S. Özdemir Kart
Pamukkale University
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Featured researches published by S. Özdemir Kart.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2014
M. Karakuş; S. Solak; Tuncer Hökelek; Hakan Dal; A. Bayrakdar; S. Özdemir Kart; M. Karabacak; H.H. Kart
The compound 2 has been synthesized from the reaction of 2,4-Bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and (R)-1-[3,5-Bis(trifloromethyl)phenyl]ethanol in toluene. The obtained crude dithiophosphonic acid 1 has been treated with the excess of N(C2H5)3 to give rise to 2, [(+HN(C2H5)3][O-CH3CH-C6H3(CF3)2)(CH3OC6H4)PS2(-)]. The compound 2 has been characterized by using the spectroscopic methods such as IR, (1)H, (13)C, (31)P NMR and structural analysing method such as X-ray crystallography. It crystallizes in the orthorhombic system, whose space group is P212121. It consists of a dithiophosphonate bridged methoxyphenyl and bis(triflorophenylethyl) groups and a triethylammonium moiety linked by N-H⋯S and C-H⋯F hydrogen bonds. In the crystal structure, the C17H14F6O2PS2 molecule is elongated along the b-axis and stacked along the a-axis. The triethylammonium, N(CH2CH3)3, molecule fill in the cavities between the C17H14F6O2PS2 molecule. Moreover, ab initio methods based on Hartree-Fock (HF) and Density Functional Theory (DFT) calculations with the basis set of 6-31G(d) are also carried out to determine the molecular structural properties and to calculate FT-IR and NMR spectrum of the compound 2. The experimental results and theoretical calculations have been compared, and they are found to be in good agreement.
Journal of Alloys and Compounds | 2009
M. Kalay; H.H. Kart; S. Özdemir Kart; Tahir Cagin
Journal of Alloys and Compounds | 2010
S. Özdemir Kart; Tahir Cagin
Journal of Non-crystalline Solids | 2004
S. Özdemir Kart; M. Tomak; M. Uludoğan; Tahir Cagin
Materials Chemistry and Physics | 2008
M. Bilge; S. Özdemir Kart; H.H. Kart; Tahir Cagin
Materials Chemistry and Physics | 2014
H.H. Kart; H. Yildirim; S. Özdemir Kart; Tahir Cagin
Materials Science and Engineering A-structural Materials Properties Microstructure and Processing | 2006
S. Özdemir Kart; M. Tomak; Mustafa Uludoğan; Tahir Çağin
Journal of achievements in materials and manufacturing engineering | 2008
M. Bilge; S. Özdemir Kart; H.H. Kart; Tahir Cagin
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2014
H.H. Kart; S. Özdemir Kart; M. Karakuş; Mustafa Kurt
Physica B-condensed Matter | 2005
S. Özdemir Kart; M. Tomak; Tahir Cagin