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Dive into the research topics where Rosana C. L. Pereira is active.

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Featured researches published by Rosana C. L. Pereira.


Analytical Chemistry | 2010

Petroleomics by EASI(±) FT-ICR MS

Yuri E. Corilo; Boniek G. Vaz; Rosineide C. Simas; Heliara D. Lopes Nascimento; Clécio F. Klitzke; Rosana C. L. Pereira; Wagner L. Bastos; Eugênio V. Santos Neto; Ryan P. Rodgers; Marcos N. Eberlin

An ambient ionization/desorption technique, namely, easy ambient sonic-spray ionization mass spectrometry (EASI), has been applied to crude oil samples. From a single droplet of the sample placed on an inert surface, EASI(+/-) is shown to promote efficient desorption and ionization of a myriad of polar components via the action of its cloud of very minute supersonic bipolar charged droplets. The gaseous [M + H](+) and [M - H](-) ions concurrently formed by EASI(+/-) were analyzed by Fourier transform mass spectrometry (FT-ICR MS), and a total of approximately 6000 acidic and basic components have been attributed. EASI(+/-) FT-ICR MS of crude oils is show to be almost as fast as ESI(+)/ESI(-) FT-ICR MS, providing similar compositional information of polar components and spectral quality comparable to that of a commercial nonochip-based robotic ESI device. EASI(+/-) requires no sample workup thus eliminating risks of contamination during sample manipulation and memory effects because of carry over in pumping ESI lines. More importantly, EASI(+/-) is a voltage-free ionization technique therefore eliminating risks of redox processes or duality of ionization mechanisms that can be observed in voltage-assisted processes. Data visualization via typical petroleomic plots confirms the similarity of the compositional information provided by EASI(+/-) compared to ESI(+)/ESI(-). The ambient EASI(+/-) FT-ICR MS method requires no voltage switching in changing the ion polarity mode, offering a workup, heating and voltage-free protocol for petroleomic studies performed at open atmosphere directly on the undisturbed crude oil sample.


international conference on european electricity market | 2008

Multi-agent simulation of generation capacity expansion decisions

Audun Botterud; Matthew Mahalik; Guenter Conzelmann; R. Figueiredo Silva; S. Vilela; Rosana C. L. Pereira

In this paper, we use a multi-agent simulation model, EMCAS, to analyze generation expansion in the Iberian electricity market. The expansion model simulates generation investment decisions of decentralized generating companies (GenCos) interacting in a complex, multidimensional environment. A probabilistic dispatch algorithm calculates prices and profits for new candidate units in different future states of the system. Uncertainties in future load, hydropower conditions, and competitorspsila actions are represented in a scenario tree, and decision analysis is used to identify the optimal expansion decision for each individual GenCo. We run the model using detailed data for the Iberian market. In a scenario analysis, we look at the impact of market design variables, such as the energy price cap and carbon emission prices. We also analyze how market concentration and GenCospsila risk preferences influence the timing and choice of new generating capacity.


Journal of the Brazilian Chemical Society | 2017

Prediction of Total Acid Number in Distillation Cuts of Crude Oil by ESI(−) FT‑ICR MS Coupled with Chemometric Tools

Luciana A. Terra; Paulo R. Filgueiras; Rosana C. L. Pereira; Alexandre O. Gomes; Géssica A. Vasconcelos; Lilian V. Tose; Eustáquio V.R. Castro; Boniek G. Vaz; Wanderson Romão; Ronei J. Poppi

Competitive adaptive reweighted sampling-partial least squares (CARS-PLS) and negative-ion mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI(−) FT-ICR MS) data were adopted to assess the total acid number (TAN) of crude oil distillation cuts. Two crude oil samples and 24 derivatives with TAN ranging from 0.20 to 0.39 mg of KOH g were investigated. The multivariate calibration PLS model was built with 18 calibration samples and tested with 8 validation samples. CARS-PLS reduced the number of variables from 1610 to only 4, allowing the identification of molecular formulas that are truly related to the TAN. The root mean square error of prediction (RMSEP) obtained was 0.01 mg of KOH g, which is lower than the error when using all variables (0.03 mg of KOH g). Finally, it was observed that the N and O2 compound classes are the most important classes for providing a better correlation between ESI(−) FT-ICR mass spectra and TAN values.


