Marta A. Fenn

Ozone and aerosol distributions and air mass characteristics over the South Pacific during the burning season

In situ and laser remote measurements of gases and aerosols were made with airborne instrumentation to establish a baseline chemical signature of the atmosphere above the South Pacific Ocean during the NASA Global Tropospheric Experiment (GTE)/Pacific Exploratory Mission-Tropics A (PEM-Tropics A) conducted in August-October 1996. This paper discusses general characteristics of the air masses encountered during this experiment using an airborne lidar system for measurements of the large-scale variations in ozone (O3) and aerosol distributions across the troposphere, calculated potential vorticity (PV) from the European Centre for Medium-Range Weather Forecasting (ECMWF), and in situ measurements for comprehensive air mass composition. Between 8°S and 52°S, biomass burning plumes containing elevated levels of O3, over 100 ppbv, were frequently encountered by the aircraft at altitudes ranging from 2 to 9 km. Air with elevated O3 was also observed remotely up to the tropopause, and these air masses were observed to have no enhanced aerosol loading. Frequently, these air masses had some enhanced PV associated with them, but not enough to explain the observed O3 levels. A relationship between PV and O3 was developed from cases of clearly defined O3 from stratospheric origin, and this relationship was used to estimate the stratospheric contribution to the air masses containing elevated O3 in the troposphere. The frequency of observation of the different air mass types and their average chemical composition is discussed in this paper.

Comparison of free tropospheric western Pacific air mass classification schemes for the PEM‐West A experiment

During September/October 1991, NASAs Global Tropospheric Experiment (GTE) conducted an airborne field measurement program (PEM-West A) in the troposphere over the western Pacific Ocean. In this paper we describe and use the relative abundance of the combustion products C2H2 and CO to classify air masses encountered during PEM-West A based on the degree that these tracers were processed by the combined effects of photochemical reactions and dynamical mixing (termed the degree of atmospheric processing). A large number of trace compounds (e.g., C2H6, C3H8, C6H6, NOy, and O3) are found to be well correlated with the degree of atmospheric processing that is reflected by changes in the ratio of C2H2/CO over the range of values from ∼0.3 to 2.0 (parts per trillion volume) C2H2/(parts per billion volume) CO. This C2H2/CO-based classification scheme is compared to model simulations and to two independent classification schemes based on air mass back-trajectory analyses and lidar profiles of O3 and aerosols. In general, these schemes agree well, and in combination they suggest that the functional dependence that other observed species exhibit with respect to the C2H2/CO atmospheric processing scale can be used to study the origin, sources, and sinks of trace species and to derive several important findings. First, the degree of atmospheric processing is found to be dominated by dilution associated with atmospheric mixing, which is found to primarily occur through the vertical mixing of relatively recent emissions of surface layer trace species. Photochemical reactions play their major role by influencing the background concentrations of trace species that are entrained during the mixing (i.e., dilution) process. Second, a significant noncontinental source(s) of NO (and NOx) in the free troposphere is evident. In particular, the enhanced NO mixing ratios that were observed in convected air masses are attributed to either emissions from lightning or the rapid recycling of NOy compounds. Third, nonsoluble trace species emitted in the continental boundary layer, such as CO and hydrocarbons, are vertically transported to the upper troposphere as efficiently as they are to the midtroposphere. In addition, the mixing ratios of CO and hydrocarbons in the upper troposphere over the western Pacific may reflect a significant contribution from northern hemisphere land areas other than Asia. Finally, we believe that these results can be valuable for the quantitative evaluation of the vertical transport processes that are usually parameterized in models.

Ozone and aerosol changes during the 1991-1992 airborne arctic stratospheric expedition.

Stratospheric ozone and aerosol distributions were measured across the wintertime Arctic vortex from January to March 1992 with an airborne lidar system as part of the 1992 Airborne Arctic Stratospheric Expedition (AASE II). Aerosols from the Mount Pinatubo eruption were found outside and inside the vortex with distinctly different distributions that clearly identified the dynamics of the vortex. Changes in aerosols inside the vortex indicated advection of air from outside to inside the vortex below 16 kilometers. No polar stratospheric clouds were observed and no evidence was found for frozen volcanic aerosols inside the vortex. Between January and March, ozone depletion was observed inside the vortex from 14 to 20 kilometers with a maximum average loss of about 23 percent near 18 kilometers.

