Stephen Lane

The origin of accretionary lapilli

Experimental investigations in a recirculating wind tunnel of the mechanisms of formation of accretionary lapilli have demonstrated that growth is controlled by collision of liquid-coated particles, due to differences in fall velocities, and binding as a result of surface tension forces and secondary mineral growth. The liquids present on particle surfaces in eruption plumes are acid solutions stable at ≪ 100% relative humidity, from which secondary minerals, e.g. calcium sulphate and sodium chloride, precipitate prior to impact of accretionary lapilli with the ground. Concentric grain-size zones within accretionary lapilli build up due to differences in the supply of particular particle sizes during aggregate growth. Accretionary lapilli do not evolve by scavenging of particles by liquid drops followed by evaporation — a process which, in wind tunnel experiments, generates horizontally layered hemispherical aggregates. Size analysis of particles in the wind tunnel air stream and particles adhering to growing aggregates demonstrate that the aggregation coefficient is highly grain-size dependent. Theoretical simulation of accretionary lapilli growth in eruption plumes predicts maximum sizes in the range 0.7–20 mm for ash cloud thicknesses of 0.5–10 km respectively.

Giant magnetoresistance in electrodeposited superlattices

We have observed ‘‘giant magnetoresistance’’ in short‐period Cu/Co‐Ni‐Cu alloy superlattices electrodeposited from a single electrolyte under potentiostatic control. The superlattices were grown on polycrystalline Cu substrates which were removed before transport measurements were made. Room‐temperature magnetoresistances of over 15% in applied magnetic fields of up to 8 kOe were observed in superlattices having Cu layer thicknesses of less than 10 A.

Pressure changes associated with the ascent and bursting of gas slugs in liquid-filled vertical and inclined conduits

At basaltic volcanoes, the sources of long-period and very-long-period seismicity and acoustic signals are frequently described in terms of fluid dynamic processes, in particular the formation and ascent of gas slugs within the magma column and their bursting at the surface. To investigate pressure changes associated with these processes, two-phase flow experiments have been carried out in vertical and inclined pipes with both single gas slugs and a continuously supplied gas phase. The ascent of individual gas slugs is accompanied by strong dynamic pressure variations resulting from the flow of liquid around the slug. These dynamic transients generate sub-static pressures below the ascending slug in viscosity-controlled systems, and produce super-static pressures when the slug reaches the surface and motion ceases in inertia-dominated systems. Conduit inclination promotes a change of regime from bubbly to slug flow and favours an increase in size and velocity of the slugs at the expense of their frequency of occurrence during continuously supplied two-phase flow. The experimental pressure data support previous theoretical analyses of oscillatory sources in ascending slugs as the slugs approach the surface and burst. Pressure oscillations are also observed during the release of gas slugs and in their wake region.

Gas slug ascent through changes in conduit diameter: Laboratory insights into a volcano‐seismic source process in low‐viscosity magmas

Seismic signals generated during the flow and degassing of low-viscosity magmas include long-period (LP) and very-long-period (VLP) events, whose sources are often attributed to dynamic fluid processes within the conduit. We present the results of laboratory experiments designed to investigate whether the passage of a gas slug through regions of changing conduit diameter could act as a suitable source mechanism. A vertical, liquid-filled glass tube featuring a concentric diameter change was used to provide canonical insights into potentially deep or shallow seismic sources. As gas slugs ascend the tube, we observe systematic pressure changes varying with slug size, liquid depth, tube diameter, and liquid viscosity. Gas slugs undergoing an abrupt flow pattern change upon entering a section of significantly increased tube diameter induce a transient pressure decrease in and above the flare and an associated pressure increase below it, which stimulates acoustic and inertial resonant oscillations. When the liquid flow is not dominantly controlled by viscosity, net vertical forces on the apparatus are also detected. The net force is a function of the magnitude of the pressure transients generated and the tube geometry, which dictates where, and hence when, the traveling pressure pulses can couple into the tube. In contrast to interpretations of related volcano-seismic data, where a single downward force is assumed to result from an upward acceleration of the center of mass in the conduit, our experiments suggest that significant downward forces can result from the rapid deceleration of relatively small volumes of downward-moving liquid.

Seismic source mechanism of degassing bursts at Kilauea Volcano, Hawaii:results from waveform inversion in the 10–50 s band

