Robert S. Whitney

Most efficient quantum thermoelectric at finite power output.

Machines are only Carnot efficient if they are reversible, but then their power output is vanishingly small. Here we ask, what is the maximum efficiency of an irreversible device with finite power output? We use a nonlinear scattering theory to answer this question for thermoelectric quantum systems, heat engines or refrigerators consisting of nanostructures or molecules that exhibit a Peltier effect. We find that quantum mechanics places an upper bound on both power output and on the efficiency at any finite power. The upper bound on efficiency equals Carnot efficiency at zero power output but decays with increasing power output. It is intrinsically quantum (wavelength dependent), unlike Carnot efficiency. This maximum efficiency occurs when the system lets through all particles in a certain energy window, but none at other energies. A physical implementation of this is discussed, as is the suppression of efficiency by a phonon heat flow.

Fundamental aspects of steady-state conversion of heat to work at the nanoscale

In recent years, the study of heat to work conversion has been re-invigorated by nanotechnology. Steady-state devices do this conversion without any macroscopic moving parts, through steady-state flows of microscopic particles such as electrons, photons, phonons, etc. This review aims to introduce some of the theories used to describe these steady-state flows in a variety of mesoscopic or nanoscale systems. These theories are introduced in the context of idealized machines which convert heat into electrical power (heat-engines) or convert electrical power into a heat flow (refrigerators). In this sense, the machines could be categorized as thermoelectrics, although this should be understood to include photovoltaics when the heat source is the sun. As quantum mechanics is important for most such machines, they fall into the field of quantum thermodynamics. In many cases, the machines we consider have few degrees of freedom, however the reservoirs of heat and work that they interact with are assumed to be macroscopic. This review discusses different theories which can take into account different aspects of mesoscopic and nanoscale physics, such as coherent quantum transport, magnetic-field induced effects (including topological ones such as the quantum Hall effect), and single electron charging effects. It discusses the efficiency of thermoelectric conversion, and the thermoelectric figure of merit. More specifically, the theories presented are (i) linear response theory with or without magnetic fields, (ii) Landauer scattering theory in the linear response regime and far from equilibrium, (iii) Green-Kubo formula for strongly interacting systems within the linear response regime, (iv) rate equation analysis for small quantum machines with or without ..... (SEE THE PDF FOR THE REST OF THIS ABSTRACT)

Geometric Nature of the Environment-Induced Berry Phase and Geometric Dephasing

We investigate the geometric phase or Berry phase acquired by a spin half which is both subject to a slowly varying magnetic field and weakly coupled to a dissipative environment (either quantum or classical). We study how this phase is modified by the environment and find that the modification is of a geometric nature. While the original Berry phase (for an isolated system) is the flux of a monopole field through the loop traversed by the magnetic field, the environment-induced modification of the phase is the flux of a quadrupolelike field. We find that the environment-induced phase is complex, and its imaginary part is a geometric contribution to dephasing. Its sign depends on the direction of the loop. Unlike the Berry phase, this geometric dephasing is gauge invariant for open paths of the magnetic field.

Berry phase in a nonisolated system.

We investigate the effect of the environment on a Berry phase measurement involving a spin-half. We model the spin + environment using a biased spin-boson Hamiltonian with a time-dependent magnetic field. We find that, contrary to naive expectations, the Berry phase acquired by the spin can be observed, but only on time scales which are neither too short nor very long. However this Berry phase is not the same as for the isolated spin-half. It does not have a simple geometric interpretation in terms of the adiabatic evolution of either bare spin states or the dressed spin resonances. This result is crucial for proposed Berry phase measurements in superconducting nanocircuits.

Finding the quantum thermoelectric with maximal efficiency and minimal entropy production at given power output

We investigate the nonlinear scattering theory for quantum systems with strong Seebeck and Peltier effects, and consider their use as heat engines and refrigerators with finite power outputs. This paper gives detailed derivations of the results summarized in a previous paper [R. S. Whitney, Phys. Rev. Lett. 112, 130601 (2014)]. It shows how to use the scattering theory to find (i) the quantum thermoelectric with maximum possible power output, and (ii) the quantum thermoelectric with maximum efficiency at given power output. The latter corresponds to a minimal entropy production at that power output. These quantities are of quantum origin since they depend on system size over electronic wavelength, and so have no analog in classical thermodynamics. The maximal efficiency coincides with Carnot efficiency at zero power output, but decreases with increasing power output. This gives a fundamental lower bound on entropy production, which means that reversibility (in the thermodynamic sense) is impossible for finite power output. The suppression of efficiency by (nonlinear) phonon and photon effects is addressed in detail; when these effects are strong, maximum efficiency coincides with maximum power. Finally, we show in particular limits (typically without magnetic fields) that relaxation within the quantum system does not allow the system to exceed the bounds derived for relaxation-free systems, however, a general proof of this remains elusive.

