Susan A. Kooi

Ozone and aerosol distributions and air mass characteristics over the South Pacific during the burning season

In situ and laser remote measurements of gases and aerosols were made with airborne instrumentation to establish a baseline chemical signature of the atmosphere above the South Pacific Ocean during the NASA Global Tropospheric Experiment (GTE)/Pacific Exploratory Mission-Tropics A (PEM-Tropics A) conducted in August-October 1996. This paper discusses general characteristics of the air masses encountered during this experiment using an airborne lidar system for measurements of the large-scale variations in ozone (O3) and aerosol distributions across the troposphere, calculated potential vorticity (PV) from the European Centre for Medium-Range Weather Forecasting (ECMWF), and in situ measurements for comprehensive air mass composition. Between 8°S and 52°S, biomass burning plumes containing elevated levels of O3, over 100 ppbv, were frequently encountered by the aircraft at altitudes ranging from 2 to 9 km. Air with elevated O3 was also observed remotely up to the tropopause, and these air masses were observed to have no enhanced aerosol loading. Frequently, these air masses had some enhanced PV associated with them, but not enough to explain the observed O3 levels. A relationship between PV and O3 was developed from cases of clearly defined O3 from stratospheric origin, and this relationship was used to estimate the stratospheric contribution to the air masses containing elevated O3 in the troposphere. The frequency of observation of the different air mass types and their average chemical composition is discussed in this paper.

Atmospheric CO 2 column measurements with an airborne intensity-modulated continuous wave 1.57 μm fiber laser lidar

The 2007 National Research Council (NRC) Decadal Survey on Earth Science and Applications from Space recommended Active Sensing of CO(2) Emissions over Nights, Days, and Seasons (ASCENDS) as a midterm, Tier II, NASA space mission. ITT Exelis, formerly ITT Corp., and NASA Langley Research Center have been working together since 2004 to develop and demonstrate a prototype laser absorption spectrometer for making high-precision, column CO(2) mixing ratio measurements needed for the ASCENDS mission. This instrument, called the multifunctional fiber laser lidar (MFLL), operates in an intensity-modulated, continuous wave mode in the 1.57 μm CO(2) absorption band. Flight experiments have been conducted with the MFLL on a Lear-25, UC-12, and DC-8 aircraft over a variety of different surfaces and under a wide range of atmospheric conditions. Very high-precision CO(2) column measurements resulting from high signal-to-noise ratio (>1300) column optical depth (OD) measurements for a 10 s (~1 km) averaging interval have been achieved. In situ measurements of atmospheric CO(2) profiles were used to derive the expected CO(2) column values, and when compared to the MFLL measurements over desert and vegetated surfaces, the MFLL measurements were found to agree with the in situ-derived CO(2) columns to within an average of 0.17% or ~0.65 ppmv with a standard deviation of 0.44% or ~1.7 ppmv. Initial results demonstrating ranging capability using a swept modulation technique are also presented.

LASE Validation Experiment

An extensive validation experiment was conducted in September 1995 from Wallops Island, Virginia, to evaluate the performance of the Lidar Atmospheric Sensing Experiment (LASE) system for the measurement of water vapor profiles under a wide range of atmospheric and solar background conditions. These measurements were compared with many different in situ and remote measurements in the most extensive water vapor intercomparison ever conducted. The LASE water vapor measurements were found to have an accuracy of better than 6% or 0.01 g/kg, whichever is greater, across the entire troposphere.

Characterization of Upper-Troposphere Water Vapor Measurements during AFWEX Using LASE

Water vapor profiles from NASAs Lidar Atmospheric Sensing Experiment (LASE) system acquired during the ARM/FIRE Water Vapor Experiment (AFWEX) are used to characterize upper troposphere (UT) water vapor measured by ground-based Raman lidars, radiosondes, and in situ aircraft sensors. Initial comparisons showed the average Vaisala radiosonde measurements to be 5-15% drier than the average LASE, Raman lidar, and DC-8 in situ diode laser hygrometer measurements. They show that corrections to the Raman lidar and Vaisala measurements significantly reduce these differences. Precipitable water vapor (PWV) derived from the LASE water vapor profiles agrees within 3% on average with PWV derived from the ARM ground-based microwave radiometer (MWR). The agreement among the LASE, Raman lidar, and MWR measurements demonstrates how the LASE measurements can be used to characterize both profile and column water vapor measurements and that ARM Raman lidar, when calibrated using the MWR PWV, can provide accurate UT water vapor measurements.

