Ross Edwards

Onset of deglacial warming in West Antarctica driven by local orbital forcing

The cause of warming in the Southern Hemisphere during the most recent deglaciation remains a matter of debate. Hypotheses for a Northern Hemisphere trigger, through oceanic redistributions of heat, are based in part on the abrupt onset of warming seen in East Antarctic ice cores and dated to 18,000 years ago, which is several thousand years after high-latitude Northern Hemisphere summer insolation intensity began increasing from its minimum, approximately 24,000 years ago. An alternative explanation is that local solar insolation changes cause the Southern Hemisphere to warm independently. Here we present results from a new, annually resolved ice-core record from West Antarctica that reconciles these two views. The records show that 18,000 years ago snow accumulation in West Antarctica began increasing, coincident with increasing carbon dioxide concentrations, warming in East Antarctica and cooling in the Northern Hemisphere associated with an abrupt decrease in Atlantic meridional overturning circulation. However, significant warming in West Antarctica began at least 2,000 years earlier. Circum-Antarctic sea-ice decline, driven by increasing local insolation, is the likely cause of this warming. The marine-influenced West Antarctic records suggest a more active role for the Southern Ocean in the onset of deglaciation than is inferred from ice cores in the East Antarctic interior, which are largely isolated from sea-ice changes.

A new bipolar ice core record of volcanism from WAIS Divide and NEEM and implications for climate forcing of the last 2000 years

Volcanism is a natural climate forcing causing short-term variations in temperatures. Histories of volcanic eruptions are needed to quantify their role in climate variability and assess human impacts. We present two new seasonally resolved, annually dated non-sea-salt sulfur records from polar ice cores - WAIS Divide (WDC06A) from West Antarctica spanning 408 B.C.E. to 2003 C.E. and NEEM (NEEM-2011-S1) from Greenland spanning 78 to 1997 C.E. - both analyzed using high-resolution continuous flow analysis coupled to two mass spectrometers. The high dating accuracy allowed placing the large bi-hemispheric deposition event ascribed to the eruption of Kuwae in Vanuatu (previously thought to be 1452/1453 C.E. and used as a tie-point in ice core dating) into the year 1458/1459 C.E. This new age is consistent with an independent ice core timescale from Law Dome and explains an apparent delayed response in tree rings to this volcanic event. A second volcanic event is detected in 1453 C.E. in both ice cores. We show for the first time ice core signals in Greenland and Antarctica from the strong eruption of Taupo in New Zealand in 232 C.E. In total, 133 volcanic events were extracted from WDC06A and 138 from NEEM-2011-S1, with 50 ice core signals - predominantly from tropical source volcanoes - identified simultaneously in both records. We assess the effect of large bipolar events on temperature-sensitive tree ring proxies. These two new volcanic records, synchronized with available ice core records to account for spatial variability in sulfate deposition, provide a basis for improving existing time series of volcanic forcing.

Microbial life at −13 °C in the brine of an ice-sealed Antarctic lake

The permanent ice cover of Lake Vida (Antarctica) encapsulates an extreme cryogenic brine ecosystem (−13 °C; salinity, 200). This aphotic ecosystem is anoxic and consists of a slightly acidic (pH 6.2) sodium chloride-dominated brine. Expeditions in 2005 and 2010 were conducted to investigate the biogeochemistry of Lake Vida’s brine system. A phylogenetically diverse and metabolically active Bacteria dominated microbial assemblage was observed in the brine. These bacteria live under very high levels of reduced metals, ammonia, molecular hydrogen (H2), and dissolved organic carbon, as well as high concentrations of oxidized species of nitrogen (i.e., supersaturated nitrous oxide and ∼1 mmol⋅L−1 nitrate) and sulfur (as sulfate). The existence of this system, with active biota, and a suite of reduced as well as oxidized compounds, is unusual given the millennial scale of its isolation from external sources of energy. The geochemistry of the brine suggests that abiotic brine-rock reactions may occur in this system and that the rich sources of dissolved electron acceptors prevent sulfate reduction and methanogenesis from being energetically favorable. The discovery of this ecosystem and the in situ biotic and abiotic processes occurring at low temperature provides a tractable system to study habitability of isolated terrestrial cryoenvironments (e.g., permafrost cryopegs and subglacial ecosystems), and is a potential analog for habitats on other icy worlds where water-rock reactions may cooccur with saline deposits and subsurface oceans.

