Raymond A. Cook

Supported ionic liquid catalysis investigated for hydrogenation reactions

The concept of supported ionic liquid catalysis (silc) has successfully been applied to hydrogenation reactions, which significantly reduced the required amounts of ionic liquid phase and enabled the usage of fixed-bed technology; the resulting catalysts exhibited high activity and outstanding stability.

Preparation of C9-aldehyde via aldol condensation reactions in ionic liquid media

C9-aldehyde has been prepared via aldol condensation reactions in ionic liquid media; catalyst investigation showed enhanced product selectivity for the desired aldehyde in ionic liquid media than in conventional solvent systems.

13C NMR study of the acid-catalyzed carbonylation of methyl tert-butyl ether (MTBE)

Methyl tert-butyl ether (MTBE) is a widely used additive in oxygenated gasoline that has recently been identified as a potential health threat to the drinking water supply due to leaking underground storage tanks. One alternate use for MTBE is the production of methyl 2,2-dimethylpropanoate (methyl pivalate) via Koch carbonylation chemistry. BF3/H2O catalysts are employed in industrial applications of Koch chemistry, but cannot be used for direct ester production because the presence of water in the system leads to the formation of carboxylic acids and lowers the selectivity to esters. Therefore, a BF3/CH3OH complex was investigated for the carbonylation of MTBE to avoid this loss in selectivity. This study used 13C NMR spectroscopy and ab initio calculations to investigate this carbonylation reaction. NMR results and ab initio calculations suggest a structure for the BF3/CH3OH acid which is in agreement with previous studies, and a Hammett acidity value of -4.2 was calculated for BF3-2.19CH3OH using the Δδ method. It is believed that these are the first reported ab initio calculations on the BF3/CH3OH system. NMR results also show that MTBE begins to react between 50 °C and 75 °C to produce oligomers of isobutene when no CO is present and carbonylated species when CO is present.