Comparison of Aerosol Optical Properties and Water Vapor Among Ground and Airborne Lidars and Sun Photometers During TARFOX

We compare aerosol optical thickness (AOT) and precipitable water vapor (PWV) measurements derived from ground and airborne lidars and Sun photometers during the Tropo- spheric Aerosol Radiative Forcing Observational Experiment. Such comparisons are important to verify the consistency between various remote sensing measurements before employing them in any assessment of the impact of aerosols on the global radiation balance. Total scattering ratio and extinction profiles measured by the ground-based NASA Goddard Space Flight Center scan- ning Raman lidar system, which operated from Wallops Island, Virginia (37.86oN, 75.51 oW), are compared with those measured by the Lidar Atmospheric Sensing Experiment (LASE) airborne lidar system aboard the NASA ER-2 aircraft. Bias and root-mean-square differences indicate that these measurements generally agreed within about 10%. Aerosol extinction profiles and esti- mates of AOT are derived from both lidar measurements using a value for the aerosol extinction/ backscattering ratio Sa = 60 sr for the aerosol extinction/backscattering ratio, which was deter- mined from the Raman lidar measurements. The lidar measurements of AOT are found to be gen- erally within 25% of the AOT measured by the NASA Ames Airborne Tracking Sun Photometer (AATS-6). However, during certain periods the lidar and Sun photometer measurements of AOT differed significantly, possibly because of variations in the aerosol physical characteristics (e.g., size, composition) which affect Sa. Estimates of PWV, derived from water vapor mixing ratio profiles measured by LASE, are within 5-10% of PWV derived from the airborne Sun photometer. Aerosol extinction profiles measured by both lidars show that aerosols were generally concen- trated in the lowest 2-3 km.

Large‐scale variability of ozone and aerosols in the summertime Arctic and sub‐Arctic troposphere

Measurements of ozone (03) and aerosol distributions were made with an airborne lidar system in the Arctic and sub-Arctic during July-August 1988 as part of the NASA Global Tropospheric Experiment/Arctic Boundary Layer Expedition (ABLE 3A). Aerosol and 0 3 profiles were measured simultaneously above and below the Electra aircraft from near the surface to above the tropopause. In situ measurements of 03 mixing ratios and aerosol size distributions and number densities were also made on the aircraft. Many different atmospheric conditions were investigated on long-range survey flights in the Arctic and on intensive flights over the tundra, ice, and marine regions near Barrow and Bethel, Alaska. The tropospheric composition at high latitudes was found to be strongly influenced by stratospheric intrusions. Regions of low-aerosol scattering and enhanced 03 mixing ratios were correlated with descending air from the lower stratosphere. Over 37% of the troposphere along our flight track at latitudes >57oN had significantly enhanced 03 levels due to stratospheric intrusions, and in the 4- to 6-km altitude range the tropospheric extent of the enhanced 03 exceeded 56%. Ozone mixing ratios of 80 ppbv at 6 km were common, with vertical 03 gradients of over 11 ppbv km -1 observed across the base of strong intrusions. In the mixed layer over the tundra, 03 was in the 25-35 ppbv range with a gradient of 5.5 ppbv km -1, while in continental polar air masses, the average gradient in the lower troposphere was 7.4 ppbv km -1, indicating more downward transport of 03 at higher latitudes. Due to the many forest fires that year, plumes from biomass burning sources were observed on several flights over Alaska. Plumes influenced about 10% of the air below 4 km, and in some photochemically active plumes, 03 was enhanced by 10-20 ppbv over ambient levels. Pollution plumes from industrial sources were infrequently observed; however, a few large plumes were found over the North Pacific with greatly enhanced aerosol scattering and with 03 levels exceeding 75 ppbv.

Large-scale air mass characteristics observed over the remote tropical Pacific Ocean during March-April 1999: Results from PEM-Tropics B field experiment

Eighteen long-range flights over the Pacific Ocean between 38oS to 20oN and 166oE to 90oW were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (03), water vapor (H20), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in 03, carbon monoxide, hydrocarbons, and aerosols and an increase in H20. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced 0 3 and aerosols and an associated decrease in H20. Average latitudinal and longitudinal distributions of 0 3 and H20 were constructed from the remote and in situ 03 and H20 data, and these distributions are compared with results from PEM-Tropics A conducted in August- October 1996. During PEM-Tropics B, low 03 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced 03 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their 03, aerosols, clouds, and potential vorticity characteristics. The data from each flight were binned by altitude according to air mass type, and these results showed the relative observational frequency of the different air masses as a function of altitude in seven regions over the Pacific. The average chemical composition of the major air mass types was determined from in situ measurements in the NH and SH, and these results provided insight into the origin, lifetime, and chemistry of the air in these regions.

