Reuven H. Heiblum

Formation of highly porous aerosol particles by atmospheric freeze-drying in ice clouds.

Significance Aerosols cycling through clouds affect particle morphological and chemical properties, thus modifying aerosol effects on cloud microphysics and climate. Previous studies have focused on aerosol processing in warm clouds via aqueous-phase reactions. Here we investigate the physical modifications of aerosols following processing within ice clouds using a unique laboratory setup that simulates ice cloud processes. The processed particles have a porous structure due to phase separation upon freezing, subsequent glass transition, and ice sublimation. Such modified aerosols can be better ice and cloud condensation nuclei and scatter less light. These changes have implications for aerosol–cloud interactions and optical properties of aerosols in the vicinity of clouds. The cycling of atmospheric aerosols through clouds can change their chemical and physical properties and thus modify how aerosols affect cloud microphysics and, subsequently, precipitation and climate. Current knowledge about aerosol processing by clouds is rather limited to chemical reactions within water droplets in warm low-altitude clouds. However, in cold high-altitude cirrus clouds and anvils of high convective clouds in the tropics and midlatitudes, humidified aerosols freeze to form ice, which upon exposure to subsaturation conditions with respect to ice can sublimate, leaving behind residual modified aerosols. This freeze-drying process can occur in various types of clouds. Here we simulate an atmospheric freeze-drying cycle of aerosols in laboratory experiments using proxies for atmospheric aerosols. We find that aerosols that contain organic material that undergo such a process can form highly porous aerosol particles with a larger diameter and a lower density than the initial homogeneous aerosol. We attribute this morphology change to phase separation upon freezing followed by a glass transition of the organic material that can preserve a porous structure after ice sublimation. A porous structure may explain the previously observed enhancement in ice nucleation efficiency of glassy organic particles. We find that highly porous aerosol particles scatter solar light less efficiently than nonporous aerosol particles. Using a combination of satellite and radiosonde data, we show that highly porous aerosol formation can readily occur in highly convective clouds, which are widespread in the tropics and midlatitudes. These observations may have implications for subsequent cloud formation cycles and aerosol albedo near cloud edges.

Aerosol effect on the evolution of the thermodynamic properties of warm convective cloud fields

Convective cloud formation and evolution strongly depend on environmental temperature and humidity profiles. The forming clouds change the profiles that created them by redistributing heat and moisture. Here we show that the evolution of the field’s thermodynamic properties depends heavily on the concentration of aerosol, liquid or solid particles suspended in the atmosphere. Under polluted conditions, rain formation is suppressed and the non-precipitating clouds act to warm the lower part of the cloudy layer (where there is net condensation) and cool and moisten the upper part of the cloudy layer (where there is net evaporation), thereby destabilizing the layer. Under clean conditions, precipitation causes net warming of the cloudy layer and net cooling of the sub-cloud layer (driven by rain evaporation), which together act to stabilize the atmosphere with time. Previous studies have examined different aspects of the effects of clouds on their environment. Here, we offer a complete analysis of the cloudy atmosphere, spanning the aerosol effect from instability-consumption to enhancement, below, inside and above warm clouds, showing the temporal evolution of the effects. We propose a direct measure for the magnitude and sign of the aerosol effect on thermodynamic instability.

Core and margin in warm convective clouds. Part II: aerosol effects on core properties

This paper follows from Part I which sought to examine the various methods of defining the cores and margins of convective clouds by using buoyancy, RH, and vertical velocity to define the core. They showed that these core diagnostics can be subsets of one another, but that this varies in space and time. This follow-on study examines the impacts of varying the aerosol concentration on the core definitions. Given that aerosols can change the cloud DSD, the condensation/evaporation rates can change,

The Consistent Behavior of Tropical Rain: Average Reflectivity Vertical Profiles Determined by Rain Top Height

AbstractSixteen years of Tropical Rain Measuring Mission (TRMM) reflectivity profile data are collected for oceanic, continental, and island tropical regions within the boreal winter intertropical convergence zone (ITCZ). When sorted by the rain top height (RTH), a consistent behavior emerges where the average reflectivity profiles originating at different RTHs form non-overlapping manifolds in the height–reflectivity space, excluding the brightband regions for stratiform type profiles. Based on reflectivity slope (dBZ km−1) profile characteristics and physical considerations, the profiles are divided into three classes: 1) cold profiles, which originate above the −20°C isotherm height and display convergence to a single reflectivity slope profile independent of RTH; 2) warm profiles, which originate below the 0°C isotherm height and display strong reflectivity slope dependence on RTH, with slope values per RTH linearly decreasing with decreased height; and 3) mixed profiles, which originate at the layer ...

Characterization of cumulus cloud fields using trajectories in the center of gravity versus water mass phase space: 2. Aerosol effects on warm convective clouds: Center of Gravity Versus Water Mass 2

In Part I of this work a 3-D cloud tracking algorithm and phase space of center of gravity altitude versus cloud liquid water mass (CvM space) were introduced and described in detail. We showed how new physical insight can be gained by following cloud trajectories in the CvM space. Here this approach is used to investigate aerosol effects on cloud fields of warm cumuli. We show a clear effect of the aerosol loading on the shape and size of CvM clusters. We also find fundamental differences in the CvM space between simulations using bin versus bulk microphysical schemes, with the bin scheme precipitation expressingmuch higher sensitivity to changes in aerosol concentrations. Using the bin microphysical scheme, we find that the increase in cloud center of gravity altitude with increase in aerosol concentrations occurs for a wide range of cloud sizes. This is attributed to reduced sedimentation, increased buoyancy and vertical velocities, and increased environmental instability, all of which are tightly coupled to inhibition of precipitation processes and subsequent feedbacks of clouds on their environment. Many of the physical processes shown here are consistent with processes typically associated with cloud invigoration.