The current (March 2008 to February 2009) summit eruptive activity at Kilauea Volcano is characterized by explosive degassing bursts accompanied by very long period (VLP) seismic signals. We model the source mechanisms of VLP signals in the 10–50 s band using data recorded for 15 bursts with a 10‐station broadband network deployed in the summit caldera. To determine the source centroid location and source mechanism, we minimize the residual error between data and synthetics calculated by the finite difference method for a point source embedded in a homogeneous medium that takes topography into account. The VLP signals associated with the bursts originate in a source region ∼1 km below the eastern perimeter of Halemaumau pit crater. The observed waveforms are well explained by the combination of a volumetric component and a vertical single force component. For the volumetric component, several source geometries are obtained which equally explain the observed waveforms. These geometries include (1) a pipe dipping 64° to the northeast; (2) two intersecting cracks including an east striking crack (dike) dipping 80° to the north, intersecting a north striking crack (another dike) dipping 65° to the east; (3) a pipe dipping 58° to the northeast, intersecting a crack dipping 48° to the west–southwest; and (4) a pipe dipping 57° to the northeast, intersecting a pipe dipping 58° to the west–southwest. Using the dual‐crack model as reference, the largest volume change obtained among the 15 bursts is ∼24,400 m3, and the maximum amplitude (peak to peak) of the force is ∼20 GN. Each burst is marked by a similar sequence of deflation and inflation, trailed by decaying oscillations of the volumetric source. The vertical force is initially upward, synchronous with source deflation, then downward, synchronous with source reinflation, followed by oscillations with polarity opposite to the volumetric oscillations. This combination of force and volume change is attributed to pressure and momentum changes induced during a fluid dynamic source mechanism involving the ascent, expansion, and burst of a large slug of gas within the upper ∼150 m of the magma conduit. As the slug expands upon approach to the surface and more liquid becomes wall supported by viscous shear forces, the pressure below the slug decreases, inducing conduit deflation and an upward force on the Earth. The final rapid slug expansion and burst stimulate VLP and LP oscillations of the conduit system, which slowly decay due to viscous dissipation and elastic radiation. Consideration of the fluid dynamic arguments leads us to prefer the dual‐crack VLP source model as it is the only candidate model capable of producing plausible values of length scales and pressure changes. The magnitudes of the vertical forces observed in the 15 bursts appear consistent with slug masses of 104 to 106 kg.

Gum rosin-acetone system as an analogue to the degassing behaviour of hydrated magmas

Solutions of gum rosin and acetone reproduce the volatile- and temperature-dependent viscosity, together with the phase behaviour, of hydrated magmas. A range of experimental exsolution conditions was investigated, including the variation of supersaturation, rate of decompression, solution temperature and volatile content. Degassing processese were controlled by the formation of an exsolution interface above a supersaturated liquid. The end-products ranged from a mildly degassed liquid to a solid foam, which preserved strained vesicles. Solutions of gum rosin and acetone are proposed as a suitable analogue system with which to study magma degassing processes.

Electric potential gradient changes during explosive activity at Sakurajima volcano, Japan

We report electric potential gradient measurements carried out at Sakurajima volcano in Japan during: (1) explosions which generated ash plumes, (2) steam explosions which produced plumes of condensing gases, and (3) periods of ashfall and plume-induced acid rainfall. Sequential positive and negative deviations occurred during explosions which generated ash plumes. However, no deflections from background were found during steam explosions. During periods of ashfall negative electric potential gradients were observed, while positive potential gradients occurred during fallout of plume-induced acid rain from the same eruption. These results suggest that a dipole arrangement of charge develops within plumes such that positive charges dominate in the volcanic gas-rich top and negative charges in the following ash-rich part of the plume. The charge polarity may be reversed for other volcanoes (Hatakeyama and Uchikawa 1952). We suggest that charge is generated by fracto-emission (Donaldson et al. 1988) processes probably during magma fragmentation within the vent, rather than by frictional effects within the plume.

Volcanic plume electrification: experimental investigation of a fracture-charging mechanism.

Although ashfall from particulate volcanic plumes is known to be highly electrically charged, little is known about the charging mechanism. We describe experiments designed to investigate the particle charges generated from the fracture of pumice. Small silicate particles were produced in the laboratory during collisions between two samples cut from pumice clasts. The net charge magnitudes detected on these particles are similar to those previously measured on ashfall from volcanic plumes (∼10−5 to 10−6 C kg−1). This net charge is also shown to be the result of a small imbalance between the sums of individual particle charges of both polarities, which are up to several orders of magnitude larger than the net charge. The magnitude of both the net and single polarity specific charges were only weakly affected by changes of relative humidity, but single polarity charges increased steadily with increasing sample impact velocities. The dominant charging process during the experiments was that of material fracture. The charging mechanism is thus interpreted to be fractoemission (the release of nuclear particles from fresh crack surfaces) occurring during the production of the silicate particles. This implies that the electrification of volcanic plumes could be the result of brittle fragmentation of magma or pumice clasts within the upper regions of the conduit and in the jet region of the plume.

Growth and characterization of electrodeposited Cu/Cu-Ni-Co alloy superlattices

Abstract We have used a recently developed potentiostatic technique to electrodeposit Cu/Cu-Ni-Co alloy superlattices from a single electrolyte. Our films have been characterized using X-ray diffraction, electron backscatter diffraction patterns and electron probe microanalysis. Good epitaxy and repeat distances as short as 15 A have been achieved.

Magnetoresistance in electrodeposited Ni-Fe-Cu/Cu multilayers

Abstract Multilayers of NiFeCu/Cu have been electrodeposited from a single electrolyte onto polycrystalline (100) textured and (100) single crystal copper substrates. Bilayer thicknesses as low as 30 A have been achieved, as confirmed by X-ray diffraction. Room temperature magnetoresistance measurements show the presence of giant magnetoresistance (GMR) and an anisotropic magnetoresistance (AMR) component in the films.