Robert Rember

Increased concentrations of dissolved trace metals and organic carbon during snowmelt in rivers of the alaskan arctic

Arctic rivers typically transport more than half of their annual amounts of water and suspended sediments during spring floods. In this study, the Sagavanirktok, Kuparuk and Colville rivers in the Alaskan Arctic were sampled during the spring floods of 2001 to determine levels of total suspended solids (TSS) and dissolved and particulate metals and organic carbon. Concentrations of dissolved organic carbon (DOC) increased from 167 to 742 μmol/L during peak discharge in the Sagavanirktok River, at about the same time that river flow increased to maximum levels. Concentrations of dissolved Cu, Pb, Zn and Fe in the Sagavanirktok River followed trends observed for DOC with 3- to 25-fold higher levels at peak flow than during off-peak discharge. Similar patterns were found for the Kuparuk and Colville rivers, where average concentrations of dissolved trace metals and DOC were even higher. These observations are linked to a large pulse of DOC and dissolved metals incorporated into snowmelt from thawing ponds and upper soil layers. In contrast with Cu, Fe, Pb and Zn, concentrations of dissolved Ba did not increase in response to increased discharge of water, TSS and DOC. Concentrations of particulate Cu, Fe, Pb and Zn were more uniform than observed for their respective dissolved species and correlated well with the Al content of the suspended particles. However, concentrations of particulate Al were poorly correlated with particulate organic carbon. Results from this study show that >80% of the suspended sediment and more than one-third of the annual inputs of dissolved Cu, Fe, Pb, Zn and DOC were carried to the coastal Beaufort Sea in 3 and 12 d, respectively, by the Kuparuk and Sagavanirktok rivers.

Mooring-Based Observations of Double-Diffusive Staircases over the Laptev Sea Slope*

AbstractA yearlong time series from mooring-based high-resolution profiles of water temperature and salinity from the Laptev Sea slope (2003–04; 2686-m depth; 78°26′N, 125°37′E) shows six remarkably persistent staircase layers in the depth range of ~140–350 m encompassing the upper Atlantic Water (AW) and lower halocline. Despite frequent displacement of isopycnal surfaces by internal waves and eddies and two strong AW warming pulses that passed through the mooring location in February and late August 2004, the layers preserved their properties. Using laboratory-derived flux laws for diffusive convection, the authors estimate the time-averaged diapycnal heat fluxes across the four shallower layers overlying the AW core to be ~8 W m−2. Temporal variability of these fluxes is strong, with standard deviations of ~3–7 W m−2. These fluxes provide a means for effective transfer of AW heat upward over more than a 100-m depth range toward the upper halocline. These findings suggest that double diffusion is an imp...

Dissolution of aerosol iron in the surface waters of the North Pacific and North Atlantic oceans as determined by a semicontinuous flow-through reactor method

Aerosol iron dissolution in oceanic waters is determined with a semicontinuous batch-leaching method. In this procedure, aerosol samples that were collected from the marine boundary layer were leached in an all-Teflon flow-through reaction chamber by multiple aliquots of similar to 40 mL 0.4 mu m filtered oceanic surface water collected using ultraclean techniques. Each aliquot of seawater is permitted to leach the aerosol sample in the reaction chamber for a predetermined time before the seawater solution is separated from the aerosol sample by a 0.4 mu m Nucleopore filter membrane. A new aliquot of seawater is then added to the leaching chamber to continue leaching the same aerosol particles retained on the filter. The procedure is repeated with progressive increases in leaching time. The method allows the Fe released from the aerosol particles to be continuously removed from the system before saturating the complexation capacity of the seawater-leaching solution or adsorbing onto the leaching chamber wall. This method results in accurate measurements of seawater-dissolvable labile aerosol Fe that is independent of the total aerosol Fe concentrations in the sample. The aerosol Fe solubility determined using this method ranges from 3.5 +/- 1.5% for the North Atlantic during September 2005 to 5.7 +/- 2.0% for the North Pacific during April 2005 and April 2006.

Greater role for Atlantic inflows on sea-ice loss in the Eurasian Basin of the Arctic Ocean

Losing its character The eastern Eurasian Basin of the Arctic Ocean is on the far side of the North Pole from the Atlantic, but it is becoming more like its larger neighbor as the climate warms. Polyakov et al. show that this region is also evolving toward a state of weakened stratification with increased vertical mixing, release of oceanic heat, and less sea ice. These changes could have considerable impacts on other geophysical and biogeochemical aspects of the Arctic Ocean system and presage a fundamentally new Arctic climate state. Science, this issue p. 285 The eastern Arctic Ocean is becoming more like the Atlantic as climate changes. Arctic sea-ice loss is a leading indicator of climate change and can be attributed, in large part, to atmospheric forcing. Here, we show that recent ice reductions, weakening of the halocline, and shoaling of the intermediate-depth Atlantic Water layer in the eastern Eurasian Basin have increased winter ventilation in the ocean interior, making this region structurally similar to that of the western Eurasian Basin. The associated enhanced release of oceanic heat has reduced winter sea-ice formation at a rate now comparable to losses from atmospheric thermodynamic forcing, thus explaining the recent reduction in sea-ice cover in the eastern Eurasian Basin. This encroaching “atlantification” of the Eurasian Basin represents an essential step toward a new Arctic climate state, with a substantially greater role for Atlantic inflows.

