Rattikorn Yimnirun

Dielectric relaxations and dielectric response in multiferroic BiFeO3 ceramics

Single-phase multiferroic BiFeO3 ceramics were fabricated using pure precipitation-prepared BiFeO3 powder. Dielectric response of BiFeO3 ceramics was investigated over a wide range of temperature and frequency. Our results reveal that the BiFeO3 ceramic sintered at 700 °C exhibited high dielectric permittivity, and three dielectric relaxations were observed. A Debye-type dielectric relaxation at low temperatures (−50 to 20 °C) is attributed to the carrier hopping process between Fe2+ and Fe3+. The other two dielectric relaxations at the temperature ranges 30–130 °C and 140–200 °C could be due to the grain boundary effect and the defect ordering and/or the conductivity, respectively.

Scaling behavior of dynamic hysteresis in soft lead zirconate titanate bulk ceramics

The scaling behavior of the dynamic hysteresis of ferroelectric bulk system was investigated. The scaling relation of hysteresis area ⟨A⟩ against frequency f and field amplitude E0 for the saturated loops of the soft lead zirconate titanate bulk ceramic takes the form of ⟨A⟩∝f−1∕4E0, which differs significantly from that of the theoretical prediction and that of the thin film. This indicates that the scaling relation is dimension dependent and that depolarizing effects in the interior must be taken into account to model bulk materials. Additionally, the scaling relation for the minor loops takes the form of ⟨A⟩∝f−1∕3E03, which is identical to that of the thin film as both cases contain similar 180° domain-reversal mechanism.

Temperature scaling of dynamic hysteresis in soft lead zirconate titanate bulk ceramic

The temperature scaling of the dynamic hysteresis was investigated in soft ferroelectric bulk ceramic. The power-law temperature scaling relations were obtained for hystersis area ⟨A⟩ and remnant polarization Pr, while the coercivity EC was found to scale linearly with temperature T. The three temperature scaling relations were also field dependent. At fixed field amplitude E0, the scaling relations take the forms of ⟨A⟩∝T−1.1024, Pr∝T−1.2322, and (EC0−EC)∝T. Furthermore, the product of Pr and EC also provides the same scaling law on the T dependence in comparison with ⟨A⟩.

Effect of uniaxial compressive pre-stress on ferroelectric properties of soft PZT ceramics

The effect of uniaxial compressive pre-stress on the ferroelectric properties of commercial soft PZT ceramics is investigated. The ferroelectric properties under the uniaxial compressive pre-stress of the ceramics are observed at stress up to 24 MPa using a compressometer in conjunction with a modified Sawyer–Tower circuit. The results show that the ferroelectric characteristics, i.e. the area of the ferroelectric hysteresis (P–E) loops, the saturation polarization (Psat), the remanent polarization (Pr), and the loop squareness (Rsq) decrease with increasing compressive pre-stress, while the coercive field (Ec) is virtually unaffected by the applied stress. The stress-induced domain wall motion suppression and non-180° ferroelectric domain switching processes are responsible for the changes observed. In addition, a significant decrease in these parameters after a full cycle of stress application has been observed and attributed to the stress-induced decrease in the switchable part of the spontaneous polarization at high stress. Furthermore, the permittivity calculated from the P–E loops is found to decrease with increasing applied pre-stress. This finding differs considerably from the results in the low-field experimental condition. Finally, this study clearly shows that the applied stress has a significant influence on the ferroelectric properties of soft PZT ceramics.

Effects of uniaxial stress on dielectric properties lead magnesium niobate?lead zirconate titanate ceramics

Effects of uniaxial stress on the dielectric properties of ceramics in lead magnesium niobate?lead zirconate titanate (PMN?PZT) system are investigated. The ceramics with a formula (x)Pb(Mg1/3Nb2/3)O3?(1?x)Pb(Zr0.52Ti0.48)O3 or (x)PMN?(1 ? x)PZT when x = 0.0, 0.1, 0.3, 0.5, 0.7, 0.9, and 1.0 are prepared by a conventional mixed-oxide method. Phase formation behaviour and microstructural features of these ceramics are studied by x-ray diffraction and scanning electron microscopy methods, respectively. The dielectric properties under the uniaxial stress of the PMN?PZT ceramics are observed at stress levels up to 5?MPa using a uniaxial compressometer. It is found that with increasing applied stress the dielectric constant of the PZT-rich compositions increases slightly, while that of the PMN-rich compositions decreases. On the other hand, the dielectric loss tangent for most of the compositions first rises and then drops with increasing applied stress.

