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The age of the Neapolitan Yellow Tuff caldera-forming eruption (Campi Flegrei caldera – Italy) assessed by 40Ar/39Ar dating method

Abstract The Neapolitan Yellow Tuff (NYT) is the product of the largest known trachytic phreatoplinian eruption. It covered an area larger than 1000 km2 with an estimated volume of about 40 km3 of erupted magma. During the course of the eruption a caldera collapsed within the previously formed Campanian Ignimbrite caldera. The resulting nested structure strongly influenced the following volcanic activity in the Campi Flegrei caldera. As previous dating of the NYT does not converge toward a unique result, a new set of 40Ar/39Ar age determinations has been carried out to better constrain the age of the eruption. Two variants of the 40Ar/39Ar dating method were applied to determine the age of the NYT eruption: (1) single-crystal total fusion (SCTF), on an individual phenocryst of feldspar, and (2) laser incremental heating (LIH), on bulk aliquots of feldspar phenocrysts. The results of the SCTF analyses show that the overall sample weighted mean age, derived from the conventional age calculation, is 15.6±0.8 ka. A weighted mean of the isochron age is 15.3±1.2 ka (2σ), and has been assumed as the best indicator of age to be derived from the SCTF analyses. The LIH analyses results show that plateau ages vary from 15.4±0.5 to 14.5±0.5 ka. The overall weighted mean age of the isochron results is 14.9±0.4 ka (2σ). This result has been assumed as the reference age for the NYT eruption, and agrees with the SCTF age. The new age obtained for the NYT deposits is of great relevance for the understanding of the evolution and the present state of the Campi Flegrei caldera and collocates the NYT in a crucial stratigraphical position to date the climatic oscillations that occurred between the Late Glacial and the Holocene.

The Neapolitan Yellow Tuff, a large-magnitude trachytic phreatoplinian eruption: eruptive dynamics, magma withdrawal and caldera collapse

The results of a detailed stratigraphical and volcanological study has allowed the definition of the Neapolitan Yellow Tuff (NYT) as the largest known trachytic phreatoplinian eruption with an estimated volume of not less than 30 km3 DRE. The NYT sequence can be subdivided in a lower and an upper member. Sedimentological and textural variations in time and space indicate that different eruptive and depositional mechanisms operated during the eruption. The lower member eruptive phase was characterized by alternating phreatoplinian and magmatic explosions while the upper member eruptive phase was characterized by a random sequence of phreatomagmatic and magmatic explosions. Particles produced by the same explosion were deposited contemporaneously by fallout and surge mechanisms either at different or at the same distance from the vent. Compositional variations show that the NYT sequence cannot be modeled as an inverted compositionally zoned magma body with magma becoming more basic in the course of the eruption. The chamber, composed of three geochemically distinct magma layers, was tapped at different depths according to the eruption dynamics. Each phreatoplinian explosion tapped concurrently all the magma layers while magmatic explosions tapped only one of them. The onset of the NYT caldera collapse is well constrained between lower and upper member eruptive phases. The collapse, which is only gravimetrically detectable, occurred inside the larger Phlegrean Fields caldera, which therefore can be defined as a nested caldera.

Fumarolic and diffuse soil degassing west of Mount Epomeo, Ischia, Italy

Abstract Fumarolic fluid compositions and diffuse soil emissions of hydrothermal fluids of the Donna Rachele area (0.86 km 2 , western flank of Mt. Epomeo, Ischia Island) have been studied in order to develop a conceptual geochemical model of the hydrothermal system. The degassing area was mapped and the total release of hydrothermal gas and heat associated with the diffuse emission of hydrothermal fluids was estimated. A mesostructural study was carried out in order to investigate the relations between the brittle structures and the main pathways of the uprising vapor. The fumarolic compositions are typical of hydrothermal fluids and water (>99%) represents the major component. All gas species in the H 2 O–H 2 –CO–CH 4 –CO 2 –H 2 S system are close to equilibrium concentrations at temperatures of ∼300°C and at redox conditions slightly more oxidizing than expected. The compositions of the Donna Rachele fumarolic gas approach the pure liquid equilibrium composition. This indicates a high fraction of separated vapor and suggests the presence of a highly energetic hydrothermal system at depth. The pure liquid equilibrium compositions of the Donna Rachele fumaroles, along with the historical records of shallow seismicity, the ‘explosion’ of a well in 1995, the occurrence of intense acoustic phenomena and of shallow wells discharging vapor indicate that the internal pressure of the hydrothermal system is occasionally larger than the hydrostatic pressure. To quantify the energy dissipated in the Donna Rachele area by the emission of fumarolic fluids, the hydrothermal diffuse degassing was studied by means of 336 soil CO 2 flux measurements. The highest CO 2 fluxes were measured in hydrothermally altered areas along the faults that border Mt. Epomeo. Structural data indicate that the vapor rises up along NW–SE striking normal faults related to gravity-induced stresses and affecting highly fractured lavas. The older faults, which are related to the Mt. Epomeo resurgence, act as a permeability barrier and bound the Donna Rachele diffuse degassing structure. The total hydrothermal CO 2 output was estimated to be ∼9 t d −1 . Assuming that the H 2 O/CO 2 ratio of the fluids that feed the diffuse degassing is the same as that of fumarolic effluents, the calculated heat flux is ∼40 MW. This value, which represents an important energy release, is only a part of the total thermal energy release of Ischia, where other fumarolic areas occur. The results obtained at Ischia indicate the importance of thermal energy released by diffuse degassing structures in the energy balance of quiescent volcanoes. Values of the thermal energy release from the Ischia hydrothermal system are comparable with those estimated on other quiescent volcanoes.

Syneruptive sequential fragmentation of pyroclasts from fractal modeling of grain size distributions of fall deposits: the Cretaio Tephra eruption (Ischia Island, Italy)

Abstract In this work we use fractal statistics in order to decipher the mechanisms acting during explosive volcanic eruptions by studying the grain size distribution (GSD) of natural pyroclastic-fall deposits. The method was applied to lithic-rich proximal deposits from a stratigraphic section of the Cretaio Tephra eruption (Ischia Island, Italy). Analyses were performed separately on bulk material, juvenile, and lithic fraction from each pyroclastic layer. Results highlight that the bulk material is characterized by a single scaling regime whereas two scaling regimes, with contrasting power-law exponents, are observed for the juvenile and the lithic fractions. On the basis of these results, we infer that the bulk material cannot be considered as a good proxy for deducing eruption dynamics because it is the result of mixing of fragments belonging to the lithic and juvenile fraction, both of which underwent different events of fragmentation governed by different mechanisms. In addition, results from fractal analyses of the lithic fraction suggest that it likely experienced a fragmentation event in which the efficiency of fragmentation was larger for the coarser fragments relative to the finer ones. On the contrary, we interpret the different scaling regimes observed for the juvenile fraction to be due to sequential events of fragmentation in the conduit, possibly enhanced by the presence of lithic fragments in the eruptive mixture. In particular, collisional events generated increasing amounts of finer particles modifying the original juvenile GSDs and determining the development of two scaling regimes in which the finer fragments record a higher efficiency of fragmentation relative to the coarser ones. We further suggest that in lithic-rich proximal fall deposits possible indications about the original GSDs of the juvenile fraction might still reside in the coarser particles fraction.