Scott K. Rowland

A Habitable Fluvio-Lacustrine Environment at Yellowknife Bay, Gale Crater, Mars

The Curiosity rover discovered fine-grained sedimentary rocks, which are inferred to represent an ancient lake and preserve evidence of an environment that would have been suited to support a martian biosphere founded on chemolithoautotrophy. This aqueous environment was characterized by neutral pH, low salinity, and variable redox states of both iron and sulfur species. Carbon, hydrogen, oxygen, sulfur, nitrogen, and phosphorus were measured directly as key biogenic elements; by inference, phosphorus is assumed to have been available. The environment probably had a minimum duration of hundreds to tens of thousands of years. These results highlight the biological viability of fluvial-lacustrine environments in the post-Noachian history of Mars.

Pahoehoe and aa in Hawaii: volumetric flow rate controls the lava structure

The historical records of Kilauea and Mauna Loa volcanoes reveal that the rough-surfaced variety of basalt lava called aa forms when lava flows at a high volumetric rate (>5–10 m3/s), and the smooth-surfaced variety called pahoehoe forms at a low volumetric rate (<5–10 m3/s). This relationship is well illustrated by the 1983–1990 and 1969–1974 eruptions of Kilauea and the recent eruptions of Mauna Loa. It is also illustrated by the eruptions that produced the remarkable paired flows of Mauna Loa, in which aa formed during an initial short period of high discharge rate (associated with high fountaining) and was followed by the eruption of pahoehoe over a sustained period at a low discharge rate (with little or no fountaining). The finest examples of paired lava flows are those of 1859 and 1880–1881. We attribute aa formation to rapid and concentrated flow in open channels. There, rapid heat loss causes an increase in viscosity to a threshold value (that varies depending on the actual flow velocity) at which, when surface crust is torn by differential flow, the underlying lava is unable to move sufficiently fast to heal the tear. We attribute pahoehoe formation to the flowage of lava at a low volumetric rate, commonly in tubes that minimize heat loss. Flow units of pahoehoe are small (usually <1 m thick), move slowly, develop a chilled skin, and become virtually static before the viscosity has risen, to the threshold value. We infer that the high-discharge-rate eruptions that generate aa flows result from the rapid emptying of major or subsidiary magma chambers. Rapid near-surface vesiculation of gas-rich magma leads to eruptions with high discharge rates, high lava fountains, and fast-moving channelized flows. We also infer that long periods of sustained flow at a low discharge rate, which favor pahoehoe, result from the development of a free and unimpeded pathway from the deep plumbing system of the volcano and the separation of gases from the magma before eruption. Achievement of this condition requires one or more episodes of rapid magma excursion through the rift zone to establish a stable magma pathway.

Assessment of ozone photochemistry in the western North Pacific as inferred from PEM-West A observations during the fall 1991

This study examines the influence of photochemical processes on ozone distributions in the western North Pacific. The analysis is based on data generated during NASAs western Pacific Exploratory Mission (PEM-West A) during the fall of 1991. Ozone trends were best described in terms of two geographical domains: the western North Pacific rim (WNPR) and the western tropical North Pacific (WTNP). For both geographical regions, ozone photochemical destruction, D(O3), decreased more rapidly with altitude than did photochemical formation, F(O3). Thus the ozone tendency, P(O3), was typically found to be negative for z 6–8 km. For nearly all altitudes and latitudes, observed nonmethane hydrocarbon (NMHC) levels were shown to be of minor importance as ozone precursor species. Air parcel types producing the largest positive values of P(O3) included fresh continental boundary layer (BL) air and high-altitude (z > 7 km) parcels influenced by deep convection/lightning. Significant negative P(O3) values were found when encountering clean marine BL air or relatively clean lower free-tropospheric air. Photochemical destruction and formation fluxes for the Pacific rim region were found to exceed average values cited for marine dry deposition and stratospheric injection in the northern hemisphere by nearly a factor of 6. This region was also found to be in near balance with respect to column-integrated O3 photochemical production and destruction. By contrast, for the tropical regime column-integrated O3 showed photochemical destruction exceeding production by nearly 80%. Both transport of O3 rich midlatitude air into the tropics as well as very high-altitude (10–17 km) photochemical O3 production were proposed as possible additional sources that might explain this estimated deficit. Results from this study further suggest that during the fall time period, deep convection over Asia and Malaysia/Indonesia provided a significant source of high-altitude NOx to the western Pacific. Given that the high-altitude NOx lifetime is estimated at between 3 and 9 days, one would predict that this source added significantly to high altitude photochemical O3 formation over large areas of the western Pacific. When viewed in terms of strong seasonal westerly flow, its influence would potentially span a large part of the Pacific.