Converse electrostriction in polymers and composites

Abstract The evaluation of electrostrictive properties of low permittivity dielectrics requires extremely sensitive instrumentation. In the present work, a modified compressometer capable of resolving fractional changes in capacitance of the order of 10 −6 is used. In the compressometric method, a high sensitivity capacitance bridge, GenRad 1615, is coupled with two lock-in amplifiers to detect attofarad (10 −18 F) level capacitance changes caused by in-phase cyclic uniaxial stresses on the samples. In studying low-permittivity polymers, we have obtained extensive electrostriction data, which along with widely accepted data on ferroelectric materials and soft polymers, verify the linear relationship between electrostriction coefficient ( Q ) and the ratio of elastic compliance and dielectric permittivity (s/ ϵ 0 ϵ r ). This leads to an effective way to predict the electrostriction coefficient in dielectric materials.

Dynamic hysteresis and scaling behavior of hard lead zirconate titanate bulk ceramics

The scaling relation of ferroelectric hysteresis area ⟨A⟩ against frequency f and field amplitude E0 for the saturated loops of the hard lead zirconate titanate bulk ceramic takes the form of ⟨A⟩∝f−0.28E00.89, while that for the minor loops takes the form of ⟨A⟩∝f−0.43E03.19. In both cases, the scaling relations are similar to those of its soft counterpart. This indicates that the dynamic behaviors and scaling relations in bulk ceramics are mainly governed by the domain states and structures, while the distinct types of complex defects contribute mainly to the difference in the coercive field observed in hard and soft ceramics.

Dynamic ferroelectric hysteresis scaling of BaTiO3 single crystals

The scaling behavior of the dynamic hysteresis of ferroelectric BaTiO3 single crystals was investigated. Two sets of the scaling relation of hysteresis area ⟨A⟩ against frequency f and field amplitude E0 were clearly established. Above the coercive field, the scaling took a form of ⟨A⟩∝f−0.195E00.950. On the other hand, the scaling in the form of ⟨A⟩∝f1.667E0−2.804E04.157 was obtained under subcoercive field condition. While these scaling relations were generally comparable to previously reported ones, it was found that the f and E0 exponents depended on E0 and f, respectively, which was in contrast to the prior theoretical prediction and experimental investigations.

Lead-free ternary perovskite compounds with large electromechanical strains

Lead-free compounds based on perovskite solid solutions in the ternary system (Bi1/2Na1/2)TiO3–(Bi1/2K1/2)TiO3–Bi(X1/2Ti1/2)O3, where X = Ni and Mg have been shown to exhibit large electromechanical strains. While the perovskite end members Bi(Mg1/2Ti1/2)O3 and Bi(Ni1/2Ti1/2)O3 display limited stability in their pure state, both compounds were found to have solid solubilities of at least 50 mol. % with (Bi1/2Na1/2)TiO3 and (Bi1/2K1/2)TiO3. Most importantly, under relatively large applied fields, these materials exhibited large hysteretic electromechanical strains characterized by a parabolic shape. With effective piezoelectric coefficients (d33*) greater than 500 pm/V, these systems have excellent potential as a Pb-free piezoelectric materials.

Charge storage mechanisms of manganese oxide nanosheets and N-doped reduced graphene oxide aerogel for high-performance asymmetric supercapacitors

Although manganese oxide- and graphene-based supercapacitors have been widely studied, their charge storage mechanisms are not yet fully investigated. In this work, we have studied the charge storage mechanisms of K-birnassite MnO2 nanosheets and N-doped reduced graphene oxide aerogel (N-rGOae) using an in situ X-ray absorption spectroscopy (XAS) and an electrochemical quart crystal microbalance (EQCM). The oxidation number of Mn at the MnO2 electrode is +3.01 at 0 V vs. SCE for the charging process and gets oxidized to +3.12 at +0.8 V vs. SCE and then reduced back to +3.01 at 0 V vs. SCE for the discharging process. The mass change of solvated ions, inserted to the layers of MnO2 during the charging process is 7.4 μg cm−2. Whilst, the mass change of the solvated ions at the N-rGOae electrode is 8.4 μg cm−2. An asymmetric supercapacitor of MnO2//N-rGOae (CR2016) provides a maximum specific capacitance of ca. 467 F g−1 at 1 A g−1, a maximum specific power of 39 kW kg−1 and a specific energy of 40 Wh kg−1 with a wide working potential of 1.6 V and 93.2% capacity retention after 7,500 cycles. The MnO2//N-rGOae supercapacitor may be practically used in high power and energy applications.