Ryan J. McAleer

Volcanoes of the passive margin: The youngest magmatic event in eastern North America

The rifted eastern North American margin (ENAM) provides important clues to the long-term evolution of continental margins. An Eocene volcanic swarm exposed in the Appalachian Valley and Ridge Province of Virginia and West Virginia (USA) contains the youngest known igneous rocks in the ENAM. These magmas provide the only window into the most recent deep processes contributing to the postrift evolution of this margin. Here we present new 40 Ar/ 39 Ar ages, geochemical data, and radiogenic isotopes that constrain the melting conditions and the timing of emplacement. Modeling of the melting conditions on primitive basalts yielded an average temperature and pressure of 1412 ± 25 °C and 2.32 ± 0.31 GPa, corresponding to a mantle potential temperature of ∼1410 °C, suggesting melting conditions slightly higher than average mantle temperatures beneath mid-ocean ridges. When compared with magmas from Atlantic hotspots, the Eocene ENAM samples share isotopic signatures with the Azores and Cape Verde. This similarity suggests the possibility of a large-scale dissemination of similar sources in the upper mantle left over from the opening of the Atlantic Ocean. Asthenosphere upwelling related to localized lithospheric delamination is a possible process that can explain the intraplate signature of these magmas that lack evidence of a thermal anomaly. This process can also explain the Cenozoic dynamic topography and evidence of rejuvenation of the central Appalachians.

Post‐rift magmatic evolution of the eastern North American “passive‐aggressive” margin

Understanding the evolution of passive margins requires knowledge of temporal and chemical constraints on magmatism following the transition from super-continent to rifting, to post-rifting evolution. The Eastern North American Margin (ENAM) is an ideal study location as several magmatic pulses occurred in the 200 My following rifting. In particular, the Virginia-West Virginia region of the ENAM has experienced two post-rift magmatic pulses at ∼152 Ma and 47 Ma, and thus provides a unique opportunity to study the long-term magmatic evolution of passive margins. Here we present a comprehensive set of geochemical data that includes new 40Ar/39Ar ages, major and trace-element compositions, and analysis of radiogenic isotopes to further constrain their magmatic history. The Late Jurassic volcanics are bi-modal, from basanites to phonolites, while the Eocene volcanics range from picrobasalt to rhyolite. Modeling suggests that the felsic volcanics from both the Late Jurassic and Eocene events are consistent with fractional crystallization. Sr-Nd-Pb systematics for the Late Jurassic event suggests HIMU and EMII components in the magma source that we interpret as upper mantle components rather than crustal interaction. Lithospheric delamination is the best hypothesis for magmatism in Virginia/West Virginia, due to tectonic instabilities that are remnant from the long-term evolution of this margin, resulting in a “passive-aggressive” margin that records multiple magmatic events long after rifting ended. This article is protected by copyright. All rights reserved.

New insight into the origin of manganese oxide ore deposits in the Appalachian Valley and Ridge of northeastern Tennessee and northern Virginia, USA

Manganese oxide deposits have long been observed in association with carbonates within the Appalachian Mountains, but their origin has remained enigmatic for well over a century. Ore deposits of Mn oxides from several productive sites located in eastern Tennessee and northern Virginia display morphologies that include botryoidal and branching forms, massive nodules, breccia matrix cements, and fracture fills. The primary ore minerals include hollandite, cryptomelane, and romanechite. Samples of Mn oxides from multiple localities in these regions were analyzed using electron microscopy, X-ray analysis, Fourier transform infrared spectroscopy, and trace/rare earth element geochemistry. The samples from eastern Tennessee have biological morphologies, contain residual biopolymers, and exhibit REE signatures that suggest the ore formation was due to supergene enrichment (likely coupled with microbial activity). In contrast, several northern Virginia ores hosted within quartz-sandstone breccias exhibit petrographic relations, mineral morphologies, and REE signatures indicating inorganic precipitation, and a likely hydrothermal origin with supergene overprinting. Nodular accumulations of Mn oxides within weathered alluvial deposits that occur near to breccia-hosted Mn deposits in Virginia show geochemical signatures that are distinct from the breccia matrices, and appear to reflect remobilization of earlier-emplaced Mn and concentration within supergene traps. Based on the proximity of all of the productive ore deposits to mapped faults or other zones of deformation, we suggest that the primary source of all of the Mn may have been deep-seated, and that Mn oxides with supergene and/or biological characteristics result from the local remobilization and concentration of this primary Mn.

Post-Taconic tilting and Acadian structural overprint of the classic Barrovian metamorphic gradient in Dutchess County, New York

Field mapping and 40Ar/39Ar age spectrum dating of white mica across the classic metamorphic gradient in Dutchess County, New York indicate that post-peak metamorphic and structural events complicate the interpretation of this sequence as an intact Taconic metamorphic field gradient. Oriented samples were collected and fabrics were measured along two ∼7 km transects. These transects extend from west of the biotite zone (west of Clove Mountain) to the sillimanite zone (Swamp River Valley) in eastern Dutchess County. Field and petrographic analysis reveals three pervasive foliations (S1, S2 and S3). S1 is folded in the lower grade rocks of the sequence, but is increasingly overprinted at garnet and higher zones by a penetrative foliation, S2. S2 dips steeply to the SE and is axial planar to folds in S1. S2 is overgrown by porphyroblasts of biotite, biotite + chloritoid, biotite + garnet ± staurolite ± kyanite ± sillimanite, at respective metamorphic grades, that appear to approximate peak temperature conditions. S1, S2, and peak temperature conditions are constrained as late Taconic based on a depositional age of ∼460 Ma (Potter, 1972) for the Walloomsac Formation and a staurolite age of ∼454 Ma (Lanzirotti and Hanson, 1997) from kyanite-sillimanite grade rocks. S3 is a greenschist facies foliation composed of muscovite ± biotite ± chlorite that truncates or overprints S2 in garnet through sillimanite grade rocks in the eastern part of the study area. S3 dips gently to the S-SE and becomes more penetrative to the east, such that in the garnet zone, S2 is overprinted by a weakly developed spaced S3 cleavage, while in many samples in the staurolite and higher metamorphic zones S2 micas are significantly overprinted by S3 micas. S3 is observed wrapping around and truncating peak temperature porphyroblasts. Three samples of lepidoblastic white mica (with varying proportions of S1, S2, and S3) from the biotite through staurolite zone all produce 40Ar/39Ar age spectra suggesting closure ages of ∼385 Ma. These white mica ages are interpreted to represent the time of cooling through white mica closure (∼350 °C). The 40Ar/39Ar ages in conjunction with field mapping and petrographic analysis suggest that S3 developed in the Devonian Acadian orogeny. Furthermore, the 40Ar/39Ar data constrains the timing of tilting and uplift of the Ordovician Barrovian sequence from the Middle Silurian to Early Devonian. This study suggests mid-crustal wedging during the Salinic orogeny as a possible mechanism for tilting the rocks of this region and exposing the Taconic-aged Barrovian field gradient at the surface today. We conclude the low-grade Acadian metamorphic overprint of these rocks involved deformation that produced a new (third) cleavage that was coincident with regional cooling from peak Taconic metamorphic conditions and thus required strain but no reheating during the Acadian.