Shin-ichiro Nakajima

High-valent metalloporphyrin, Fe(tpp)OTf, catalyzed rearrangement of α,β-epoxy ketones into 1,2-diketones

Iron(III) tetraphenylporphyrin triflate, Fe(tpp)OTf, works as an efficient and characteristic Lewis acid catalyst in the selective rearrangement of α,β-epoxy ketones into 1,2-diketones.

METALLOPORPHYRIN-CATALYZED REGIOSELECTIVE REARRANGEMENT OF MONOALKYL-SUBSTITUTED EPOXIDES INTO ALDEHYDES

Abstract Iron(III) tetraphenylporphyrin, Fe(tpp)OTf, is an efficient catalyst for the regioselective rearrangement of simple monoalkyl-substituted epoxides into the corresponding aldehydes.

Metallophthalocyanine complex, Cr(TBPC)OTf: an efficient, recyclable Lewis acid catalyst in the regio- and stereoselective rearrangement of epoxides to aldehydes

The metallophthalocyanine complex Cr(TBPC)OTf works as a highly efficient, recyclable Lewis acid catalyst for the regio- and stereoselective rearrangements of epoxides to aldehydes.