Shaun Berry

Laser-induced fluorescence-cued, laser-induced breakdown spectroscopy biological-agent detection

Methods for accurately characterizing aerosols are required for detecting biological warfare agents. Currently, fluorescence-based biological agent sensors provide adequate detection sensitivity but suffer from high false-alarm rates. Combining single-particle fluorescence analysis with laser-induced breakdown spectroscopy (LIBS) provides additional discrimination and potentially reduces false-alarm rates. A transportable UV laser-induced fluorescence-cued LIBS test bed has been developed and used to evaluate the utility of LIBS for biological-agent detection. Analysis of these data indicates that LIBS adds discrimination capability to fluorescence-based biological-agent detectors. However, the data also show that LIBS signatures of biological agent simulants are affected by washing. This may limit the specificity of LIBS and narrow the scope of its applicability in biological-agent detection.

Versatile alignment layer method for new types of liquid crystal photonic devices

Liquid crystal photonic devices are becoming increasingly popular. These devices often present a challenge when it comes to creating a robust alignment layer in pre-assembled cells. In this paper, we describe a method of infusing a dye into a microcavity to produce an effective photo-definable alignment layer. However, previous research on such alignment layers has shown that they have limited stability, particularly against subsequent light exposure. As such, we further describe a method of utilizing a pre-polymer, infused into the microcavity along with the liquid crystal, to provide photostability. We demonstrate that the polymer layer, formed under ultraviolet irradiation of liquid crystal cells, has been effectively localized to a thin region near the substrate surface and provides a significant improvement in the photostability of the liquid crystal alignment. This versatile alignment layer method, capable of being utilized in devices from the described microcavities to displays, offers significant promise for new photonics applications.

High Efficiency Large-Angle Pancharatnam Phase Deflector Based on Dual Twist Design

We have previously shown through simulation that an optical beam deflector based on the Pancharatnam (geometric) phase can provide high efficiency with up to 80° deflection using a dual-twist structure for polarization-state control [Appl. Opt.54, 10035 (2015)]. In this report, we demonstrate that its optical performance is as predicted and far beyond what could be expected for a conventional diffractive optical device. We provide details about construction and characterization of a ± 40° beam-steering device with 90% diffraction efficiency based on our dual-twist design at a 633nm wavelength.

New Generation of Digital Microfluidic Devices

This paper reports on the design, fabrication, and performance of micro-sized fluidic devices that use electrowetting to control and transport liquids. Using standard microfabrication techniques, new pumping systems are developed with significantly more capability than open digital microfluidic systems that are often associated with electrowetting. This paper demonstrates that, by integrating closed microchannels with different channel heights and using electrowetting actuation, liquid interfaces can be controlled, and pressure work can be done, resulting in fluid pumping. The operation of two different on-chip pumps and devices that can form water drops is described. In addition, a theory is presented to explain the details of single-electrode actuation in a closed channel.

Effects of humidity and surface on photoalignment of brilliant yellow

ABSTRACT Controlling and optimising the alignment of liquid crystals is a crucial process for display application. Here, we investigate the effects of humidity and surface types on photoalignment of an azo-dye brilliant yellow (BY). Specifically, the effect of humidity on the photoalignment of BY was studied at the stage of substrate storage before coating, during the spin-coating process, between film coating and exposure, and after exposure. Surprising results are the drastic effect of humidity during the spin-coating process, the humidity annealing to increase the order of the BY layer after exposure and the dry annealing to stabilise the layer. Our results are interpreted in terms of the effect of water on the aggregation of BY. The type of surface studied had minimal effects. Thin BY films (about 3 nm thickness) were sensitive to the hydrophilicity of the surface while thick BY films (about 30 nm thickness) were not affected by changing the surface. The results of this paper allow for the optimisation of the BY photoalignment for liquid crystal display application as well as a better understanding of the BY photoalignment mechanism. Graphical Abstract

Microhydraulic Electrowetting Actuators

The conversion of electrical to mechanical power on a sub-centimeter scale is a key technology in many microsystems and energy harvesting devices. In this paper, we present a type of a capacitive energy conversion device that uses capillary pressure and electrowetting to reversibly convert electrical power to hydraulic power. These microhydraulic actuators use a high surface-to-volume ratio to deliver high power at a relatively low voltage with an energy conversion efficiency of over 65%. The capillary pressure generated grows linearly with shrinking capillary diameter, as does the frequency of actuation. We present the pressure, frequency, and power scaling properties of these actuators and demonstrate that power density scales up as the inverse capillary diameter squared, leading to high-efficiency actuators with a strength density exceeding biological muscle. Two potential applications for microhydraulics are also demonstrated: soft-microrobotics and energy harvesting.

Reversible Electrowetting on Dual-Scale-Patterned Corrugated Microstructured Surfaces

The ability to reversibly switch between a hydrophobic Cassie state and a hydrophilic Wenzel state is often not possible on textured surfaces because of energy barriers which result from the geometry of the microstructure. In this paper, we report on a simple microstructure geometry that allows an aqueous droplet to be reversibly switched between these states by the application of electrowetting. We demonstrate reversible electrowetting in air on microstructured surfaces consisting of parallel corrugations and show that this geometry can be engineered to produce a Cassie state and can be electrically controlled to switch to a Wenzel wetting state having high adhesion. When the electric field was removed, we observed spontaneous dewetting along the corrugations as the droplet transitioned from the Wenzel state back to a Cassie state.

Validation of the trapped charge model of electrowetting contact angle saturation on lipid bilayers

The problem of modeling contact angle saturation in electrowetting has resisted a number of concentrated efforts by leading researchers. Several models have been proposed, from charge trapping, to droplet ejection, to thermodynamic instability, but no consensus has been reached as to which model better describes the effect. In this paper, we validate the charge trapping based model of contact angle saturation in electrowetting on lipid bilayers, through careful analysis of charge movement between the liquid charge states and trapped charge states at the solid dielectric interface. We also describe a powerful new methodology for studying electrowetting systems by modeling them with an equivalent circuit and simulating the circuit using the SPICE circuit simulator.

Etching selectivity of indium tin oxide to photoresist in high density chlorine- and ethylene-containing plasmas

Etching of indium tin oxide (ITO) thin films in high density chlorine plasmas is studied, with the goal of increasing the etching selectivity to photoresist. The ITO etching rate increases with ethylene addition, but is not affected by BCl3 addition. ITO exhibits a threshold energy for ion etching, whereas the photoresist etches spontaneously in chlorine plasmas. The ITO:photoresist selectivity increases with BCl3 addition, ion bombardment energy, and C2H4 addition. It is proposed that the ITO etching rate is limited by desorption of InClx products, and that ethylene addition assists in scavenging oxygen from ITO leaving loosely bound In, which is more easily removed by physical sputtering.

A Scalable Fabrication Process for Liquid Crystal Based Uncooled Thermal Imagers

A novel sensor is being developed for a new uncooled imager technology that is scalable to large formats (tens of megapixels), which is greater than what is achieved by commercial microbolometer arrays. In this novel sensor, a liquid-crystal transducer is used to change a long-wavelength infrared scene into a visible image that can be detected using a conventional visible imager. This approach has the potential for making a more flexible thermal sensor that can be optimized for a variety of applications. In this paper, we describe the microfabrication processes required to create an array of sealed thermally isolated micro-cavities filled with liquid crystals to be used for an uncooled thermal imager. Experimental results from the fabricated arrays will also be discussed.