The Petrochemistry of Jake_M: A Martian Mugearite

“Jake_M,” the first rock analyzed by the Alpha Particle X-ray Spectrometer instrument on the Curiosity rover, differs substantially in chemical composition from other known martian igneous rocks: It is alkaline (>15% normative nepheline) and relatively fractionated. Jake_M is compositionally similar to terrestrial mugearites, a rock type typically found at ocean islands and continental rifts. By analogy with these comparable terrestrial rocks, Jake_M could have been produced by extensive fractional crystallization of a primary alkaline or transitional magma at elevated pressure, with or without elevated water contents. The discovery of Jake_M suggests that alkaline magmas may be more abundant on Mars than on Earth and that Curiosity could encounter even more fractionated alkaline rocks (for example, phonolites and trachytes).

Toothpaste lava: Characteristics and origin of a lava structural type transitional between pahoehoe and aa

Toothpaste lava, an important basalt structural type which illustrates the transition from pahoehoe to aa, is particularly well displayed on the 1960 Kapoho lava of Kilauea Volcano. Its transitional features stem from a viscosity higher than that of pahoehoe and a rate of flow slower than that of aa. Viscosity can be quantified by the limited settling of olivine phenocrysts and rate of flow by field observations related to the low-angle slope on which the lava flowed. Much can be learned about the viscosity, rheologic condition, and flow velocity of lavas long after solidification by analyses of their structural characteristics, and it is possible to make at least a semiquantitative assessment of the numerical values of these parameters.

Comparison of free tropospheric western Pacific air mass classification schemes for the PEM‐West A experiment

During September/October 1991, NASAs Global Tropospheric Experiment (GTE) conducted an airborne field measurement program (PEM-West A) in the troposphere over the western Pacific Ocean. In this paper we describe and use the relative abundance of the combustion products C2H2 and CO to classify air masses encountered during PEM-West A based on the degree that these tracers were processed by the combined effects of photochemical reactions and dynamical mixing (termed the degree of atmospheric processing). A large number of trace compounds (e.g., C2H6, C3H8, C6H6, NOy, and O3) are found to be well correlated with the degree of atmospheric processing that is reflected by changes in the ratio of C2H2/CO over the range of values from ∼0.3 to 2.0 (parts per trillion volume) C2H2/(parts per billion volume) CO. This C2H2/CO-based classification scheme is compared to model simulations and to two independent classification schemes based on air mass back-trajectory analyses and lidar profiles of O3 and aerosols. In general, these schemes agree well, and in combination they suggest that the functional dependence that other observed species exhibit with respect to the C2H2/CO atmospheric processing scale can be used to study the origin, sources, and sinks of trace species and to derive several important findings. First, the degree of atmospheric processing is found to be dominated by dilution associated with atmospheric mixing, which is found to primarily occur through the vertical mixing of relatively recent emissions of surface layer trace species. Photochemical reactions play their major role by influencing the background concentrations of trace species that are entrained during the mixing (i.e., dilution) process. Second, a significant noncontinental source(s) of NO (and NOx) in the free troposphere is evident. In particular, the enhanced NO mixing ratios that were observed in convected air masses are attributed to either emissions from lightning or the rapid recycling of NOy compounds. Third, nonsoluble trace species emitted in the continental boundary layer, such as CO and hydrocarbons, are vertically transported to the upper troposphere as efficiently as they are to the midtroposphere. In addition, the mixing ratios of CO and hydrocarbons in the upper troposphere over the western Pacific may reflect a significant contribution from northern hemisphere land areas other than Asia. Finally, we believe that these results can be valuable for the quantitative evaluation of the vertical transport processes that are usually parameterized in models.

Slopes, lava flow volumes, and vent distributions on Volcán Fernandina, Galápagos Islands

Digital elevation data from TOPSAR, an airborne synthetic aperture radar system that uses interferometry to derive topography, are used to determine slope distributions and lava flow thicknesses on Fernandina Volcano, Galapagos Islands. Four extracaldera slope regions are defined (from the coast inland): A coastal plain (average slope ∼2°), an apron (6°–12°), steep slopes 250–600 m high (20°–43°), and a 0.5- to 1-km-wide summit platform (∼10°). Lava flows and vents are mapped using Shuttle Imaging Radar-C (SIR-C), SPOT, Landsat Thematic Mapper (TM), and air photos. Over 500 flows are identified and categorized as young, intermediate, or old based on albedo, vegetation cover, and margin preservation. By area, young flows constitute 55% of the island, 34% are intermediate, and 7% are old. The aa:pahoehoe ratio of the young flows is 85:15, whereas for the intermediate flows it is 58:42. Of the 423 vents that were classified, 236 are radial and 80% of these are in the apron, 143 are arcuate and 94% of these are in the summit platform, and 46 have transitional orientations and are about equally divided between the steep slopes and summit platform; 95% of all vents are within 13 km of the caldera center. TOPSAR data allow flow volumes to be estimated, and young flows range from <0.01 to 0.12 km3, with a total volume of 2.3 km3. By volume, 91% of the young lava erupted from radial vents below the steep slopes, many of which are concentrated within the SE apron about 5–6 km from the caldera. Similar concentrations to the NE, NW, and SW consist of young and intermediate flows. Different proportions of lava flows and vents form the different slope regions; the coastal plain averages 0.1 vents/km2 and the slightly steeper apron averages 0.6 to 0.9 vents/km2, increasing inland. The summit platform averages 4.7 vents/km2, and this concentration supports previously proposed mechanisms for producing higher elevations and steeper slopes in the central part of the volcano. Temporal changes in the plumbing system and/or magma supply, rate are suggested by the change in aa:pahoehoe ratio; it appears that in the past, low effusion rate eruptions were more common (perhaps from a filled caldera), whereas more recently, high effusion rate eruptions have dominated.

