Sonja Pullen

Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework

A molecular proton reduction catalyst [FeFe](dcbdt)(CO)6 (1, dcbdt = 1,4-dicarboxylbenzene-2,3-dithiolate) with structural similarities to [FeFe]-hydrogenase active sites has been incorporated into a highly robust Zr(IV)-based metal–organic framework (MOF) by postsynthetic exchange (PSE). The PSE protocol is crucial as direct solvothermal synthesis fails to produce the functionalized MOF. The molecular integrity of the organometallic site within the MOF is demonstrated by a variety of techniques, including X-ray absorption spectroscopy. In conjunction with [Ru(bpy)3]2+ as a photosensitizer and ascorbate as an electron donor, MOF-[FeFe](dcbdt)(CO)6 catalyzes photochemical hydrogen evolution in water at pH 5. The immobilized catalyst shows substantially improved initial rates and overall hydrogen production when compared to a reference system of complex 1 in solution. Improved catalytic performance is ascribed to structural stabilization of the complex when incorporated in the MOF as well as the protection of reduced catalysts 1– and 12– from undesirable charge recombination with oxidized ascorbate.

Structural dynamics inside a functionalized metal–organic framework probed by ultrafast 2D IR spectroscopy

Significance A unique aspect of metal–organic frameworks (MOFs) is their structural flexibility coexisting with a degree of regularity. Adsorbed guest molecules can cause MOF pore shapes to deform. Pore shape changes may be related to the high capacity and selectivity of the MOFs for gas adsorption and other processes. MOF flexibility and other properties are influenced by fast dynamics of the framework. Direct measurements to characterize fast motions of the MOFs have not been applied previously. We show that 2D IR spectroscopy can be performed on functionalized MOFs. We use 2D IR and other ultrafast IR methods to elucidate the timescales for ultrafast structural fluctuations and how they are influenced by a solvent filling the pores. The structural elasticity of metal–organic frameworks (MOFs) is a key property for their functionality. Here, we show that 2D IR spectroscopy with pulse-shaping techniques can probe the ultrafast structural fluctuations of MOFs. 2D IR data, obtained from a vibrational probe attached to the linkers of UiO-66 MOF in low concentration, revealed that the structural fluctuations have time constants of 7 and 670 ps with no solvent. Filling the MOF pores with dimethylformamide (DMF) slows the structural fluctuations by reducing the ability of the MOF to undergo deformations, and the dynamics of the DMF molecules are also greatly restricted. Methodology advances were required to remove the severe light scattering caused by the macroscopic-sized MOF particles, eliminate interfering oscillatory components from the 2D IR data, and address Förster vibrational excitation transfer.

Direct Observation of Key Catalytic Intermediates in a Photoinduced Proton Reduction Cycle with a Diiron Carbonyl Complex

The structure and reactivity of intermediates in the photocatalytic cycle of a proton reduction catalyst, [Fe2(bdt)(CO)6] (bdt = benzenedithiolate), were investigated by time-resolved spectroscopy. The singly reduced catalyst [Fe2(bdt)(CO)6](-), a key intermediate in photocatalytic H2 formation, was generated by reaction with one-electron reductants in laser flash-quench experiments and could be observed spectroscopically on the nanoseconds to microseconds time scale. From UV/vis and IR spectroscopy, [Fe2(bdt)(CO)6](-) is readily distinguished from the two-electron reduced catalyst [Fe2(bdt)(CO)6](2-) that is obtained inevitably in the electrochemical reduction of [Fe2(bdt)(CO)6]. For the disproportionation rate constant of [Fe2(bdt)(CO)6](-), an upper limit on the order of 10(7) M(-1) s(-1) was estimated, which precludes a major role of [Fe2(bdt)(CO)6](2-) in photoinduced proton reduction cycles. Structurally [Fe2(bdt)(CO)6](-) is characterized by a rather asymmetrically distorted geometry with one broken Fe-S bond and six terminal CO ligands. Acids with pK(a) ≤ 12.7 protonate [Fe2(bdt)(CO)6](-) with bimolecular rate constants of 4 × 10(6), 7 × 10(6), and 2 × 10(8) M(-1) s(-1) (trichloroacetic, trifluoroacetic, and toluenesulfonic acids, respectively). The resulting hydride complex [Fe2(bdt)(CO)6H] is therefore likely to be an intermediate in photocatalytic cycles. This intermediate resembles structurally and electronically the parent complex [Fe2(bdt)(CO)6], with very similar carbonyl stretching frequencies.

Hydrogen evolution with nanoengineered ZnO interfaces decorated using a beetroot extract and a hydrogenase mimic

Herein, we report a nano-hybrid photo-system based on abundant elements for H2 production with visible light. The photo-systems proficiency relates to the novel ZnO nanocrystals employed. The ZnO carboxylate oligoethylene glycol shell enhances charge separation and accumulates reactive electrons for the photocatalytic process.

Functional small-molecules & polymers containing PC and AsC bonds as hybrid π-conjugated materials

Stable phospha- and arsaalkenes were used to synthesize polymers containing unsaturated PC and AsC moieties. The composition, chemical environment, structure, optical, and electronic properties of the monomers and polymers were elucidated. The incorporation of the heteroatom–carbon double bonded units efficiently perturbs the optoelectronics and solid state features of both monomeric and polymeric scaffolds. Proof-of principle work supports their responsive character through post-functionalisation and electrochromic behaviour. To the best of our knowledge, this is the first example of a polymer containing arsenic–carbon double bonds.

Photochemical Hydrogen Production with Metal-Organic Frameworks

Metal–Organic Frameworks (MOFs) have attracted increasing attention for the creation of solid-state platforms for catalysis applications. In this review article, we present strategies to employ MOF-based materials in photochemical hydrogen production. The scope ranges from the incorporation of single functions (catalyst or photosensitizer) to multifunctional MOFs that combine both light-harvesting and catalysis in one scaffold.

Homogeneous Cobalt/Vanadium Complexes as Precursors for Functionalized Mixed Oxides in Visible‐Light‐Driven Water Oxidation

The heterometallic complexes (NH4 )2 [Co(H2 O)6 ]2 [V10 O28 ]⋅4 H2 O (1) and (NH4 )2 [Co(H2 O)5 (β-HAla)]2 [V10 O28 ]⋅4 H2 O (2) have been synthesized and used for the preparation of mixed oxides as catalysts for water oxidation. Thermal decomposition of 1 and 2 at relatively low temperatures (<500 °C) leads to the formation of the solid mixed oxides CoV2 O6 /V2 O5 (3) and Co2 V2 O7 /V2 O5 (4). The complexes (1, 2) and heterogeneous materials (3, 4) act as catalysts for photoinduced water oxidation. A modification of the thermal decomposition procedure allowed the deposition of mixed metal oxides (MMO) on a mesoporous TiO2 film. The electrodes containing Co/V MMOs in TiO2 films were used for electrocatalytic water oxidation and showed good stability and sustained anodic currents of about 5 mA cm-2 at 1.72 V versus relative hydrogen electrode (RHE). This method of functionalizing TiO2 films with MMOs at relatively low temperatures (<500 °C) can be used to produce other oxides with different functionality for applications in, for example, artificial photosynthesis.

Direct evidence of catalyst reduction on dye and catalyst co-sensitized NiO photocathodes by mid-infrared transient absorption spectroscopy

Co-sensitization of molecular dyes and catalysts on semiconductor surfaces is a promising strategy to build photoelectrodes for solar fuel production.