Onsager relations in coupled electric, thermoelectric, and spin transport: The tenfold way

Hamiltonian systems can be classified into ten classes, in terms of the presence or absence of time-reversal symmetry, particle-hole symmetry and sublattice/chiral symmetry. We construct a quantum coherent scattering theory of linear transport for coupled electric, heat and spin transport; including the effect of Andreev reflection from superconductors. We derive a complete list of the Onsager reciprocity relations between transport coefficients for coupled electric, spin, thermoelectric and spin caloritronic effects. We apply these to all ten symmetry classes, paying special attention to specific additional relations that follow from the combination of symmetries, beyond microreversibility. We discuss these relations in several illustrative situations. We show the reciprocity between spin-Hall and inverse spin-Hall effects, and the reciprocity between spin-injection and magnetoelectric spin currents. We discuss the symmetry and reciprocity relations of Seebeck, Peltier, spin-Seebeck and spin-Peltier effects in systems with and without coupling to superconductors.

Form factor for a family of quantum graphs: an expansion to third order

For certain types of quantum graphs we show that the random matrix form factor can be recovered to at least third order in the scaled time τ from periodic-orbit theory. We consider the contributions from pairs of periodic orbits represented by diagrams with up to two self-intersections connected by up to four arcs and explain why all other diagrams are expected to give higher-order corrections only. For a large family of graphs with ergodic classical dynamics the diagrams that exist in the absence of time-reversal symmetry sum to zero. The mechanism for this cancellation is rather general which suggests that it also applies at higher orders in the expansion. This expectation is in full agreement with the fact that in this case the linear-τ contribution, the diagonal approximation, already reproduces the random matrix form factor for τ < 1. For systems with time-reversal symmetry there are more diagrams which contribute at third order. We sum these contributions for quantum graphs with uniformly hyperbolic dynamics, obtaining +2τ3, in agreement with random matrix theory. As in the previous calculation of the leading-order correction to the diagonal approximation we find that the third-order contribution can be attributed to exceptional orbits representing the intersection of diagram classes.

Leading off-diagonal correction to the form factor of large graphs

Using periodic-orbit theory beyond the diagonal approximation we investigate the form factor, K(tau), of a generic quantum graph with mixing classical dynamics and time-reversal symmetry. We calculate the contribution from pairs of self-intersecting orbits that differ from each other only in the orientation of a single loop. In the limit of large graphs, these pairs produce a contribution -2tau(2) to the form factor which agrees with random-matrix theory.

Nonlinear thermoelectricity in point contacts at pinch off: A catastrophe aids cooling

We consider refrigeration and heat engine circuits based on the nonlinear thermoelectric response of point-contacts at pinch-off, allowing for electrostatic interaction effects. We show that a refrigerator can cool to much lower temperatures than predicted by the thermoelectric figure-of-merit ZT (which is based on linear-response arguments). The lowest achievable temperature has a discontinuity, called a fold catastrophe in mathematics, at a critical driving current I=I_c. For I >I_c one can in principle cool to absolute zero, when for I<I_c the lowest temperature is about half the ambient temperature. Heat back-flow due to phonons and photons stop cooling at a temperature above absolute zero, and above a certain threshold turns the discontinuity into a sharp cusp. We also give a heuristic condition for when an arbitrary systems nonlinear response means that its ZT ceases to indicate (even qualitatively) the lowest temperature to which the system can refrigerate.

Huge Conductance Peak Caused by Symmetry in Double Quantum Dots

We predict a huge interference effect contributing to the conductance through large ultra-clean quantum dots of chaotic shape. When a double-dot structure is made such that the dots are the mirror-image of each other, constructive interference can make a tunnel barrier located on the symmetry axis effectively transparent. We show (via theoretical analysis and numerical simulation) that this effect can be orders of magnitude larger than the well-known universal conductance fluctuations and weak-localization (both less than a conductance quantum). A small magnetic field destroys the effect, massively reducing the double-dot conductance; thus a magnetic field detector is obtained, with a similar sensitivity to a SQUID, but requiring no superconductors.