Serena Viti

Evaporation of ices near massive stars: models based on laboratory temperature programmed desorption data

Hot cores and their precursors contain an integrated record of the physics of the collapse process in the chemistry of the ices deposited during that collapse. In this paper, we present results from a new model of the chemistry near high-mass stars in which the desorption of each species in the ice mixture is described as indicated by new experimental results obtained under conditions similar to those in hot cores. Our models show that provided there is a monotonic increase in the temperature of the gas and dust surrounding the protostar, the changes in the chemical evolution of each species due to differential desorption are important. The species H2S, SO, SO2, OCS, H2CS, CS, NS, CH3OH, HCOOCH3 ,C H 2CO, C2H5OH show a strong time dependence that may be a useful signature of time evolution in the warm-up phase as the star moves on to the main sequence. This preliminary study demonstrates the consequences of incorporating reliable temperature programmed desorption data into chemical models. Ke yw ords: stars: formation ‐ ISM: abundances ‐ ISM: clouds ‐ ISM: molecules.

A photon dominated region code comparison study

Aims. We present a comparison between independent computer codes, modeling the physics and chemistry of interstellar photon dominated regions (PDRs). Our goal was to understand the mutual differences in the PDR codes and their effects on the physical and chemical structure of the model clouds, and to converge the output of different codes to a common solution. Methods. A number of benchmark models have been created, covering low and high gas densities n = 10 3 , 10 5.5 cm −3 and far ultraviolet intensities χ = 10, 10 5 in units of the Draine field (FUV: 6 < h ν< 13.6 eV). The benchmark models were computed in two ways: one set assuming constant temperatures, thus testing the consistency of the chemical network and photo-processes, and a second set determining the temperature self consistently by solving the thermal balance, thus testing the modeling of the heating and cooling mechanisms accounting for the detailed energy balance throughout the clouds. Results. We investigated the impact of PDR geometry and agreed on the comparison of results from spherical and plane-parallel PDR models. We identified a number of key processes governing the chemical network which have been treated differently in the various codes such as the effect of PAHs on the electron density or the temperature dependence of the dissociation of CO by cosmic ray induced secondary photons, and defined a proper common treatment. We established a comprehensive set of reference models for ongoing and future PDR model bench-marking and were able to increase the agreement in model predictions for all benchmark models significantly. Nevertheless, the remaining spread in the computed observables such as the atomic fine-structure line intensities serves as a warning that there is still a considerable uncertainty when interpreting astronomical data with our models.Aims. We present a comparison between independent computer codes, modeling the physics and chemistry of photon dominated regions (PDRs). Our goal was to understand the mutual differences in the PDR codes and their effects on the physical and chemical structure of the model clouds, and to converge the output of different codes to a common solution. Methods. A number of benchmark models have been calculated, covering low and high gas densities n = 103, 105.5 cm−3 and far ultraviolet intensities χ = 10, 105 (FUV: 6 < h ν < 13.6 eV). The benchmark models were computed in two ways: one set assuming constant temperatures, thus testing the consistency of the chemical network and photo-reactions, and a second set determining the temperature self consistently by solving the thermal balance, thus testing the modeling of the heating and cooling mechanisms accounting for the detailed energy balance throughout the clouds. Results. We investigated the impact of PDR geometry and agreed on the comparison of results from spherical and plane-parallel PDR models. We identified a number of key processes governing the chemical network which have been treated differently in the various codes such as the effect of PAHs on the electron density or the temperature dependence of the dissociation of CO by cosmic ray induced secondary photons, and defined a proper common treatment. We established a comprehensive set of reference models for ongoing and future PDR modeling and were able to increase the agreement in model predictions for all benchmark models significantly. Nevertheless, the remaining spread in the computed observables such as the atomic fine-structure line intensities serves as a warning that the astronomical data should not be overinterpreted.

Water in Star-forming Regions with the Herschel Space Observatory (WISH). I. Overview of Key Program and First Results

Water In Star-forming regions with Herschel (WISH) is a key program on the Herschel Space Observatory designed to probe the physical and chemical structures of young stellar objects using water and related molecules and to follow the water abundance from collapsing clouds to planet-forming disks. About 80 sources are targeted, covering a wide ranee of luminosities-from low ( 10(5) L-circle dot)-and a wide range of evolutionary stages-from cold prestellar cores to warm protostellar envelopes and outflows to disks around young stars. Both the HIFI and PACS instruments are used to observe a variety of lines of H2O, (H2O)-O-18 and chemically related species at the source position and in small maps around the protostars and selected outflow positions. In addition, high-frequency lines of CO, (CO)-C-13, and (CO)-O-18 are obtained with Herschel and are complemented by ground-based observations of dust continuum, HDO, CO and its isotopologs, and other molecules to ensure a self-consistent data set for analysis. An overview of the scientific motivation and observational strategy of the program is given, together with the modeling approach and analysis tools that have been developed. Initial science results are presented. These include a lack of water in cold gas at abundances that are lower than most predictions, strong water emission from shocks in protostellar environments, the importance of UV radiation in heating the gas along outflow walls across the full range of luminosities, and surprisingly widespread detection of the chemically related hydrides OH+ and H2O+ in outflows and foreground gas. Quantitative estimates of the energy budget indicate that H2O is generally not the dominant coolant in the warm dense gas associated with protostars. Very deep limits on the cold gaseous water reservoir in the outer regions of protoplanetary disks are obtained that have profound implications for our understanding of grain growth and mixing in disks.

