Sonia Bhandari
University of Delhi
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Featured researches published by Sonia Bhandari.
CrystEngComm | 2015
Nidhi Sinha; Sonia Bhandari; Harsh Yadav; Geeta Ray; Sanjay Godara; Nidhi Tyagi; Jyoti Dalal; Sonu Kumar; Binay Kumar
Single crystals of 0.01 and 0.02 mol% crystal violet dye doped triglycine sulfate (NH2CH2COOH)3·H2SO4 (TGS) have been grown by a slow evaporation technique. Enhanced dielectric, optical, thermal and mechanical properties have been achieved by dye doping. Monoclinic structures showing particular coloring patterns and morphology change with dye concentration were obtained. Various functional groups and dye incorporation in the grown crystals were confirmed qualitatively by FTIR and Raman analysis. A significant increase in Curie temperature from 50 to 55 °C with a decrease in maximum permittivity has been observed. The UV-vis spectra showed an increased transmittance window and an increased optical band gap from 5.61 to 6.11 eV as a result of doping. An increase in the sharpness and intensity of the photoluminescence peak with a blue shift has been observed in doped crystals. The thermal stability and the decomposition temperature were found to increase by about 10 °C in 0.01 mol% dye doped TGS. The mechanical strength of the grown crystals was estimated by the Vickers microhardness test and was found to be high for dye doped TGS. A high piezoelectric charge coefficient d33 of 16 pC N−1 was observed for pure TGS which decreased as a result of the dye effect. The fabrication of a patch antenna was carried out after simulating its resonant frequency, making it suitable for telecommunication applications.
CrystEngComm | 2014
Sonia Bhandari; Nidhi Sinha; Geeta Ray; Binay Kumar
We have grown single crystals of lead-free (Na0.5Bi0.5)TiO3–(K0.5Bi0.5)TiO3 (abbreviated as BNKT) as promising materials for ferroelectric applications. The single crystals were grown by a high temperature self-flux solution method in which A-site compounds were used as complex flux. The crystal structure was analyzed by means of an X-ray diffraction technique showing a perovskite phase with tetragonal symmetry at room temperature. The surface morphology of the BNKT crystals was examined by scanning electron microscopy (SEM) and was found depicting a layered like hopper structure. The temperature and frequency dependence of the dielectric constant and loss for the as-grown single crystals was investigated, showing a decrease in Tmax from 316 °C at 50 kHz to 310 °C at 1 MHz. To study the degree of dielectric relaxation, modified power law fitting and Lorentz type quadratic fitting were performed. The relative composition of the studied sample and its phase transition behavior were confirmed by Raman spectroscopy. The piezoelectric coefficient d33 with optimized poling field was found to be 216 pC N−1. The ferroelectric response of the BNKT crystals with temperature at an applied field of 37 kV cm−1 was studied. The results suggest a promising approach for growing high quality alkali based single crystals with a relatively large size for piezoelectric and ferroelectric applications.
Journal of Asian Ceramic Societies | 2016
Abid Hussain; Nidhi Sinha; Sonia Bhandari; Harsh Yadav; Binay Kumar
Abstract A near MPB composition of 0.64PMN–0.36PT ceramic has been synthesized by solid-state reaction technique using columbite precursor. Sintering at 1030 °C resulted in a single perovskite phase with tetragonal structure having uniform and dense microstructure as revealed by powder XRD, Raman spectroscopy and FESEM analyses. An excellent dielectric response was obtained with room temperature dielectric permittivity value of 142 and high-phase transition temperature (Tm) of 210 °C at 1 kHz. A huge value of piezoelectric charge coefficient (490 pC/N) was obtained, which shows potential of PMN–PT for piezoelectric device applications. Well-shaped and fatigue-free P–E hysteresis loops over a wide temperature range of 30–230 °C were traced. A very large value of pyroelectric coefficient (p ∼ 2739.2 μC m−2 °C−1) was obtained.
CrystEngComm | 2014
Geeta Ray; Nidhi Sinha; Sonia Bhandari; Budhendra Singh; Igor Bdikin; Binay Kumar
High quality lead free ferroelectric single crystals of 0.94[Na0.5K0.5NbO3]–0.06LiNbO3 (NKLN) were grown by the self-flux method. The crystals were characterized for structural and dielectric properties, piezo/ferro response (both on the macro and microlevel) and electrical behavior. The characterization confirmed a perfectly homogeneous stoichiometry having negligible defects in the sample. Further, the crystals were found to exhibit high Curie phase transition (~420 °C) with a high value of d33 coefficient (=115 pC N−1) and remnant polarization (=4.01 μC cm−2 at 30 °C). Its pyroelectric coefficient was found to be ~309.8 μC m−2 °C−1. In addition, the crystals did not show any fatigue. Further, ferroelectric domains were analyzed using piezoresponse force microscopy and the effective d33 coefficient on the microlevel was calculated to be ~80 pm V−1 after a 20 min relaxation of 75 V induced bias. The results suggest NKLN crystals to be a very promising material in the family of available lead free materials for various ferroelectric applications.
Ceramics International | 2014
Nidhi Sinha; Geeta Ray; Sonia Bhandari; Sanjay Godara; Binay Kumar
Chemical Physics Letters | 2014
Sonia Bhandari; Nidhi Sinha; Geeta Ray; Binay Kumar
Scripta Materialia | 2014
Sonia Bhandari; Nidhi Sinha; Geeta Ray; Binay Kumar
Scripta Materialia | 2015
Geeta Ray; Nidhi Sinha; Sonia Bhandari; Binay Kumar
Crystal Growth & Design | 2015
Sonia Bhandari; Binay Kumar
Ceramics International | 2016
Sonia Bhandari; Nidhi Sinha; Binay Kumar