The caldera of Volcan Fernandina: a remote sensing study of its structure and recent activity

Air photographs taken in 1946, 1960, and 1982, together with SPOT HVR-1 images obtained in April and October of 1988, are used to characterize recent activity in and around the caldera of Fernandina Volcano, West Galapagos Islands. The eruptive and collapse events during this time span appear to be distributed in a NW-SE band across the summit and caldera. On the flanks of the volcano, subtle topographic ridges indicate that this is a long-term preferred orientation of extra-caldera activity as well (although radial and arcuate fissures are found on all sectors). The caldera is formed from the coalescence of multiple collapse features that are also distributed along a NW-SE direction, and these give the caldera its elongate and scalloped outline. The NW and SE benches consist of lavas that ponded in once-separated depressions that have been incorporated into the caldera by more recent collapse. The volume of individual eruptions within the caldera over the observed 42 years appears to be small (∼4x106 m3) in comparison to the volumes of individual flows exposed in the caldera walls (∼120–150x106 m3). Field observations (in 1989) of lavas exposed in the caldera walls and their cross-cutting relationships show that there have been at least three generations of calderas, and that at times each was completely filled. An interplay between a varying supply rate to the volcano and a regional stress regime is suggested to be the cause of long-term spatial and volumetric variations in activity. When supply is high, the caldera is filled in relative to collapse and dikes tend to propagate in all directions through the edifice. At other times (such as the present) supply is relatively low; eruptions are small, the caldera is far from being filled in, and dike propagation is influenced by an extra-volcano stress regime.

Analysis of active volcanoes from the earth observing system

Abstract A study of volcanic activity and its effects on the atmosphere is one of 28 interdisciplinary investigations, for the Earth Observing System (EOS), due to be launched in 1997 and 1999. The volcanology investigation will include long- and short-term monitoring of selected volcanoes, the detection of precursory activity associated with unanticipated eruptions, and the detailed study of on-going eruptions. The data collected will allow us to address two aspects of volcanism: volcanic padforms and the atmospheric effects of eruptions. A variety of instruments on the two NASA EOS platforms, together with supplemental data from the Japanese and European platforms, will enable the study of local- to regional-scale thermal and deformational features of volcanoes, and the chemical and structural features of volcanic eruption plumes and aerosols. This investigation fits well within the overall goal of the EOS Project, which is to study the regional and global interrelationships between components of the Earth System, because it specifically investigates the links between volcanism, atmospheric chemistry and short-term (1–3 year) climate change.

Quantifying the effect of rheology on lava-flow margins using fractal geometry

This study aims at quantifying the effect of rheology on plan-view shapes of lava flows using fractal geometry. Plan-view shapes of lava flows are important because they reflect the processes governing flow emplacement and may provide insight into lava-flow rheology and dynamics. In our earlier investigation (Bruno et al. 1992), we reported that flow margins of basalts are fractal, having a characteristic shape regardless of scale. We also found we could use fractal dimension (D, a parameter which quantifies flow-margin convolution) to distinguish between the two endmember types of basalts: a′ a (D: 1.05–1.09) and pahoehoe (D: 1.13–1.23). In this work, we confirm those earlier results for basalts based on a larger database and over a wider range of scale (0.125 m–2.4 km). Additionally, we analyze ten silicic flows (SiO2: 52–74%) over a similar scale range (10 m–4.5 km). We note that silicic flows tend to exhibit scale-dependent, or non-fractal, behavior. We attribute this breakdown of fractal behavior at increased silica contents to the suppression of small-scale features in the flow margin, due to the higher viscosities and yield strengths of silicic flows. These results suggest we can use the fractal properties of flow margins as a remote-sensing tool to distinguish flow types. Our evaluation of the nonlinear aspects of flow dynamics indicates a tendency toward fractal behavior for basaltic lavas whose flow is controlled by internal fluid dynamic processes. For silicic flows, or basaltic flows whose flow is controlled by steep slopes, our evaluation indicates non-fractal behavior, consistent with our observations.