Rongzhong Wang

Precipitation, adsorption and rhizosphere effect: The mechanisms for Phosphate-induced Pb immobilization in soils—A review

Lead (Pb) is one of the most toxic heavy metals that pose a direct threat to organisms and it can not been degraded through microbial activities or chemical reaction. Bioavaibility and eco-toxicity of Pb which mostly depend on Pb chemical speciation play an important role in the remediation of Pb-contaminated soils. Phosphate (P) amendments which could transfer Pb from unstable fraction to stable fraction are commonly used to immobilize Pb in soils and have been extensively studied by researchers during decades. Based on the previous study, it can be concluded that three principal mechanisms may be responsible for P-induced Pb immobilization: 1) the precipitation of Pb-phosphates, including direct precipitation, ion-exchange (or substitution) effect and liming effect; 2) the adsorption of Pb, including the direct adsorption and the adsorption of Pb to iron (hydr)oxides; 3) the rhizosphere effect, including acidification effect and mycorrhizae effect. In this review, these mechanisms have been completely discussed and the internal relationships among them were summarized to give a better understanding of P-induced Pb immobilization in soils and promote the development of P-based remediation technology.

Application of molecularly imprinted polymers in wastewater treatment: a review

Molecularly imprinted polymers are synthetic polymers possessing specific cavities designed for target molecules. They are prepared by copolymerization of a cross-linking agent with the complex formed from a template and monomers that have functional groups specifically interacting with the template through covalent or noncovalent bonds. Subsequent removal of the imprint template leaves specific cavities whose shape, size, and functional groups are complementary to the template molecule. Because of their predetermined selectivity, molecularly imprinted polymers (MIPs) can be used as ideal materials in wastewater treatment. Especially, MIP-based composites offer a wide range of potentialities in wastewater treatment. This paper reviews the latest applications of MIPs in wastewater treatment, highlights the development of MIP-based composites in wastewater, and offers suggestions for future success in the field of MIPs.

Combination of Fenton processes and biotreatment for wastewater treatment and soil remediation.

There is a continuously increasing worldwide concern for the development of wastewater and contaminated soil treatment technologies. Fenton processes and biological treatments have long been used as common technologies for treating wastewater and polluted soil but they still need to be modified because of some defects (high costs of Fenton process and long remediation time of biotreatments). This work first briefly introduced the Fenton technology and biotreatment, and then discussed the main considerations in the construction of a combined system. This review shows a critical overview of recent researches combining Fenton processes (as pre-treatment or post-treatment) with bioremediation for treatment of wastewater or polluted soil. We concluded that the combined treatment can be regarded as a novel and competitive technology. Furthermore, the outlook for potential applications of this combination in different polluted soil and wastewater, as well as the mechanism of combination was also discussed.

Stabilized Nanoscale Zerovalent Iron Mediated Cadmium Accumulation and Oxidative Damage of Boehmeria nivea (L.) Gaudich Cultivated in Cadmium Contaminated Sediments

Nanoparticles can be absorbed by plants, but their impacts on phytoremediation are not yet well understood. This study was carried out to determine the impacts of starch stabilized nanoscale zerovalent iron (S-nZVI) on the cadmium (Cd) accumulation and the oxidative stress in Boehmeria nivea (L.) Gaudich (ramie). Plants were cultivated in Cd-contaminated sediments amended with S-nZVI at 100, 500, and 1000 mg/kg, respectively. Results showed that S-nZVI promoted Cd accumulation in ramie seedlings. The subcellular distribution result showed that Cd content in cell wall of plants reduced, and its concentration in cell organelle and soluble fractions increased at S-nZVI treatments, indicating the promotion of Cd entering plant cells by S-nZVI. In addition, the 100 mg/kg S-nZVI alleviated the oxidative damage to ramie under Cd-stress, while 500 and 1000 mg/kg S-nZVI inhibited plant growth and aggravated the oxidative damage to plants. These findings demonstrate that nanoparticles at low concentration can improve the efficiency of phytoremediation. This study herein develops a promising novel technique by the combined use of nanotechnology and phytoremediation in the remediation of heavy metal contaminated sites.

Composting of 4-nonylphenol-contaminated river sediment with inocula of Phanerochaete chrysosporium.

A composting study was performed to investigate the degradation of 4-nonylphenol (4-NP) in river sediment by inoculating Phanerochaete chrysosporium (Pc). Pc was inoculated into composting Reactor A, C and D, while Reactor B without inocula was used as control. The results showed that composting with Pc accelerated the degradation of 4-NP, increased the catalase and polyphenol oxidase enzyme activities in contaminated sediment. The dissipation half-life (t1/2) of 4-NP in Reactor A, C and D with inocula of Pc were 2.079, 2.558, 2.424days, while in Reactor B without inocula of Pc it was 3.239days, respectively. Correlation analysis showed that the contents of 4-NP in sediment in Reactor A and D were negatively correlated with the actives of laccase, whereas no obvious correlation was observed in Reactor B and C. All these findings also indicated that Pc enhanced the maturity of compost, and the best composting C/N ratio was 25.46:1.

