Yongyut Laosiritaworn

Scaling behavior of dynamic hysteresis in soft lead zirconate titanate bulk ceramics

The scaling behavior of the dynamic hysteresis of ferroelectric bulk system was investigated. The scaling relation of hysteresis area ⟨A⟩ against frequency f and field amplitude E0 for the saturated loops of the soft lead zirconate titanate bulk ceramic takes the form of ⟨A⟩∝f−1∕4E0, which differs significantly from that of the theoretical prediction and that of the thin film. This indicates that the scaling relation is dimension dependent and that depolarizing effects in the interior must be taken into account to model bulk materials. Additionally, the scaling relation for the minor loops takes the form of ⟨A⟩∝f−1∕3E03, which is identical to that of the thin film as both cases contain similar 180° domain-reversal mechanism.

Temperature scaling of dynamic hysteresis in soft lead zirconate titanate bulk ceramic

The temperature scaling of the dynamic hysteresis was investigated in soft ferroelectric bulk ceramic. The power-law temperature scaling relations were obtained for hystersis area ⟨A⟩ and remnant polarization Pr, while the coercivity EC was found to scale linearly with temperature T. The three temperature scaling relations were also field dependent. At fixed field amplitude E0, the scaling relations take the forms of ⟨A⟩∝T−1.1024, Pr∝T−1.2322, and (EC0−EC)∝T. Furthermore, the product of Pr and EC also provides the same scaling law on the T dependence in comparison with ⟨A⟩.

Effect of uniaxial compressive pre-stress on ferroelectric properties of soft PZT ceramics

The effect of uniaxial compressive pre-stress on the ferroelectric properties of commercial soft PZT ceramics is investigated. The ferroelectric properties under the uniaxial compressive pre-stress of the ceramics are observed at stress up to 24 MPa using a compressometer in conjunction with a modified Sawyer–Tower circuit. The results show that the ferroelectric characteristics, i.e. the area of the ferroelectric hysteresis (P–E) loops, the saturation polarization (Psat), the remanent polarization (Pr), and the loop squareness (Rsq) decrease with increasing compressive pre-stress, while the coercive field (Ec) is virtually unaffected by the applied stress. The stress-induced domain wall motion suppression and non-180° ferroelectric domain switching processes are responsible for the changes observed. In addition, a significant decrease in these parameters after a full cycle of stress application has been observed and attributed to the stress-induced decrease in the switchable part of the spontaneous polarization at high stress. Furthermore, the permittivity calculated from the P–E loops is found to decrease with increasing applied pre-stress. This finding differs considerably from the results in the low-field experimental condition. Finally, this study clearly shows that the applied stress has a significant influence on the ferroelectric properties of soft PZT ceramics.

Dynamic hysteresis and scaling behavior of hard lead zirconate titanate bulk ceramics

The scaling relation of ferroelectric hysteresis area ⟨A⟩ against frequency f and field amplitude E0 for the saturated loops of the hard lead zirconate titanate bulk ceramic takes the form of ⟨A⟩∝f−0.28E00.89, while that for the minor loops takes the form of ⟨A⟩∝f−0.43E03.19. In both cases, the scaling relations are similar to those of its soft counterpart. This indicates that the dynamic behaviors and scaling relations in bulk ceramics are mainly governed by the domain states and structures, while the distinct types of complex defects contribute mainly to the difference in the coercive field observed in hard and soft ceramics.

Dynamic ferroelectric hysteresis scaling of BaTiO3 single crystals

The scaling behavior of the dynamic hysteresis of ferroelectric BaTiO3 single crystals was investigated. Two sets of the scaling relation of hysteresis area ⟨A⟩ against frequency f and field amplitude E0 were clearly established. Above the coercive field, the scaling took a form of ⟨A⟩∝f−0.195E00.950. On the other hand, the scaling in the form of ⟨A⟩∝f1.667E0−2.804E04.157 was obtained under subcoercive field condition. While these scaling relations were generally comparable to previously reported ones, it was found that the f and E0 exponents depended on E0 and f, respectively, which was in contrast to the prior theoretical prediction and experimental investigations.

