few side-by-side comparisons of both technologies and their digestate products have been performed. The objective of this study was to compare the impact of initial feedstock properties (moisture content and/or C/N ratio) on stabilization rate by AED and AD and soil amendment characteristics of the final products. Green and food wastes were considered as they are two of the main contributors to municipal organic waste. Stabilization rate was assessed by measurement of CH4 and CO2 evolution for AD and AED, respectively. For AD, CH4 yield showed a second-order relationship with the C/N content (P < 0.05); the optimal C/N ratio indicated by the relationship was 25.5. For AED, cumulative CO2 evolution values were significantly affected by the C/N ratio and moisture content of the initial feedstock (P < 0.05). A response surface model showed optimal AED stabilization for a C/N of 25.6 and moisture of 64.9% (wet basis). AD final products presented lower soluble chemical oxygen demand (COD) but lower humification degree and aromaticity than the products from AED. This lower stability may lead to further degradation when amended to soil. The results suggest that composting feedstocks with higher C/N produces an end-product with higher suitability for soil amendment. The instability of end products from AD could be leveraged in pest control techniques that rely on organic matter degradation to produce compounds with pesticidal properties.

Ambient-temperature co-digestion of low-solids municipal and industrial waste mixtures: Insights from molecular analyses

ABSTRACT The performance of ambient temperature anaerobic co-digestion was investigated for mixtures of six substrates: canned tomato and salsa waste, portable toilet waste, septic tank waste, winery waste, beer and cider waste, and fats, oils, and grease (FOG). Laboratory semi-continuous reactor studies and molecular biological analyses revealed that beer/winery, and tomato/FOG/winery/beer mixtures resulted in the best performance in terms of biogas production (515 and 371 mL CH4/g VS, respectively) and methanogenic populations. A portable toilet/septage mixture resulted in the overall poorest performance and inhibition of microbial activity was evident. Average methane content was ~70% for all mixtures tested. The findings of this study reveal that healthy methanogen populations were present, further supporting the feasibility of biogas production via the novel feedstock mixtures in ambient temperature lagoons. Implications: Disposal of septic tank waste and other high chemical oxygen demand (COD) 10 industrial food processing waste at a small wastewater treatment plant is uncommon, because it can upset the treatment process and requires additional power for treatment. Ambient-temperature covered lagoon digesters can be an alternative low-cost technology for co-digestion of these recalcitrant waste streams while generating bioenergy. The results of this study demonstrated that there is potential for implementation of unheated covered lagoon digester systems 15 for conversion of liquid wastes for production of renewable biomethane while eliminating the need to treat these wastes at a wastewater treatment plant.

Methods of Responsibly Managing End-of-Life Foams and Plastics Containing Flame Retardants: Part II

Flame retardants (FRs) are added to foams and plastics to comply with flammability standards and test requirements in products for household and industrial uses. When these regulations were implemented, potential health and environmental impacts of FR use were not fully recognized or understood. Extensive research in the past decades reveal that exposure to halogenated FRs, such as those used widely in furniture foam, is associated with and/or causally related to numerous health effects in animals and humans. While many of the toxic FRs have been eliminated and replaced by other FRs, existing products containing toxic or potentially toxic chemical FRs will remain in use for decades, and new products containing these and similar chemicals will permeate the environment. When such products reach the end of their useful life, proper disposal methods are needed to avoid health and ecological risks. To minimize continued human and environmental exposures to hazardous FR chemicals from discarded products, waste management technologies and processes must be improved. This review discusses a wide range of issues associated with all aspects of the use and responsible disposal of wastes containing FRs, and identifies basic and applied research needs in the areas of responsible collection, pretreatment, processing, and management of these wastes.