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Featured researches published by Richard D. Offeman.


Waste Management & Research | 2016

A pilot-scale steam autoclave system for treating municipal solid waste for recovery of renewable organic content: Operational results and energy usage

Kevin M. Holtman; David V. Bozzi; Diana Franqui-Villanueva; Richard D. Offeman; William J. Orts

A pilot-scale (1800 kg per batch capacity) autoclave used in this study reduces municipal solid waste to a debris contaminated pulp product that is efficiently separated into its renewable organic content and non-renewable organic content fractions using a rotary trommel screen. The renewable organic content can be recovered at nearly 90% efficiency and the trommel rejects are also much easier to sort for recovery. This study provides the evaluation of autoclave operation, including mass and energy balances for the purpose of integration into organic diversion systems. Several methods of cooking municipal solid waste were explored from indirect oil heating only, a combination of oil and direct steam during the same cooking cycle, and steam only. Gross energy requirements averaged 1290 kJ kg−1 material in vessel, including the weight of free water and steam added during heating. On average, steam recovery can recoup 43% of the water added and 30% of the energy, supplying on average 40% of steam requirements for the next cook. Steam recycle from one vessel to the next can reduce gross energy requirements to an average of 790 kJ kg−1.


Journal of Agricultural and Food Chemistry | 2015

Countercurrent Extraction of Soluble Sugars from Almond Hulls and Assessment of the Bioenergy Potential

Kevin M. Holtman; Richard D. Offeman; Diana Franqui-Villanueva; Andre K. Bayati; William J. Orts

Almond hulls contain considerable proportions (37% by dry weight) of water-soluble, fermentable sugars (sucrose, glucose, and fructose), which can be extracted for industrial purposes. The maximum optimal solids loading was determined to be 20% for sugar extraction, and the addition of 0.5% (w/v) pectinase aided in maintaining a sufficient free water volume for sugar recovery. A laboratory countercurrent extraction experiment utilizing a 1 h steep followed by three extraction (wash) stages produced a high-concentration (131 g/L fermentable sugar) syrup. Overall, sugar recovery efficiency was 88%. The inner stage washing efficiencies were compatible with solution equilibrium calculations, indicating that efficiency was high. The concentrated sugar syrup was fermented to ethanol at high efficiency (86% conversion), and ethanol concentrations in the broth were 7.4% (v/v). Thin stillage contained 233 g SCOD/L, which was converted to biomethane at an efficiency of 90% with a biomethane potential of 297 mL/g SCODdestroyed. Overall, results suggested that a minima of 49 gal (185 L) ethanol and 75 m(3) methane/t hulls (dry whole hull basis) are achievable.


Canadian Journal of Chemistry | 2008

Effect of relative humidity on the morphology of electrospun polymer fibers

Eliton S. Medeiros; Luiz H. C. Mattoso; Richard D. Offeman; Delilah F. Wood; William J. Orts


Journal of Biobased Materials and Bioenergy | 2008

Electrospun Nanofibers of Poly(vinyl alcohol) Reinforced with Cellulose Nanofibrils

Eliton S. Medeiros; Luiz H. C. Mattoso; Edson N. Ito; Kay S. Gregorski; George H. Robertson; Richard D. Offeman; Delilah F. Wood; William J. Orts; Syed H. Imam


Industrial & Engineering Chemistry Research | 2005

Solvent Extraction of Ethanol from Aqueous Solutions. I. Screening Methodology for Solvents

Richard D. Offeman; Serena K. Stephenson; George H. Robertson; William J. Orts


Journal of Membrane Science | 2011

Effect of nanoscale morphology on selective ethanol transport through block copolymer membranes

Ashish K. Jha; Liang Chen; Richard D. Offeman; Nitash P. Balsara


Separation and Purification Technology | 2008

Extraction of ethanol with higher alcohol solvents and their toxicity to yeast

Richard D. Offeman; Serena K. Stephenson; Diana Franqui; Jessica L. Cline; George H. Robertson; William J. Orts


Journal of Membrane Science | 2011

Poisoning of mixed matrix membranes by fermentation components in pervaporation of ethanol

Richard D. Offeman; Charles N. Ludvik


Archive | 2004

Spiral-wound liquid membrane module for separation of fluids and gases

Richard D. Offeman; George H. Robertson


Journal of Membrane Science | 2011

A novel method to fabricate high permeance, high selectivity thin-film composite membranes

Richard D. Offeman; Charles N. Ludvik

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William J. Orts

United States Department of Agriculture

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George H. Robertson

United States Department of Agriculture

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Serena K. Stephenson

United States Department of Agriculture

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Kevin M. Holtman

United States Department of Agriculture

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Charles N. Ludvik

United States Department of Agriculture

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Eliton S. Medeiros

Federal University of Paraíba

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Luiz H. C. Mattoso

Empresa Brasileira de Pesquisa Agropecuária

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Ashish K. Jha

University of California

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Delilah F. Wood

United States Department of Agriculture

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Diana Franqui-Villanueva

United States Department of Agriculture

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