S. Sujecki

Progress in rare-earth-doped mid-infrared fiber lasers.

The progress, and current challenges, in fabricating rare-earth-doped chalcogenide-glass fibers for developing mid-infrared (IR) fiber lasers are reviewed. For the first time a coherent explanation is forwarded for the failure to date to develop a gallium-lanthanum-sulfide glass mid-IR fiber laser. For the more covalent chalcogenide glasses, the importance of optimizing the glass host and glass processing routes in order to minimize non-radiative decay and to avoid rare earth ion clustering and glass devitrification is discussed. For the first time a new idea is explored to explain an additional method of non-radiative depopulation of the excited state in the mid-IR that has not been properly recognized before: that of impurity multiphonon relaxation. Practical characterization of candidate selenide glasses is presented. Potential applications of mid-infrared fiber lasers are suggested.

C3‐Symmetric Lanthanide Tris(alkoxide) Complexes Formed by Preferential Complexation and Their Stereoselective Polymerization of rac‐Lactide

Restoring order: YIII, EuIII, and ErIII tris(ligand) complexes of a new chiral alkoxide ligand, tBu2P(O)CH2CH(tBu)OH (HL), preferentially form as C3‐symmetric diastereomers. Thus racemic HL affords (RRR)‐ and (SSS)‐[LnL3] complexes, which are active catalysts for the stereoselective polymerization of rac‐lactide to afford highly isotactic polylactic acid.

Study of mid-infrared laser action in chalcogenide rare earth doped glass with Dy 3+ , Pr 3+ and Tb 3+

We present a study of chalcogenide glass fiber lasers doped with Dy3+, Pr3+ or Tb3+ that would operate in the mid-infrared wavelength range. A set of chalcogenide glass samples doped with different concentrations of rare earth ions is fabricated. The modeling parameters are directly extracted from FTIR absorption measurements of the fabricated bulk glass samples using Judd-Ofelt, Fuchtbauer–Ladenburg theory and McCumber theory. The modeling results show that, for all the dopants considered, an efficient mid-infrared laser action is possible if optical losses are kept at the level of 1dB/m or below.

Nonlinear properties of tapered laser cavities

The nonlinear phenomena accompanying the process of light generation in high-power tapered semiconductor lasers are studied using a combination of simulation and experiment. Optical pumping, electrical overpumping, filamentation, and spatial hole burning are shown to be the key nonlinear phenomena influencing the operation of tapered lasers at high output powers. In the particular tapered laser studied, the optical pumping effect is found to have the largest impact on the output beam quality. The simulation model used in this study employs the wide-angle finite-difference beam propagation method for the analysis of the optical propagation within the cavity. Quasi-three-dimensional (3-D) thermal and electrical models are used for the calculation of the 3-D distributions of the temperature, electrons, holes, and electrical potential. The simulation results reproduce key features and the experimental trends.

Mid-infrared supercontinuum generation to 12.5μm in large NA chalcogenide step-index fibres pumped at 4.5μm

We present numerical modeling of mid-infrared (MIR) supercontinuum generation (SCG) in dispersion-optimized chalcogenide (CHALC) step-index fibres (SIFs) with exceptionally high numerical aperture (NA) around one, pumped with mode-locked praseodymium-doped (Pr(3+)) chalcogenide fibre lasers. The 4.5um laser is assumed to have a repetition rate of 4MHz with 50ps long pulses having a peak power of 4.7kW. A thorough fibre design optimisation was conducted using measured material dispersion (As-Se/Ge-As-Se) and measured fibre loss obtained in fabricated fibre of the same materials. The loss was below 2.5dB/m in the 3.3-9.4μm region. Fibres with 8 and 10μm core diameters generated an SC out to 12.5 and 10.7μm in less than 2m of fibre when pumped with 0.75 and 1kW, respectively. Larger core fibres with 20μm core diameters for potential higher power handling generated an SC out to 10.6μm for the highest NA considered but required pumping at 4.7kW as well as up to 3m of fibre to compensate for the lower nonlinearities. The amount of power converted into the 8-10μm band was 7.5 and 8.8mW for the 8 and 10μm fibres, respectively. For the 20μm core fibres up to 46mW was converted.