Dispersion measure variations and their effect on precision pulsar timing

We present an analysis of the variations seen in the dispersion measures (DMs) of 20-ms pulsars observed as part of the Parkes Pulsar Timing Array project.We carry out a statistically rigorous structure function analysis for each pulsar and show that the variations seen for most pulsars are consistent with those expected for an interstellar medium characterized by a Kolmogorov turbulence spectrum. The structure functions for PSRs J1045−4509 and J1909−3744 provide the first clear evidence for a large inner scale, possibly due to ion–neutral damping. We also show the effect of the solar wind on the DMs and show that the simple models presently implemented into pulsar timing packages cannot reliably correct for this effect. For the first time we clearly show how DM variations affect pulsar timing residuals and how they can be corrected in order to obtain the highest possible timing precision. Even with our presently limited data span, the residuals (and all parameters derived from the timing) for six of our pulsars have been significantly improved by correcting for the DM variations.

Antarctic-wide array of high-resolution ice core records reveals pervasive lead pollution began in 1889 and persists today

Interior Antarctica is among the most remote places on Earth and was thought to be beyond the reach of human impacts when Amundsen and Scott raced to the South Pole in 1911. Here we show detailed measurements from an extensive array of 16 ice cores quantifying substantial toxic heavy metal lead pollution at South Pole and throughout Antarctica by 1889 – beating polar explorers by more than 22 years. Unlike the Arctic where lead pollution peaked in the 1970s, lead pollution in Antarctica was as high in the early 20th century as at any time since industrialization. The similar timing and magnitude of changes in lead deposition across Antarctica, as well as the characteristic isotopic signature of Broken Hill lead found throughout the continent, suggest that this single emission source in southern Australia was responsible for the introduction of lead pollution into Antarctica at the end of the 19th century and remains a significant source today. An estimated 660 t of industrial lead have been deposited over Antarctica during the past 130 years as a result of mid-latitude industrial emissions, with regional-to-global scale circulation likely modulating aerosol concentrations. Despite abatement efforts, significant lead pollution in Antarctica persists into the 21st century.

Ultratrace analysis of Antarctic snow and ice samples using high resolution inductively coupled plasma mass spectrometry

High resolution ICP-MS was used to determine the concentrations of Al, Sc, V, Mn, Fe, Co, Pb and Bi in snow and ice from Antarctica. To overcome some potentially problematic spectral interferences, measurements were acquired in both low and medium resolution modes. Small sample volumes were analysed using a microconcentric nebuliser. After rigorous instrument cleaning and sample preparation, detection levels in the low and sub-pg g–1 range (0.3–48 pg g–1) were found for all elements. Concentration values were determined for a continental snow, sea ice snow and a representative ice core. Concentration ranges for all snow samples (n=25) were (in pg g–1): Al (30–2000), V (2–16), Mn (2–30) and Fe (30–1500), while Sc and Co were typically below detection or blank limits. The ice core sample had Al, Mn, Fe and Pb concentrations of 90, 7, 110 and 1 pg g–1, respectively, while Sc, V, Co and Bi could not be quantified (below detection or blank limits). The reliability of the analytical method for Fe was confirmed by flow injection analysis with spectrophotometric detection.

Combined DNA, toxicological and heavy metal analyses provides an auditing toolkit to improve pharmacovigilance of traditional Chinese medicine (TCM).

Globally, there has been an increase in the use of herbal remedies including traditional Chinese medicine (TCM). There is a perception that products are natural, safe and effectively regulated, however, regulatory agencies are hampered by a lack of a toolkit to audit ingredient lists, adulterants and constituent active compounds. Here, for the first time, a multidisciplinary approach to assessing the molecular content of 26 TCMs is described. Next generation DNA sequencing is combined with toxicological and heavy metal screening by separation techniques and mass spectrometry (MS) to provide a comprehensive audit. Genetic analysis revealed that 50% of samples contained DNA of undeclared plant or animal taxa, including an endangered species of Panthera (snow leopard). In 50% of the TCMs, an undeclared pharmaceutical agent was detected including warfarin, dexamethasone, diclofenac, cyproheptadine and paracetamol. Mass spectrometry revealed heavy metals including arsenic, lead and cadmium, one with a level of arsenic >10 times the acceptable limit. The study showed 92% of the TCMs examined were found to have some form of contamination and/or substitution. This study demonstrates that a combination of molecular methodologies can provide an effective means by which to audit complementary and alternative medicines.

