Rongfei Wei

PVP-Assisted Solvothermal Synthesis of High-Yielded Bi2Te3 Hexagonal Nanoplates: Application in Passively Q-Switched Fiber Laser.

High-yielded Bi2Te3 hexagonal nanoplates were fabricated via a facile solvothermal method with the assistance of poly (vinyl pyrrolidone) (PVP). Effects of PVP molecular weight and concentration on the morphology and size distribution of the products were illustrated in this study. Molecular weight of PVP is significant for determining the morphology of Bi2Te3. The hexagonal nanoplates with high yield were obtained in the presence of PVP with molecular weight of 40000–45000. The average size and size distribution of Bi2Te3 nanoplates can be slightly varied by controlling concentration of PVP. High-yielded Bi2Te3 nanoplates exhibit characteristics of saturable absorption, identified by open-aperture Z-scan technique. The synthesized Bi2Te3 nanoplates with large saturation intensity of 4.6 GW/cm2 and high modulation depth of 45.95% generated a stable passively Q-switched fiber laser pulse at 1.5 μm. In comparison with recently reported Q-switched fiber lasers utilizing exfoliated Bi2Te3 nanosheets, our passive Q-switching operations could be conducted at a relatively low threshold power of 30.2 mW or a quite high output power of 99.45 mW by tuning the cavity parameters.

Ultrafast saturable absorption in topological insulator Bi 2 SeTe 2 nanosheets

Topological insulator (TI) Bi2SeTe2 nanosheets with very regular hexagonal morphology were synthesized by a hydrothermal route. Open aperture (OA) z-scan method was performed to measure the saturable absorption (SA) characteristics of the as-prepared TI Bi2SeTe2 nanosheets. The measured modulation depth, saturation intensity and nonsaturable loss of the sample were 61.9%, 4.46 GW/cm2 and 4.5% respectively. An ultrafast intraband scattering time of ~50 fs was obtained through simulating the SA curve, which indicates the TI Bi2SeTe2 nanosheets may be a good candidate for mode-locking material.

Versatile preparation of ultrathin MoS 2 nanosheets with reverse saturable absorption response

High-yielded ultrathin MoS2 nanosheets (UMS) with thickness below 4 nm were successfully synthesized by a simple, cost-effective and reproducible solid-state reaction method. Significant reverse saturable absorption and nonlinear refraction responses of the UMS were measured by the z-scan experiment under femtosecond pulses at 800 nm. The figure of merit is calculated to be ~2.52 × 10−15 esu cm. Furthermore, optical limiting (OL) effects of the UMS were observed with low threshold FOL ~44 mJ/cm2. These results reveal that solid-state reaction is a feasible method for the fabrication of optical nanomaterials used in nanophotonic devices including optical limiter, which can be expanded to prepare other two-dimensional nanomaterials.

Ultra-broadband nonlinear saturable absorption of high-yield MoS2 nanosheets

High-yield MoS2 nanosheets with strong nonlinear optical (NLO) responses in a broad near-infrared range were synthesized by a facile hydrothermal method. The observation of saturable absorption, which was excited by the light with photon energy smaller than the gap energy of MoS2, can be attributed to the enhancement of the hybridization between the Mo d-orbital and S p-orbital by the oxygen incorporation into MoS2. High-yield MoS2 nanosheets with high modulation depth and large saturable intensity generated a stable, passively Q-switched fiber laser pulse at 1.56 μm. The high output power of 1.08 mW can be attained under a very low pump power of 30.87 mW. Compared to recently reported passively Q-switched fiber lasers utilizing exfoliated MoS2 nanosheets, the efficiency of the laser for our passive Q-switching operation is larger and reaches 3.50%. This research may extend the understanding on the NLO properties of MoS2 and indicate the feasibility of the high-yield MoS2 nanosheets to passively Q-switched fiber laser effectively at low pump strengths.

Vertically standing layered MoS 2 nanosheets on TiO 2 nanofibers for enhanced nonlinear optical property

Vertical layered MoS₂ nanosheets rooting into TiO₂ nanofibers were successfully prepared by a facile two-step method: prefabrication of porous TiO₂ nanofibers based on an electrospinning technique, and assembly of MoS₂ ultrathin nanosheets through a simple hydrothermal reaction. Significant enhancement of nonlinear optical response of the MoS₂/TiO₂ nanocomposite was confirmed by an open-aperture z-scan measurement. The nanocomposite displayed strong optical limiting (OL) effects to ultrafast laser pulses with a low OL threshold of ~22.3 mJ/cm², which is lower than that of pristine TiO₂ nanofibers and MoS₂ nanosheets. In addition to the contribution of the strong nonlinear absorption of MoS₂ nanosheets and TiO₂ nanofibers, such phenomenon is also attributed to the unique structure of vertically standing layered MoS₂ nanosheets on TiO₂ nanofibers with a large amount of exposed edge states, large surface areas and fast electron transfer between TiO₂ and MoS₂. This work broadens our vision to engineering novel hierarchical MoS₂-based nanocomposite for efficiently enhanced nonlinear light-matter interaction.

Enhanced nonlinear optical response of Se-doped MoS2 nanosheets for passively Q-switched fiber laser application

An enhanced nonlinear optical (NLO) performance was observed in Se-doped MoS2 nanosheets synthesized through a facile annealing process. Se-doped MoS2 nanosheets with a large saturable intensity and high modulation depth generated stable passively Q-switched fiber laser pulses at 1559 nm. In comparison with the Q-switched fiber laser utilizing the pristine MoS2 nanosheets as a saturable absorber, the passive Q-switching operation based on Se-doped MoS2 nanosheets could be conducted at a lower threshold power of 50 mW, a wider range of repetition rates from 28.97 to 130 kHz, and a higher SNR of 56 dB. More importantly, the shortest pulse duration of 1.502 μs was realized and the output power and pulse energy reached 17.2 mW and 133.07 nJ, respectively. These results indicate that tailoring the chemical composition of optical nanomaterials by introducing a dopant is a feasible method of improving the NLO response of the MoS2 nanosheets and realizing excellent ultrafast pulse generation.