Journal of Astm International | 2010

Determination of Ester Content in Different Kinds of Biodiesel

Fátima Regina Dutra Faria; Klaire O. Cerqueira; Glaucia P. Leal; Rosana C. L. Pereira; Manoel J. R. Guimar~aes Neto

Since the beginning of the Brazilian National Program of Production and Use of Biodiesel, Petrobras Research Center has been working in the evaluation of several raw materials for biodiesel production. Soybean, castor oil, animal fat, palm oil, and other raw materials have been studied. In Brazil, international methodologies have been used to analyze biodiesel samples. The existing international methods are not applicable to biodiesel samples from all sources. Due to the variety of existing raw materials in the country, it was necessary to develop a method for the determination of total ester content of biodiesel from any source, including animal fat, castor oil, palm, coconut, and others. A new Brazilian standard method, ABNT NBR 15764:2009 [1], was developed using gas chromatography and a mixture of esters as an external standard.


RSC Advances | 2018

Petroleomics via Orbitrap mass spectrometry with resolving power above 1 000 000 at m/z 200

Eduardo Morgado Schmidt; Marcos A. Pudenzi; Jandyson M. Santos; Célio Fernando Figueiredo Angolini; Rosana C. L. Pereira; Ygor dos Santos Rocha; Eduard Denisov; Eugen Damoc; Alexander Makarov; Marcos N. Eberlin

The performance of the high-field MegaOrbitrap Fourier transform mass spectrometer (FT-MS) with electrospray ionization (ESI) was evaluated to perform petroleum sample characterization via classical petroleomics approaches. Pertinent parameters that underpin the main figures of merit, that is, signal to noise ratios, dynamic range, spectral error, scan speed, mass accuracy and mass resolving power = Rp, and provide subsidies to develop these analyzers were tested. Comparisons are made with data obtained using the most common petroleomics instrument, which is a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS), that has been used in the last decade in our laboratory for crude oil analysis providing Rp of 340 000 at m/z 400 with transients of 3 s duration, and has been extensively demonstrated to fulfill all major requirements for precise petroleomics investigations. The high-field compact MegaOrbitrap mass analyzer, when operated at an Rp = 840 000 at m/z 400 (Rp > 1 000 000 at m/z 200) with a detection time of 3 s, was found to be well suited for adequate characterization of crude oil. Accurate class classification and mass accuracy below 1 ppm was obtained leading to proper, comprehensive petroleomics characterization.


Energy & Fuels | 2007

Biodiesel Typification and Quality Control by Direct Infusion Electrospray Ionization Mass Spectrometry Fingerprinting

Rodrigo Ramos Catharino; Humberto M. S. Milagre; Sérgio Adriano Saraiva; Camila Martins Garcia; Ulf Schuchardt; Marcos N. Eberlin; Rodinei Augusti; Rosana C. L. Pereira; Manoel J. R. Guimarães; Gilberto F. de Sá; Janaína Marques R. Caixeiro; Vanderléa de Souza


Energy & Fuels | 2013

Predictive Petroleomics: Measurement of the Total Acid Number by Electrospray Fourier Transform Mass Spectrometry and Chemometric Analysis

Boniek G. Vaz; Patrícia V. Abdelnur; Werickson Fortunato de Carvalho Rocha; Alexandre O. Gomes; Rosana C. L. Pereira


Energy & Fuels | 2013

Characterization of Bio-oils from Different Pyrolysis Process Steps and Biomass Using High-Resolution Mass Spectrometry

Patrícia V. Abdelnur; Boniek G. Vaz; José D. Rocha; Marlon B. B. de Almeida; Marco Antonio G. Teixeira; Rosana C. L. Pereira


Energy & Fuels | 2013

Petroleomics by Traveling Wave Ion Mobility–Mass Spectrometry Using CO2 as a Drift Gas

Maíra Fasciotti; Priscila M. Lalli; Clécio F. Klitzke; Yuri E. Corilo; Marcos A. Pudenzi; Rosana C. L. Pereira; Wagner L. Bastos; Romeu J. Daroda; Marcos N. Eberlin


Energy & Fuels | 2012

Comprehensive Chemical Composition of Gas Oil Cuts Using Two-Dimensional Gas Chromatography with Time-of-Flight Mass Spectrometry and Electrospray Ionization Coupled to Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

Bárbara M.F. Ávila; Boniek G. Vaz; Ricardo Pereira; Alexandre O. Gomes; Rosana C. L. Pereira; Yuri E. Corilo; Rosineide C. Simas; Heliara D. Lopes Nascimento; Marcos N. Eberlin; Débora A. Azevedo

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Marcos N. Eberlin

State University of Campinas

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Boniek G. Vaz

Universidade Federal de Goiás

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Clécio F. Klitzke

State University of Campinas

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Marcos A. Pudenzi

State University of Campinas

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Rosineide C. Simas

State University of Campinas

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Yuri E. Corilo

State University of Campinas

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Débora A. Azevedo

Federal University of Rio de Janeiro

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