Molecular line intensities as measures of cloud masses – I. Sensitivity of CO emissions to physical parameter variations

A reliable estimate of the molecular gas content in galaxies plays a crucial role in determining their dynamical and star-forming properties. However, H-2, the dominant molecular species, is difficult to observe directly, particularly in the regions where most molecular gas is thought to reside. Its mass is therefore commonly inferred by assuming a direct proportionality with the integrated intensity of the (CO)-C-12(J = 1 --> 0) emission line, using a CO-to-H-2 conversion factor, X. Although a canonical value for X is used extensively in such estimates, there is increasing evidence, both theoretical and observational, that the conversion factor may vary by over an order of magnitude under conditions different from those of the local neighbourhood. In an effort to understand the influence of changing environmental conditions on the conversion factor, we derive theoretical estimates of X for a wide range of physical parameters using a photon-dominated region (PDR) time-dependent chemical model, benchmarking key results against those of an independent PDR code to ensure reliability. Based on these results, the sensitivity of the X factor to change in each physical parameter is interpreted in terms of the chemistry and physical processes within the cloud. In addition to confirming previous observationally derived trends, we find that the time-dependence of the chemistry, often neglected in such models, has a considerable influence on the value of the conversion factor.

Water cooling of shocks in protostellar outflows: Herschel-PACS map of L1157

Context. The far-IR/sub-mm spectral mapping facility provided by the Herschel-PACS and HIFI instruments has made it possible to obtain, for the first time, images of H2O emission with a spatial resolution comparable to ground based mm/sub-mm observations. Aims. In the framework of the Water In Star-forming regions with Herschel (WISH) key program, maps in water lines of several outflows from young stars are being obtained, to study the water production in shocks and its role in the outflow cooling. This paper reports the first results of this program, presenting a PACS map of the o-H2O 179 mu m transition obtained toward the young outflow L1157. Methods. The 179 mu m map is compared with those of other important shock tracers, and with previous single-pointing ISO, SWAS, and Odin water observations of the same source that allow us to constrain the H2O abundance and total cooling. Results. Strong H2O peaks are localized on both shocked emission knots and the central source position. The H2O 179 mu m emission is spatially correlated with emission from H-2 rotational lines, excited in shocks leading to a significant enhancement of the water abundance. Water emission peaks along the outflow also correlate with peaks of other shock-produced molecular species, such as SiO and NH3. A strong H2O peak is also observed at the location of the proto-star, where none of the other molecules have significant emission. The absolute 179 mu m intensity and its intensity ratio to the H2O 557 GHz line previously observed with Odin/SWAS indicate that the water emission originates in warm compact clumps, spatially unresolved by PACS, having a H2O abundance of the order of 10(-4). This testifies that the clumps have been heated for a time long enough to allow the conversion of almost all the available gas-phase oxygen into water. The total H2O cooling is similar to 10(-1) L-circle dot, about 40% of the cooling due to H-2 and 23% of the total energy released in shocks along the L1157 outflow.

Herschel spectral surveys of star-forming regions - Overview of the 555–636 GHz range

High resolution line spectra of star-forming regions are mines of information: they provide unique clues to reconstruct the chemical, dynamical, and physical structure of the observed source. We present the first results from the Herschel key project “Chemical HErschel Surveys of Star forming regions”, CHESS. We report and discuss observations towards five CHESS targets, one outflow shock spot and four protostars with luminosities bewteen 20 and 2 × 105 L_ȯ: L1157-B1, IRAS 16293-2422, OMC2-FIR4, AFGL 2591, and NGC 6334I. The observations were obtained with the heterodyne spectrometer HIFI on board Herschel, with a spectral resolution of 1 MHz. They cover the frequency range 555-636 GHz, a range largely unexplored before the launch of the Herschel satellite. A comparison of the five spectra highlights spectacular differences in the five sources, for example in the density of methanol lines, or the presence/absence of lines from S-bearing molecules or deuterated species. We discuss how these differences can be attributed to the different star-forming mass or evolutionary status. Herschel is an ESA space observatory with science instruments provided by European-led principal Investigator consortia and with important participation from NASA.Figures [see full textsee full text]-[see full textsee full text] and Tables 3, 4 (pages 6 to 8) are only available in electronic form at http://www.aanda.org

C i lines as tracers of molecular gas, and their prospects at high redshifts

We examine the fine structure lines

The JCMT Legacy Survey of the Gould Belt: a first look at Orion B with HARP

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L1157-B1: WATER AND AMMONIA AS DIAGNOSTICS OF SHOCK TEMPERATURE

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