Winter Convection Transports Atlantic Water Heat to the Surface Layer in the Eastern Arctic Ocean

A 1-yr (2009/10) record of temperature and salinity profiles from Ice-Tethered Profiler (ITP) buoys in the Eurasian Basin (EB) of the Arctic Ocean is used to quantify the flux of heat from the upper pycnocline to the surface mixed layer. The upper pycnocline in the central EB is fed by the upward flux of heat from the intermediate-depth(;150‐900m)AtlanticWater(AW)layer;thisfluxisestimatedtobe;1Wm 22 averaged over one year. Release of heat from the upper pycnocline, through the cold halocline layer to the surface mixed layer is, however, seasonally intensified, occurring more strongly in winter. This seasonal heat loss averages ;3‐4Wm 22 between January and April, reducing the rate of winter sea ice formation. This study hypothesizes that the winter heat loss is driven by mixing caused by a combination of brine-driven convection associated with sea ice formation and larger vertical velocity shear below the base of the surface mixed layer (SML), enhanced by atmospheric storms and the seasonal reduction in density difference between the SML and underlying pycnocline.

Radium Isotopes Across the Arctic Ocean Show Time Scales of Water Mass Ventilation and Increasing Shelf Inputs

The first full transarctic section of 228Ra in surface waters measured during GEOTRACES cruises PS94 and HLY1502 (2015) shows a consistent distribution with maximum activities in the Transpolar Drift. Activities in the central Arctic have increased from 2007 through 2011 to 2015. The increased 228Ra input is attributed to stronger wave action on shelves resulting from a longer ice‐free season. A concomitant decrease in the 228Th/228Ra ratio likely results from more rapid transit of surface waters depleted in 228Th by scavenging over the shelf. The 228Ra activities observed in intermediate waters (< 1500m) in the Amundsen Basin are explained by ventilation with shelf water on a time scale of about 15‐18 years, in good agreement with estimates based on SF6 and 129I/236U. The 228Th excess below the mixed layer up to 1500m depth can complement 234Th and 210Po as tracers of export production, after correction for the inherent excess resulting from the similarity of 228Ra and 228Th decay times. We show with a Th/Ra profile model that the 228Th/228Ra ratio below 1500m is inappropriate for this purpose because it is a delicate balance between horizontal supply of 228Ra and vertical flux of particulate 228Th. The accumulation of 226Ra in the deep Makarov Basin is not associated with an accumulation of Ba and can therefore be attributed to supply from decay of 230Th in the bottom sediment. We estimate a ventilation time of 480 years for the deep Makarov‐Canada Basin, in good agreement with previous estimates using other tracers.

Heat, salt, and volume transports in the eastern Eurasian Basin ofthe Arctic Ocean, from two years of mooring observations

Abstract. This study discusses along-slope volume, heat, and salt transports derived from observations collected in 2013–15 using a cross-slope array of six moorings ranging from 250 m to 3900 m in the eastern Eurasian Basin (EB) of the Arctic Ocean. These observations demonstrate that in the upper 780 m layer, the along-slope boundary current advected, on average, 5.1 ± 0.1 Sv of water, predominantly in the eastward (shallow-to-right) direction. Monthly net volume transports across the Laptev Sea slope vary widely, from ~ 0.3 ± 0.8 in April 2014 to ~ 9.9 ± 0.8 Sv in June 2014. 3.1 ± 0.1 Sv (or 60 %) of the net transport was associated with warm and salty intermediate-depth Atlantic Water (AW). Calculated heat transport for 2013–15 (relative to −1.8 °C) was 46.0 ± 1.7 TW, and net salt transport (relative to zero salinity) was 172 ± 6 Mkg/s. Estimates for AW heat and salt transports were 32.7 ± 1.3 TW (71 % of net heat transport) and 112 ± 4 Mkg/s (65 % of net salt transport). The variability of currents explains ~ 90 % of the variability of the heat and salt transports. The remaining ~ 10 % is controlled by temperature and salinity anomalies together with temporal variability of the AW layer thickness. The annual mean volume transports decreased by 25 % from 5.8 ± 0.2 Sv in 2013–14 to 4.4 ± 0.2 Sv in 2014–15 suggesting that changes of the transports at interannual and longer time scales in the eastern EB may be significant.

On the Seasonal Cycles Observed at the Continental Slope of the Eastern Eurasian Basin of the Arctic Ocean

AbstractThe Eurasian Basin (EB) of the Arctic Ocean is subject to substantial seasonality. We here use data collected between 2013 and 2015 from six moorings across the continental slope in the eas...

Inter-laboratory study for the certification of trace elements in seawater certified reference materials NASS-7 and CASS-6

Certification of trace metals in seawater certified reference materials (CRMs) NASS-7 and CASS-6 is described. At the National Research Council Canada (NRC), column separation was performed to remove the seawater matrix prior to the determination of Cd, Cr, Cu, Fe, Pb, Mn, Mo, Ni, U, V, and Zn, whereas As was directly measured in 10-fold diluted seawater samples, and B was directly measured in 200-fold diluted seawater samples. High-resolution inductively coupled plasma mass spectrometry (HR-ICPMS) was used for elemental analyses, with double isotope dilution for the accurate determination of B, Cd, Cr, Cu, Fe, Pb, Mo, Ni, U, and Zn in seawater NASS-7 and CASS-6, and standard addition calibration for As, Co, Mn, and V. In addition, all analytes were measured using standard addition calibration with triple quadrupole (QQQ)-ICPMS to provide a second set of data at NRC. Expert laboratories worldwide were invited to contribute data to the certification of trace metals in NASS-7 and CASS-6. Various analytical methods were employed by participants including column separation, co-precipitation, and simple dilution coupled to ICPMS detection or flow injection analysis coupled to chemiluminescence detection, with use of double isotope dilution calibration, matrix matching external calibration, and standard addition calibration. Results presented in this study show that majority of laboratories have demonstrated their measurement capabilities for the accurate determination of trace metals in seawater. As a result of this comparison, certified/reference values and associated uncertainties were assigned for 14 elements in seawater CRMs NASS-7 and CASS-6, suitable for the validation of methods used for seawater analysis.