Quasi-3-D simulation of high-brightness tapered lasers

We present a simulation tool useful to optimize the design of semiconductor tapered lasers and to study the physical processes inside of them. This is achieved by using a state-of-the-art quasi-three-dimensional (quasi-3-D) electrical and thermal model, coupled to a two-dimensional (2-D) wide-angle beam propagation method optical model. A calibration procedure of model parameters is proposed to contribute to the development of reliable simulation tools. Different laser diodes with a tapered gain section, emitting at 735 and 975 nm, are used to validate the model through the extensive comparison of experimental and simulated results. The suitability of 2-D and 3-D electrical, thermal, and optical models is discussed in terms accuracy and computational effort.

Design and Simulation of Next-Generation High-Power, High-Brightness Laser Diodes

High-brightness laser diode technology is progressing rapidly in response to competitive and evolving markets. The large volume resonators required for high-power, high-brightness operation makes their beam parameters and brightness sensitive to thermal- and carrier-induced lensing and also to multimode operation. Power and beam quality are no longer the only concerns for the design of high-brightness lasers. The increased demand for these technologies is accompanied by new performance requirements, including a wider range of wavelengths, direct electrical modulation, spectral purity and stability, and phase-locking techniques for coherent beam combining. This paper explores some of the next-generation technologies being pursued, while illustrating the growing importance of simulation and design tools. The paper begins by investigating the brightness limitations of broad-area laser diodes, including the use of asymmetric feedback to improve the modal discrimination. Next, tapered lasers are considered, with an emphasis on emerging device technologies for applications requiring electrical modulation and high spectral brightness.

Low loss Ge-As-Se chalcogenide glass fiber, fabricated using extruded preform, for mid-infrared photonics

Chalcogenide glass fibers have attractive properties (e.g. wide transparent window, high optical non-linearity) and numerous potential applications in the mid-infrared (MIR) region. Low optical loss is desired and important in the development of these fibers. Ge-As-Se glass has a large glass-forming range to provide versatility of choice from continuously varying physical properties. Recently, broadband MIR supercontinuum generation has been achieved in chalcogenide fibers by using Ge-As-Se glass in the core/clad. structure. In the shaping of chalcogenide glass optical fiber preforms, extrusion is a useful technique. This work reports glass properties (viscosity-temperature curve and glass transition) and optical losses of Ge-As-Se fiber fabricated from an extruded preform. A robust cut-back method of fiber loss measurement is developed and the corresponding error calculation discussed. MIR light is propagated through 52 meters of a fiber, which has the lowest loss yet reported for Ge-As-Se fiber of 83 ± 2 dB/km at 6.60 μm wavelength. The fiber baseline loss is 83-90 dB/km across 5.6-6.8 μm, a Se-H impurity absorption band of 1.4 dB/m at 4.5 μm wavelength is superposed and other impurity bands (e.g. O-H, As-O, Ge-O) are ≤ 20 dB/km. Optical losses of fiber fabricated from different positions of the extruded preform are investigated.

Narrow-line coherently combined tapered laser diodes in a Talbot external cavity with a volume Bragg grating

We present the phase locking of an array of index-guided tapered laser diodes. An external cavity based on the self-imaging Talbot effect has been built. A volume Bragg grating is used as the output coupler to stabilize and narrow the spectrum at 976nm. A power of 1.7W is achieved in the in-phase single main lobe mode with a high visibility. We have checked that each emitter is locked to the Bragg wavelength with a 100pm spectrum linewidth. The experimental results compare well with numerical simulations performed with two-dimensional wide-angle finite difference beam propagation method.

Refractive index dispersion of chalcogenide glasses for ultra-high numerical-aperture fiber for mid-infrared supercontinuum generation

We select a chalcogenide core glass, AsSe, and cladding glass, GeAsSe, for their disparate refractive indices yet sufficient thermal-compatibility for fabricating step index fiber (SIF) for mid-infrared supercontinuum generation (MIR-SCG). The refractive index dispersion of both bulk glasses is measured over the 0.4 µm–33 µm wavelength-range, probing the electronic and vibrational behavior of these glasses. We verify that a two-term Sellmeier model is unique and sufficient to describe the refractive index dispersion over the wavelength range for which the experimentally determined extinction coefficient is insignificant. A SIF composed of the glasses is fabricated and calculated to exhibit an ultra-high numerical aperture >0.97 over the entire wavelength range 0.4-33 µm suggesting that the SIF glass pair is a promising candidate for MIR-SCG. Material dispersion characteristics and the zero dispersion wavelength, both critical design parameters for SIF for MIR-SCG, are derived.