Intercomparison of Water Vapor Data Measured with Lidar during IHOP_2002. Part I: Airborne to Ground-Based Lidar Systems and Comparisons with Chilled-Mirror Hygrometer Radiosondes

Abstract The water vapor data measured with airborne and ground-based lidar systems during the International H2O Project (IHOP_2002), which took place in the Southern Great Plains during 13 May–25 June 2002 were investigated. So far, the data collected during IHOP_2002 provide the largest set of state-of-the-art water vapor lidar data measured in a field campaign. In this first of two companion papers, intercomparisons between the scanning Raman lidar (SRL) of the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC) and two airborne systems are discussed. There are 9 intercomparisons possible between SRL and the differential absorption lidar (DIAL) of Deutsches Zentrum fur Luft- und Raumfahrt (DLR), while there are 10 intercomparisons between SRL and the Lidar Atmospheric Sensing Experiment (LASE) of the NASA Langley Research Center. Mean biases of (−0.30 ± 0.25) g kg−1 or −4.3% ± 3.2% for SRL compared to DLR DIAL (DLR DIAL drier) and (0.16 ± 0.31) g kg−1 or 5.3% ± 5.1% ...

Comparisons of LASE, aircraft, and satellite measurements of aerosol optical properties and water vapor during TARFOX

We examine aerosol extinction and optical thickness from the Lidar Atmospheric Sensing Experiment (LASE), the in situ nephelometer and absorption photometer on the University of Washington C-131A aircraft, and the NASA Ames Airborne Tracking Sun Photometer (AATS-6) on the C-131A measured during the Tropospheric Aerosol Radiative Forcing Observational Experiment (TARFOX) over the east coast of the United States in July 1996. On July 17 and 24 the LASE profiles of aerosol extinction and aerosol optical thickness (AOT) had a bias difference of 0.0055 km-1 (10%) and a root-mean-square difference of 0.026 km-1 (42%) when compared to corresponding profiles derived from the airborne in situ data when the nephelometer measurements are adjusted to ambient relative humidities. Larger differences for two other days were associated with much smaller aerosol optical thicknesses (July 20) and differences in the locations sampled by the two aircraft (July 26). LASE profiles of AOT are about 10% higher than those derived from the airborne Sun photometer, which in turn are about 10-15% higher than those derived from the airborne in situ measurements. These differences are generally within the error estimates of the various measurements. The LASE measurements of AOT generally agree with AOT derived from both the Along-Track and Scanning Radiometer 2 (ATSR 2) sensor flown on the European Remote Sensing Satellite 2 (ERS-2) and from the Moderate-Resolution Imaging Spectroradiometer (MODIS) airborne simulator (MAS) which flew with LASE on the NASA ER-2 aircraft. Effective particle sizes derived from the MAS data indicate that the LASE retrievals of AOT are valid for effective particle radii less than 0.4 μm. Variations in the relative humidity derived from the LASE water vapor measurements on July 26 are found to be highly correlated with variations in the effective particle size derived from the MAS. Copyright 2000 by the American Geophysical Union.

Intercomparison of Water Vapor Data Measured with Lidar during IHOP_2002. Part II: Airborne-to-Airborne Systems

Abstract The dataset of the International H2O Project (IHOP_2002) gives the first opportunity for direct intercomparisons of airborne water vapor lidar systems and allows very important conclusions to be drawn for future field campaigns. Three airborne differential absorption lidar (DIAL) systems were operated simultaneously during some IHOP_2002 missions: the DIAL of Deutsches Zentrum fur Luft- und Raumfahrt (DLR), the Lidar Atmospheric Sensing Experiment (LASE) of the National Aeronautics and Space Administration (NASA) Langley Research Center, and the Lidar Embarque pour l’etude des Aerosols et des Nuages de l’interaction Dynamique Rayonnement et du cycle de l’Eau (LEANDRE II) of the Centre National de la Recherche Scientifique (CNRS). Data of one formation flight with DLR DIAL and LEANDRE II were investigated, which consists of 54 independent profiles of the two instruments measured with 10-s temporal average. For the height range of 1.14–1.64 km above sea level, a bias of (−0.41 ± 0.16) g kg−1 or −7....