Selective removal of BPA from aqueous solution using molecularly imprinted polymers based on magnetic graphene oxide

Bisphenol A (BPA) is a chemical with the potential to cause estrogenic and genotoxic effects on humans and wildlife. In this study, a novel and quick method was employed for selective removal of BPA from aqueous solutions, which used magnetic graphene oxide-based molecularly imprinted polymers as the adsorbent. Adsorption experiments were carried out to examine the effect of pH, initial concentration of BPA, isotherms and sorption kinetics on the adsorption of BPA by magnetic molecularly imprinted polymers (MMIPs). Results revealed the maximum adsorption capacity of BPA by MMIPs was 106.38 mg g−1 at 298 K and the equilibrium data of MMIPs were described well by a Langmuir isotherm model. Furthermore, the sorption kinetics followed the pseudo-second-order equation, which indicated that the chemical process might be the rate limiting step in the adsorption process for BPA. In addition, selective binding experiments were performed using 2,4-dichlorophenol and phenol as competitive compounds, and the resulting selectivity coefficients for the experiment were 2.505 and 2.440, respectively. All these results revealed that the prepared MMIPs had good selectivity and effective adsorption for BPA.

High adsorption of methylene blue by salicylic acid–methanol modified steel converter slag and evaluation of its mechanism

A novel adsorbent based on steel converter slag (SCS), useful for adsorbing cationic pollutants from water was prepared by a simple method. The characterization showed that salicylic acid-methanol (SAM) modification selectively removed calcium silicate minerals from the surface of SCS and lead to a prominent increase in the specific surface areas. The maximum adsorption capacity of SAM-modified SCS for methylene blue (MB) at initial pH of 7.0 and temperature of 293 K was 41.62 mg/g, which is 35.2-times higher than that of SCS (1.15 mg/g). Adsorption kinetics and isotherms of MB on the SAM-modified SCS can be satisfactorily fitted by pseudo-second order kinetic and Langmuir model, respectively, which suggest that single-layer chemical adsorption was mainly responsible for MB removal. Further studies showed that pH value and ionic strength of wastewater have minimal effects on the adsorption capacity of SAM-modified SCS. A small decrease (<10%) was found in the adsorption capacity of SAM-modified SCS after five cycles. These findings indicate that SAM-modified SCS is a promising adsorbent for the efficient removal of MB from aqueous solution due to its low cost, good thermal stability, excellent adsorption performance and simple separation.

Remediation of contaminated soils by biotechnology with nanomaterials: bio-behavior, applications, and perspectives

Abstract Soil contamination caused by heavy metals and organic pollutants has drawn world-wide concern. Biotechnology has been applied for many years to the decontamination of soils polluted with organic and inorganic contaminants, and novel nanomaterials (NMs) has attracted much concern due to their high capacity for the removal/stabilization/degradation of pollutants. Recently, developing advanced biotechnology with NMs for the remediation of contaminated soils has become a hot research topic. Some researchers found that bioremediation efficiency of contaminated soils was enhanced by the addition of NMs, while others demonstrated that the toxicity of NMs to the organism negatively influenced the repair capacity of polluted soils. This paper reviews the application of biotechnology and NMs in soil remediation, and further provides a critical view of the effects of NMs on the phytoremediation and micro-remediation of contaminated soils. This review also discusses the future research needs for the combined application of biotechnology and NMs in soil remediation.

Sorptive removal of ionizable antibiotic sulfamethazine from aqueous solution by graphene oxide-coated biochar nanocomposites: Influencing factors and mechanism

Significant concerns have been raised over antibiotics pollution in aquatic environments in recent years. In this study, sorption of sulfamethazine (SMT) by novel graphene oxide-coated biochar nanocomposites (GO-BC) based on graphene oxide (GO) with bamboo sawdust biochar (BC) was investigated. In comparison with the original BC, the sorption capacity of GO-BC for SMT increased by 1.14 times. Sorption of SMT onto GO-BC was proved to be dominantly by chemisorption, and Freundlich isotherm described the sorption adequately. It was found that variation of pH and ionic strength obviously affected the sorption of SMT, and GO-BC had a good sorption effect on SMT at pH 3.0-6.0 and lower ionic strength. Obvious enhancement (by 30%) in sorption of SMT on GO-BC was observed, which might be attributed to the increase of functional groups on the surface of GO-BC. Moreover, the main sorption mechanism for SMT was π-π electron-donor-acceptor interaction, while auxiliary sorption mechanisms were inferred as pore-filling, cation exchange, hydrogen bonding interaction and electrostatic interaction. The results indicated that GO-BC sorption was an efficient way for the removal of SMT.

Pyrolysis and reutilization of plant residues after phytoremediation of heavy metals contaminated sediments: For heavy metals stabilization and dye adsorption

This study aimed to investigate the effect of pyrolysis on the stabilization of heavy metals in plant residues obtained after phytoremediation. Ramie residues, being collected after phytoremediation of metal contaminated sediments, were pyrolyzed at different temperatures (300-700 °C). Results indicated that pyrolysis was effective in the stabilization of Cd, Cr, Zn, Cu, and Pb in ramie residues by converting the acid-soluble fraction of metals into residual form and decreasing the TCLP-leachable metal contents. Meanwhile, the reutilization potential of using the pyrolysis products generated from ramie residues obtained after phytoremediation as sorbents was investigated. Adsorption experiments results revealed that the pyrolysis products presented excellent ability to adsorb methylene blue (MB) with a maximum adsorption capacity of 259.27 mg/g. This study demonstrated that pyrolysis could be used as an efficient alternative method for stabilizing heavy metals in plant residues obtained after phytoremediation, and their pyrolysis products could be reutilized for dye adsorption.