Sara Mateo

Optimization of an integrated electrodisinfection/electrocoagulation process with Al bipolar electrodes for urban wastewater reclamation

In this work, a novel integrated electrochemical process for urban wastewater regeneration is described. The electrochemical cell consists in a Boron Doped Diamond (BDD) or a Dimensionally Stable Anode (DSA) as anode, a Stainless Steel (SS) as cathode and a perforated aluminum plate, which behaves as bipolar electrode, between anode and cathode. Thus, in this cell, it is possible to carry out, at the same time, two different electrochemical processes: electrodisinfection (ED) and electrocoagulation (EC). The treatment of urban wastewater with different anodes and different operating conditions is studied. First of all, in order to check the process performance, experiments with synthetic wastewaters were carried out, showing that it is possible to achieve a 100% of turbidity removal by the electrodissolution of the bipolar electrode. Next, the effect of the current density and the anode material are studied during the ED-EC process of actual effluents. Results show that it is possible to remove Escherichia coli and turbidity simultaneously of an actual effluent from a WasteWater Treatment Facility (WWTF). The use of BDD anodes allows to remove the E. coli completely at an applied electric charge of 0.0077 A h dm(-3) when working with a current density of 6.65 A m(-2). On the other hand, with DSA anodes, the current density necessary to achieve the total removal of E. coli is higher (11.12 A m(-2)) than that required with BDD anodes. Finally, the influence of cell flow path and flow rate have been studied. Results show that the performance of the process strongly depends on the characteristics of the initial effluent (E. coli concentration and Cl(-)/NH(4)(+) initial ratio) and that a cell configuration cathode (inlet)-anode (outlet) and a higher flow rate enhance the removal of the turbidity from the treated effluent.

Oxygen availability effect on the performance of air‐breathing cathode microbial fuel cell

The effect of the oxygen availability over the performance of an air‐breathing microbial fuel cell (MFC) was studied by limiting the oxygen supply to the cathode. It was found that anodic reaction was the limiting stage in the performance of the MFC while oxygen was fully available at cathode. As the cathode was depleted of oxygen, the current density becomes limited by oxygen transport to the electrode surface. The exerted current density was maintained when oxygen mole fraction was higher than 10% due to the very good performance of the cathodic catalysts. However, the current density drastically falls when working at lower concentrations because of mass transfer limitations. In this sense it must be highlighted that the maximum exerted power, when oxygen mole fraction was higher than 10%, was almost three times higher than that obtained when oxygen mole fraction was 5%. Regarding to the wastewater treatment, a significant decrease in the COD removal was obtained when the MFC performance was reduced due to the limited availability of oxygen, which indicates the significant role of the electrogenic microorganisms in the COD removal in MFC. In addition, the low availability of oxygen at the cathode leads to a lower presence of oxygen at the anode, resulting in an increase in the coulombic efficiency.

Bioelectricity generation in a self-sustainable Microbial Solar Cell.

The possibility to develop devices based on bioprocesses for solar energy harvesting is significant from the economic and environmental point of view. In this communication it has been demonstrated that such device can be can be made by controlling the equilibrium between photosynthetic and electrogenic cultures. This device is a membrane-less and mediator-free apparatus with a graphite plate anode and a stainless steel grid cathode with a steady electricity production of about 1 mV m(-2).

Long-term effects of the transient COD concentration on the performance of microbial fuel cells.

In this work, the long‐term effects of transient chemical oxygen demands (COD) concentrations over the performance of a microbial fuel cell were studied. From the obtained results, it was observed that the repetitive change in the COD loading rate during 12 h conditioned the behavior of the system during periods of up to 7 days. The main modifications were the enhancement of the COD consumption rate and the exerted current. These enhancements yielded increasing Coulombic efficiencies (CEs) when working with COD concentrations of 300 mg/L, but constant CEs when working with COD concentrations from 900 to 1800 mg/L. This effect could be explained by the higher affinity for the substrate of Geobacter than that of the nonelectrogenic organisms such as Clostridia.

A critical view on microbial fuel cells: what’s the next stage?

Microbial fuel cells (MFCs) have garnered interest from the scientific community since the beginning of this century and this has caused a considerable increase in the scientific production of MFCs. However, the ability of MFCs to generate power has not increased considerably within this timeframe. In recent years, the power generated by MFCs has remained at an almost contact level owing to difficulties in the scale-up of the technology and thus the application of MFCs for powering systems with high energy demands will not be fully developed, at least within a short temporal horizon. Scale-up by increasing the size of the electrodes has failed, because of the wrong assumption that a linear function describes the relationship between the amount of power generated by a MFC and its size. However, more efficient energy generation upon working with small MFCs has been described. This has led to a new approach for scaling up on the basis of miniaturization and replication. Then, MFCs can be connected electrically in series to increase the overall potential and in parallel to increase the overall current. However, cell-voltage reversal and ionic short-circuit issues must be solved for this approach to be successful. Nowadays, the applicability of MFC technology in wastewater treatment does not make any sense in light of the power levels reached, despite the fact that MFCs were seen as a paramount opportunity less than a decade ago. However, MFCs can be used for wastewater treatment with coupled energy generation, as well as for other technologies such as biosensors and biologically inspired robots.

Driving force behind electrochemical performance of microbial fuel cells fed with different substrates

The performance of miniaturized microbial fuel cells operating with five different substrates (acetate, lactate, glucose and octanoate) were studied with the aim to identify the reason for its different performance. In all cases, the COD removal rate was about 650 mg COD L-1 d-1. However, the bio-electrochemical performance of the MFC was very different, showing the MFC fed with acetate the best performance: 20 A m-2 as maximum current density, 2 W m-2 of maximum power density, 0.376 V of OCV and 12.6% of CE. In addition, the acetate showed the best bio-electrochemical performance in the polarization curves and cyclic voltammetries. These polarization curves were modelled and the key to explain the better electrical performance of acetate was its lower ohmic losses. When working with acetate, its ohmic losses were one log-unit below those attained by the other substrates. These lower ohmic losses were not associated to the electrolyte conductivity of the fuel but to the lower ohmic loses of the biofilm generated.