A reconstruction of extratropical Indo-Pacific sea-level pressure patterns during the Medieval Climate Anomaly

AbstractSubtropical and extratropical proxy records of wind field, sea level pressure (SLP), temperature and hydrological anomalies from South Africa, Australia/New Zealand, Patagonian South America and Antarctica were used to reconstruct the Indo-Pacific extratropical southern hemisphere sea-level pressure anomaly (SLPa) fields for the Medieval Climate Anomaly (MCA ~700–1350 CE) and transition to the Little Ice Age (LIA 1350–1450 CE). The multivariate array of proxy data were simultaneously evaluated against global climate model output in order to identify climate state analogues that are most consistent with the majority of proxy data. The mean SLP and SLP anomaly patterns derived from these analogues illustrate the evolution of low frequency changes in the extratropics. The Indo-Pacific extratropical mean climate state was dominated by a strong tropical interaction with Antarctica emanating from: (1) the eastern Indian and south-west Pacific regions prior to 1100 CE, then, (2) the eastern Pacific evolving to the central Pacific La Niña-like pattern interacting with a +ve SAM to 1300 CE. A relatively abrupt shift to –ve SAM and the central Pacific El Niño-like pattern occurred at ~1300. A poleward (equatorward) shift in the subtropical ridge occurred during the MCA (MCA–LIA transition). The Hadley Cell expansion in the Australian and Southwest Pacific, region together with the poleward shift of the zonal westerlies is contemporaneous with previously reported Hadley Cell expansion in the North Pacific and Atlantic regions, and suggests that bipolar climate symmetry was a feature of the MCA.

Stormwater and fire as sources of black carbon nanoparticles to Lake Tahoe.

Emitted to the atmosphere through fire and fossil fuel combustion, refractory black carbon nanoparticles (rBC) impact human health, climate, and the carbon cycle. Eventually these particles enter aquatic environments, where they may affect the fate of other pollutants. While ubiquitous, the particles are still poorly characterized in freshwater systems. Here we present the results of a study determining rBC in waters of the Lake Tahoe watershed in the western United States from 2007 to 2009. The study period spanned a large fire within the Tahoe basin, seasonal snowmelt, and a number of storm events, which resulted in pulses of urban runoff into the lake with rBC concentrations up to 4 orders of magnitude higher than midlake concentrations. The results show that rBC pulses from both the fire and urban runoff were rapidly attenuated suggesting unexpected aggregation or degradation of the particles. We find that those processes prevent rBC concentrations from building up in the clear and oligotrophic Lake Tahoe. This rapid removal of rBC soon after entry into the lake has implications for the transport of rBC in the global aquatic environment and the flux of rBC from continents to the global ocean.

The ultra trace analysis of Antarctic snow and ice samples using High Resolution ICP-MS

High resolution ICP-MS was used to determine the concentrations of Al, Sc, V, Mn, Fe, Co, Pb and Bi in snow and ice from Antarctica. To overcome some potentially problematic spectral interferences, measurements were acquired in both low and medium resolution modes. Small sample volumes were analysed using a microconcentric nebuliser. After rigorous instrument cleaning and sample preparation, detection levels in the low and sub-pg g�1 range (0.3�48 pg g�1) were found for all elements. Concentration values were determined for a continental snow, sea ice snow and a representative ice core. Concentration ranges for all snow samples (n=25) were (in pg g�1): Al (30�2000), V (2�16), Mn (2�30) and Fe (30�1500), while Sc and Co were typically below detection or blank limits. The ice core sample had Al, Mn, Fe and Pb concentrations of 90, 7, 110 and 1 pg g�1, respectively, while Sc, V, Co and Bi could not be quantified (below detection or blank limits). The reliability of the analytical method for Fe was confirmed by flow injection analysis with spectrophotometric detection.