Roger P. Kelly

Direct comparison of 210Po, 234Th and POC particle-size distributions and export fluxes at the Bermuda Atlantic Time―series Study (BATS) site

Particle-reactive, naturally occurring radionuclides are useful tracers of the sinking flux of organic matter from the surface to the deep ocean. Since the Joint Global Ocean Flux Study (JGOFS) began in 1987, the disequilibrium between (234)Th and its parent (238)U has become widely used as a technique to measure particle export fluxes from surface ocean waters. Another radionuclide pair, (210)Po and (210)Pb, can be used for the same purpose but has not been as widely adopted due to difficulty with accurately constraining the (210)Po/(210)Pb radiochemical balance in the ocean and because of the more time-consuming radiochemical procedures. Direct comparison of particle flux estimated in different ocean regions using these short-lived radionuclides is important in evaluating their utility and accuracy as tracers of particle flux. In this paper, we present paired (234)Th/(238)U and (210)Po/(210)Pb data from oligotrophic surface waters of the subtropical Northwest Atlantic and discuss their advantages and limitations. Vertical profiles of total and particle size-fractionated (210)Po and (234)Th activities, together with particulate organic carbon (POC) concentrations, were measured during three seasons at the Bermuda Atlantic Time-series Study (BATS) site. Both (210)Po and (234)Th reasonably predict sinking POC flux caught in sediment traps, and each tracer provides unique information about the magnitude and efficiency of the oceans biological pump.

Cross-shelf mixing and mid-shelf front dynamics in the Mid-Atlantic Bight evaluated using the radium quartet

Mid-shelf fronts (MSFs) are thought to be ubiquitous in shelf areas. However, their dynamical role in cross-shelf mixing has yet to be fully characterized. In January, February, and April of 2007, radium isotopes (223Ra, t1/2 = 11 d; 224Ra, t1/2 = 3.7 d; 226Ra, t1/2 = 1600 yr; 228Ra, t1/2 = 5.7 yr) were measured along a transect in the Mid-Atlantic Bight to constrain mixing rates at and around a MSF. Cross-shelf eddy diffusivities (Kx) were determined from 223Ra and 224Ra distributions using a variable-depth model. Two key assumptions – minimal advection and negligible benthic radium input – involving the use of 223Ra and 224Ra as tracers of mixing were quantitatively evaluated in order to assess the accuracy of the Kx estimates. Eddy diffusivities over the three-month sampling period range from 0.1 ± 0.05 − 1.6 ± 0.5 × 102 m2 s−1 for 223Ra and from 1.7 ± 0.4 − 2.2 ± 0.6 × 102 m2 s−1 for 224Ra. The temporal variability in Kx is low in comparison to the uncertainty of the derived values, indicating that eddy diffusivity in this area is relatively constant throughout the sampling period. Observations in the Mid-Atlantic Bight differ from theoretical data corresponding to the tidal dispersion frontogenesis model, suggesting that a different mechanism is responsible for MSF formation. Variability in supported 223Ra and 228Ra observed near the front indicates that cross-shelf mixing may be inhibited by MSFs. Conversely, along-shelf transport is enhanced by the front’s presence. These results indicate that the equatorward jet associated with the front is capable of effectively transporting dissolved chemicals over hundreds of kilometers.

How well does wind speed predict air‐sea gas transfer in the sea ice zone? A synthesis of radon deficit profiles in the upper water column of the Arctic Ocean

We present 34 profiles of radon-deficit from the ice-ocean boundary layer of the Beaufort Sea. Including these 34, there are presently 58 published radon-deficit estimates of k, the air-sea gas transfer velocity in the Arctic Ocean; 52 of these estimates were derived from water covered by 10% sea ice or more. The average value of k collected since 2011 is 4.0 ± 1.2 m d−1 This exceeds the quadratic wind speed prediction of weighted kws = 2.85 m d−1 with mean weighted wind speed of 6.4 m s−1. We show how ice cover changes the mixed-layer radon budget, and yields an “effective gas transfer velocity”. We use these 58 estimates to statistically evaluate the suitability of a wind speed parameterization for k, when the ocean surface is ice covered. Whereas the six profiles taken from the open ocean indicate a statistically good fit to wind speed parameterizations, the same parameterizations could not reproduce k from the sea ice zone. We conclude that techniques for estimating k in the open ocean cannot be similarly applied to determine k in the presence of sea ice. The magnitude of k through gaps in the ice may reach high values as ice cover increases, possibly as a result of focused turbulence dissipation at openings in the free surface. These 58 profiles are presently the most complete set of estimates of k across seasons and variable ice cover; as dissolved tracer budgets they reflect air-sea gas exchange with no impact from air-ice gas exchange.