Shengcan Ma

Peculiarity of magnetoresistance in high pressure annealed Ni43Mn41Co5Sn11 alloy

Magnetic and resistance measurements have been carried out on a Ni43Mn41Co5Sn11 alloy annealed under high-pressure. Due to the existence of the intermediate phase, a change of slope in the temperature dependence of resistivity curves has been observed prior to the martensitic transformation for the high-pressure annealed alloy. As a consequence, two successive magnetoresistance peaks with the same sign are achieved around room-temperature, corresponding to the martensitic transformation and intermediate phase transition, respectively. The origin of the peculiarity of magnetoresistance properties in high-pressure annealed Ni43Mn41Co5Sn11 alloy is discussed.

The antiferromagnetic-ferromagnetic conversion and magnetostructural transformation in Mn-Ni-Fe-Ge ribbons

Two Mn-Ni-Fe-Ge ribbon samples are prepared. The ribbons reveal the complicated magnetization process with the variation of temperature and magnetic field. Strikingly, the antiferromagnetic-ferromagnetic conversion and competition are observed in the TiNiSi-type phase in these ribbons. The required field to complete the conversion decreases with increasing temperature. When completing conversion, the coupled magnetostructural transformation from the ferromagnetic TiNiSi-type to paramagnetic Ni2In-type state with large magnetic entropy changes near room temperature is achieved for these ribbons. However, it is found that the magnetic field would be difficult to drive ferromagnetic-paramagnetic magnetostructural transformation for these ribbons unlike temperature.

Giant magnetocaloric and magnetoresistance effects in ferrimagnetic Mn1.9Co0.1Sb alloy

Magnetic and transitional behaviors are investigated in Mn1.9Co0.1Sb intermetallic compound. Mn2Sb is a simple ferrimagnet with Neel temperature around 550 K. The Co-introduction results in the appearance of antiferromagnetic state, and therefore, the first-order magnetic transition occurs between antiferromagnetic and ferrimagnetic state, which can be induced by temperature/magnetic field, in Mn1.9Co0.1Sb alloy. Accordingly, a magnetic entropy change as high as 5 J kg−1 K−1 and a large magnetoresistance of 46% under the field change of 10 and 50 kOe are achieved, respectively.

Driving higher magnetic field sensitivity of the martensitic transformation in MnCoGe ferromagnet

The sharp metamagnetic martensitic transformation (MMT) triggered by a low critical field plays a pivotal role in magnetoresponsive effects for ferromagnetic shape memory alloys (FSMAs). Here, a sharper magnetic-field-induced metamagnetic martensitic transformation (MFIMMT) is realized in Mn1−xCo1+xGe systems with a giant magnetocaloric effect around room temperature, which represents the lowest magnetic driving and completion fields as well as the largest magnetization difference around MFIMMT reported heretofore in MnCoGe-based FSMAs. More interestingly, a reversible MFIMMT with field cycling is observed in the Mn0.965Co0.035Ge compound. These results indicate that the consensus would be broken that the magnetic field is difficult to trigger the MMT for MnCoGe-based systems. The origin of a higher degree of sensitivity of martensitic transformation to the magnetic field is discussed based on the X-ray absorption spectroscopic results.

Tuning the metamagnetism in a metallic helical antiferromagnet

The antiferromagnetic (AFM)-ferromagnetic (FM) conversion in martensite was observed in Mn/Ni-substitution upon FM elements, such as Fe or Co, in MnNiGe helical antiferromagnets. Here, we report an AFM-FM conversion and consequently a sharp magnetic-field-driven metamagnetic martensitic transformation from paramagnetic (PM) austenite to FM martensite in the Ni- and Mn-substituted MnNiGe alloys with indium, a non-magnetic and large-sized main group element. Accordingly, a giant magnetocaloric effect such that a twofold increase of the magnetic entropy change in MnNi0.92GeIn0.08 and even a nearly threefold increase in the Mn0.92NiGeIn0.08 alloy is obtained with respect to the MnNiGe0.95In0.05 alloy. The origin of AFM-FM conversion and resultantly sharp magnetic-field-induced PM-FM metamagnetic transformation is discussed based on the first-principles calculations and X-ray absorption spectroscopic results.The antiferromagnetic (AFM)-ferromagnetic (FM) conversion in martensite was observed in Mn/Ni-substitution upon FM elements, such as Fe or Co, in MnNiGe helical antiferromagnets. Here, we report an AFM-FM conversion and consequently a sharp magnetic-field-driven metamagnetic martensitic transformation from paramagnetic (PM) austenite to FM martensite in the Ni- and Mn-substituted MnNiGe alloys with indium, a non-magnetic and large-sized main group element. Accordingly, a giant magnetocaloric effect such that a twofold increase of the magnetic entropy change in MnNi0.92GeIn0.08 and even a nearly threefold increase in the Mn0.92NiGeIn0.08 alloy is obtained with respect to the MnNiGe0.95In0.05 alloy. The origin of AFM-FM conversion and resultantly sharp magnetic-field-induced PM-FM metamagnetic transformation is discussed based on the first-principles calculations and X-ray absorption spectroscopic results.

