Ramzy Abdelaziz

Design of a Perfect Black Absorber at Visible Frequencies Using Plasmonic Metamaterials

The design and fabrication of a plasmonic black absorber with almost 100% absorbance spanning a broad range of frequencies from ultraviolet (UV) to the near infrared (NIR) is demonstrated. The perfect plasmonic absorber is achieved by a combination of a metal film with suitable metal/dielectric nanocomposites. Our fabrication technique is simple, versatile, cost-effective, and compatible with current industrial methods for solar absorber production.

Green chemistry and nanofabrication in a levitated Leidenfrost drop

Green nanotechnology focuses on the development of new and sustainable methods of creating nanoparticles, their localized assembly and integration into useful systems and devices in a cost-effective, simple and eco-friendly manner. Here we present our experimental findings on the use of the Leidenfrost drop as an overheated and charged green chemical reactor. Employing a droplet of aqueous solution on hot substrates, this method is capable of fabricating nanoparticles, creating nanoscale coatings on complex objects and designing porous metal in suspension and foam form, all in a levitated Leidenfrost drop. As examples of the potential applications of the Leidenfrost drop, fabrication of nanoporous black gold as a plasmonic wideband superabsorber, and synthesis of superhydrophilic and thermal resistive metal–polymer hybrid foams are demonstrated. We believe that the presented nanofabrication method may be a promising strategy towards the sustainable production of functional nanomaterials.

A Novel Nanohybrid Nanofibrous Adsorbent for Water Purification from Dye Pollutants

In this study, we devised a novel nanofibrous adsorbent made of polyethersulfone (PES) for removal of methylene blue (MB) dye pollutant from water. The polymer shows a low isoelectric point thus at elevated pHs and, being nanofibrous, can offer a huge highly hydroxylated surface area for adsorption of cationic MB molecules. As an extra challenge, to augment the adsorbent’s properties in terms of adsorption capacity in neutral and acidic conditions and thermal stability, vanadium pentoxide (V2O5) nanoparticles were added to the nanofibers. Adsorption data were analyzed according to the Freundlich adsorption model. The thermodynamic parameters verified that only at basic pH is the adsorption spontaneous and in general the process is entropy-driven and endothermic. The kinetics of the adsorption process was evaluated by the pseudo-first- and pseudo-second-order models. The latter model exhibited the highest correlation with data. In sum, the adsorbent showed a promising potential for dye removal from industrial dyeing wastewater systems, especially when envisaging their alkaline and hot conditions.

Photoresponsive Transparent Conductive Metal with a Photobleaching Nose

Smart materials that respond to a stimulus or their environment to produce a dynamic and reversible change in critical properties are in focus of actual research. [ 1 ] Among several stimuli, photochromism is receiving increasing attention because of its potential applications in molecular switching, lenses, and data storage among others. [ 2 ] In general, photochromic molecules can turn any composite into a smart material provided the host matrix is soft enough (e.g., a polymer) to let the molecule rotate upon illumination. The unique properties of these molecules can be even more benefi cial implemented into the devices whose optical properties are the matter of interest (e.g., optoelctronic devices) and to make them smart. In this regard, transparent conductors (TCs) can be a proper matter since their optical properties are crucial. Traditionally, indium tin oxide (ITO) has been widely implemented as a standard TC in different kinds of optoelectronic devices. However having phototunable optical transparency along with high electrical conductivity would be potentially applicable for novel smart optoelectronic sensors. During the course of last decades great efforts have been made to develop new kind of TCs to replace ITO. [ 3–5 ] In this regard, different materials and composites have been proposed and studied, including conductive polymers, [ 6 ]

Biomimetic Transferable Surface for a Real Time Control over Wettability and Photoerasable Writing with Water Drop Lens

We demonstrate a transferable device that can turn wettability of surfaces to sticky or slippy, as per requirement. It is composed of polymeric yarn with a fibrous structure, which can be lifted and placed on any surface to render it the unique wettability properties. We introduce Polyvinylidenefluoride (PVDF) random fiber as biomimetic rose petal surface. When it is decorated with PVDF nanofibers yarns, the random mesh transform from rose petal sticky state into grass leaf slippy state. When it is placed on sticky, hydrophilic metal coin, it converts the surface of the coin to super hydrophobic. Adjustments in the yarn system, like interyarn spacing, can be done in real time to influence its wettability, which is a unique feature. Next, we load the polymer with a photochromic compound for chemical restructuring. It affects the sliding angle of water drop and makes the fibers optically active. We also demonstrate a “water droplets lens” concept that enables erasable writing on photochromic rose petal sticky fibrous surface. The droplet on a highly hydrophobic surface acts as a ball lens to concentrate light onto a hot spot; thereby we demonstrate UV light writing with water lenses and visible light erasing.

Thermo-Plasmonics for Localized Graphitization and Welding of Polymeric Nanofibers

There is a growing interest in modulating the temperature under the illumination of light. As a heat source, metal nanoparticles (NPs) have played an important role to pave the way for a new branch of plasmonics, i.e., thermo-plasmonics. While thermo-plasmonics have been well established in photo-thermal therapy, it has received comparatively less attention in materials science and chemistry. Here, we demonstrate the first proof of concept experiment of local chemistry and graphitization of metalized polymeric nanofibers through thermo-plasmonic effect. In particular, by tuning the plasmonic absorption of the nanohybrid through a change in the thickness of the deposited silver film on the fibers, the thermo-plasmonic effect can be adjusted in such a way that high enough temperature is generated enabling local welding and graphitization of the polymeric nanofibers.

Underwater Leidenfrost nanochemistry for creation of size-tailored zinc peroxide cancer nanotherapeutics

The dynamic underwater chemistry seen in nature is inspiring for the next generation of eco-friendly nanochemistry. In this context, green synthesis of size-tailored nanoparticles in a facile and scalable manner via a dynamic process is an interesting challenge. Simulating the volcano-induced dynamic chemistry of the deep ocean, here we demonstrate the Leidenfrost dynamic chemistry occurring in an underwater overheated confined zone as a new tool for customized creation of nanoclusters of zinc peroxide. The hydrodynamic nature of the phenomenon ensures eruption of the nanoclusters towards a much colder region, giving rise to growth of monodisperse, size-tailored nanoclusters. Such nanoparticles are investigated in terms of their cytotoxicity on suspension and adherent cells to prove their applicability as cancer nanotherapeutics. Our research can pave the way for employment of the dynamic green nanochemistry in facile, scalable fabrication of size-tailored nanoparticles for biomedical applications.