Magnetic properties of Ising thin films with cubic lattices

We have used Monte Carlo simulations to observe the magnetic behaviour of Ising thin-films with cubic lattice structures as a function of temperature and thickness especially in the critical region. The fourth order Binder cumulant is used to extract critical temperatures, and an extension of finite size scaling theory for reduced geometry is derived to calculate the critical exponents. Magnetisation and magnetic susceptibility per spin in each layer are also investigated. In addition, mean-field calculations are also performed for comparison. We find that the magnetic behaviour changes from two dimensional to three dimensional character with increasing thickness of the film. The crossover of the critical temperature from a two dimensional to a bulk value is also observed with both the Monte Carlo simulations and the mean-field analysis. Nevertheless, the simulations have shown that the critical exponents only vary a little from their two dimensional values. In particular, the results for films with up to eight layers provide a strong indication of two dimensional universality.

Change of dielectric properties of ceramics in lead magnesium niobate-lead titanate system with compressive stress

Effects of compressive stress on the dielectric properties of PMN?PT ceramics were investigated. The ceramics with the formula (1 ? x)Pb(Mg1/3Nb2/3)O3-(x)PbTiO3 or (1 ? x)PMN?(x)PT (x = 0.1?0.5) were prepared by a conventional mixed-oxide method and then characterized with x-ray diffraction (XRD) and scanning electron microscopy. Dense perovskite-phase PMN?PT ceramics with uniform microstructure were successfully obtained. The dielectric properties under compressive stress were observed at stress up to 230?MPa using a home-built compressometer. The experimental results revealed that the superimposed compression stress significantly reduced both the dielectric constant and the dielectric loss tangent of 0.9PMN?0.1PT ceramic, while the changes were not as significant in the other PMN?PT ceramic compositions. In addition, the dielectric properties were considerably lowered after a stress cycle. Since change in the dielectric properties with applied stress was attributed to the competing influences of the intrinsic and the extrinsic contributions, the observations were mainly interpreted in terms of domain switching through non-180? domain walls, de-ageing, clamping of domain walls and the stress induced decrease in the switchable part of spontaneous polarization.

Stress-dependent scaling behavior of dynamic hysteresis in bulk soft ferroelectric ceramic

The effects of frequency f, field amplitude E0, and mechanical stress σ on the hysteresis area ⟨A⟩ and their scaling relations were investigated on soft PZT bulk ceramics. The hysteresis area was found to depend on the frequency and field amplitude with a same set of exponents to the power-law scaling for both with and without stresses, indicating the universality. The inclusion of stresses into the power law was also obtained in the form of ⟨A−Aσ=0⟩∝f−0.25E0σ0.44, which indicates the difference of the energy dissipation between the under stress and stress-free conditions and reveals how the hysteresis area decays with increasing stresses.

Stress- and temperature-dependent scaling behavior of dynamic hysteresis in soft PZT bulk ceramics

Effects of electric field-frequency, electric field-amplitude, mechanical stress, and temperature on the hysteresis area, especially the scaling form, were investigated in soft lead zirconate titanate (PZT) bulk ceramics. The hysteresis area was found to depend on the frequency and field-amplitude with the same set of exponents as the power-law scaling for both with and without stresses. The inclusion of stresses into the power-law was obtained in the form of which indicates the difference in energy dissipation between the under-stress and stress-free conditions. The power-law temperature scaling relations were obtained for hysteresis area A and remanent polarization Pr, while the coercivity EC was found to scale linearly with temperature T. The three temperature scaling relations were also field-dependent. At fixed field amplitude E0, the scaling relations take the forms of , Pr ∝T−1.2322 and (EC0 - EC) ∝T.

Changes in ferroelectric properties of ceramics in lead magnesium niobate–lead titanate system with compressive stress

Effects of compressive stress on the ferroelectric properties of Pb(Mg1/3Nb2/3)O3–PbTiO3 (PMN-PT) ceramics were investigated. The ceramics with the formula (1−x)Pb(Mg1/3Nb2/3)O3−(x)PbTiO3 or (1−x)PMN−(x)PT (x=0.1–0.5) were prepared by a conventional mixed-oxide method. Dense perovskite-phase PMN-PT ceramics with a uniform microstructure were obtained. The ferroelectric properties were measured under compressive stress (0–75 MPa) using a homebuilt compressometer in conjunction with a modified Sawyer–Tower circuit. The experimental results revealed that the superimposed compression stress significantly reduced both the dissipation energy and the polarizations of the near morphotropic phase boundary compositions, i.e., 0.8PMN-0.2PT, 0.7PMN-0.3PT, and 0.6PMN-0.4PT, while the stress influence was much less in other compositions. On the contrary, the applied compressive stress showed little or no influence on the coercive field. These results were interpreted through the non-180° ferroelastic domain switching p...