Microstructure, magnetic and magnetocaloric properties in Ni42.9Co6.9Mn38.3Sn11.9 alloy ribbons

The microstructure, magnetic and magnetocaloric properties are investigated in the melt-spun and annealed Ni42.9Co6.9Mn38.3Sn11.9 ribbons. The columnar grains grow perpendicular to ribbon surfaces. After annealing, the grain size increases greatly. Meanwhile, the parent phase is suppressed and therefore L10 martensite predominates, indicating obvious shift of martensitic transformation to high temperature. More interestingly, the martensite variants are distinctly observed on the fractured cross-section of annealed ribbons, not just on the free surface in general. The significant enhancement of magnetic entropy change and effective refrigerant capacities with relatively smaller thermal hysteresis make annealed ribbons potential candidate in magnetic refrigeration around room temperature.

Improved magnetic properties and thermal stabilities of Pr-Nd-Fe-B sintered magnets by Hf addition

Nd2Fe14B-type permanent magnets have been widely applied in various fields such as wind power, voice coil motors, and medical instruments. The large temperature dependence of coercivity, however, limits their further applications. We have systematically investigated the magnetic properties, thermal stabilities and coercivity mechanisms of the (Pr0.2Nd0.8)13Fe81-xB6Hfx (x=0, 0.5) nanocrystalline magnets fabricated by a spark plasma sintering (SPS) technique. The results indicate that the influence of Hf addition is significant on magnetic properties and thermal stabilities of the (PrNd)2Fe14B-type sintered magnets. It is shown that the sample with x = 0.5 at 300 K has much higher coercivity and remanent magnetization than those counterparts without Hf. The temperature coefficients of remanence (α) and coercivity (β) of the (Pr0.2Nd0.8)13Fe81-xB6Hfx magnets are improved significantly from -0.23 %/K, -0.57 %/K for the sample at x = 0 to -0.17 %/K, -0.49 %/K for the sample at x = 0.5 in the temperature range ...

Interstitial effects of B and Li on the magnetic phase transition and magnetocaloric effects in Gd2In alloy

Interstitial effects of B and Li on the phase transition and magnetocaloric effect in Gd2In alloys had been studied. The antiferromagnetic (AFM) - ferromagnetic (FM) phase transition was found to be of first-order nature while ferromagnetic - paramagnetic (PM) phase transition was of second-order nature in B- or Li-doped Gd2In alloys. AFM-FM phase transition temperature was increased while FM-PM phase transition was decreased with more doping concentrations. During AFM-FM phase transition, the slope of temperature-dependent critical field (μ0Hcr) was increased by increased doping amounts. The magnetic entropy changes under small field change were enhanced by B and Li addition, which showed the beneficial effects of B and Li additions.

Microstructure evolution and coercivity enhancement in Nd-Fe-B thin films diffusion-processed by R-Al alloys (R=Nd, Pr)

Diffusion process by Nd-Al and Pr-Al alloys was compared and investigated in Nd-Fe-B thin films. Enhanced coercivity 2.06T and good squareness was obtained by using Pr85Al15 and Nd85Al15 alloys as diffusion sources. But the coercivity of diffusion-processed thin films by Pr70Al30 and Pr55Al45 alloys decreased to 2.04T and 1.82T. High ambient coercivity of 2.26T was achieved in diffusion-processed thin film by Nd70Al30 leading to an improved coercivity thermal stability because Nd2Fe14B grains were enveloped by Nd-rich phase as seen by transmission electron microscopy Nd-loss image. Meanwhile, microstructure-dependent parameters α and Neff were improved. However, high content of Al in diffusion-processed thin film by Nd55Al45 lead to degraded texture and coercivity.

Effect of Ga addition on the valence state of Ce and magnetic properties of melt-spun Ce17Fe78-xB6Gax (x = 0-1.0) ribbons

The Ce17Fe78-xB6Gax (x=0-1.0) ribbons were fabricated by a melt-spinning technique in order to study the mechanism of the valence variation of Ce and their magnetic properties as well as improve the thermal stability of Ce-based rare earth permanent magnets. The systematic investigations of the Ce17Fe78-xB6Gax (x=0-1.0) alloys show that the room-temperature coercivity increases significantly from 352 kA/m at x = 0 to 492 kA/m at x = 1.0. The Curie temperature (Tc) increases monotonically from 424.5 K to 433.6 K, and the temperature coefficients of remanence (α) and coercivity (β) of the ribbons are better off from -0.56 %/K, -0.75 %/K for x = 0 to -0.45 %/K, -0.65 %/K for x = 0.75 in the temperature range of 300–400 K, respectively. The Ce L3-edge X-ray absorption near edge structure (XANES) spectrums reveal that there is more Ce4+ in ribbons under total electron yield than fluorescence yield as Ce has a high affinity with oxygen. The weight of Ce3+ increases while the weight of Ce4+ decreases in Ga-added...