Large-scale air mass characteristics observed over the remote tropical Pacific Ocean during March-April 1999: Results from PEM-Tropics B field experiment

Eighteen long-range flights over the Pacific Ocean between 38oS to 20oN and 166oE to 90oW were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (03), water vapor (H20), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in 03, carbon monoxide, hydrocarbons, and aerosols and an increase in H20. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced 0 3 and aerosols and an associated decrease in H20. Average latitudinal and longitudinal distributions of 0 3 and H20 were constructed from the remote and in situ 03 and H20 data, and these distributions are compared with results from PEM-Tropics A conducted in August- October 1996. During PEM-Tropics B, low 03 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced 03 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their 03, aerosols, clouds, and potential vorticity characteristics. The data from each flight were binned by altitude according to air mass type, and these results showed the relative observational frequency of the different air masses as a function of altitude in seven regions over the Pacific. The average chemical composition of the major air mass types was determined from in situ measurements in the NH and SH, and these results provided insight into the origin, lifetime, and chemistry of the air in these regions.

The 2013 Rim Fire: Implications for Predicting Extreme Fire Spread, Pyroconvection, and Smoke Emissions

AbstractThe 2013 Rim Fire, which burned over 104,000 ha, was one of the most severe fire events in California’s history, in terms of its rapid growth, intensity, overall size, and persistent smoke plume. At least two large pyrocumulonimbus (pyroCb) events were observed, allowing smoke particles to extend through the upper troposphere over a large portion of the Pacific Northwest. However, the most extreme fire spread was observed on days without pyroCb activity or significant regional convection. A diverse archive of ground, airborne, and satellite data collected during the Rim Fire provides a unique opportunity to examine the conditions required for both extreme spread events and pyroCb development. Results highlight the importance of upper-level and nocturnal meteorology, as well as the limitations of traditional fire weather indices. The Rim Fire dataset also allows for a detailed examination of conflicting hypotheses surrounding the primary source of moisture during pyroCb development. All pyroCbs wer...

Thunderstorms enhance tropospheric ozone by wrapping and shedding stratospheric air

A significant source of ozone in the troposphere is transport from the stratosphere. The stratospheric contribution has been estimated mainly using global models that attribute the transport process largely to the global scale Brewer-Dobson circulation and synoptic scale dynamics associated with upper tropospheric jet streams. We report observations from research aircraft that reveal additional transport of ozone-rich stratospheric air downward into the upper troposphere by a leading-line-trailing-stratiform (LLTS) mesoscale convective system (MCS) with convection overshooting the tropopause altitude. The fine-scale transport demonstrated by these observations poses a significant challenge to global models that currently do not resolve storm scale dynamics. Thus the upper tropospheric ozone budget simulated by global chemistry-climate models where large-scale dynamics and photochemical production from lightning-produced NO are the controlling factors may require modification.

A case study of transport of tropical marine boundary layer and lower tropospheric air masses to the northern midlatitude upper troposphere

Low-ozone (<20 ppbv) air masses were observed in the upper troposphere in northern midlatitudes over the eastern United States and the North Atlantic Ocean on several occasions in October 1997 during the NASA Subsonic Assessment, Ozone and Nitrogen Oxide Experiment (SONEX) mission. Three cases of low-ozone air masses were shown to have originated in the tropical Pacific marine boundary layer or lower troposphere and advected poleward along a warm conveyor belt during a synoptic-scale disturbance. The tropopause was elevated in the region with the low-ozone air mass. Stratospheric intrusions accompanied the disturbances. On the basis of storm track and stratospheric intrusion climatologies, such events appear to be more frequent from September through March than the rest of the year.

Observations of convective and dynamical instabilities in tropopause folds and their contribution to stratosphere-troposphere exchange

With aircraft-mounted in situ and remote sensing instruments for dynamical, thermal, and chemical measurements we studied two cases of tropopause folding. In both folds we found Kelvin-Helmholtz billows with horizontal wavelength of ∼900 m and thickness of ∼120 m. In one case the instability was effectively mixing the bottomside of the fold, leading to the transfer of stratospheric air into the troposphere. Also, we discovered in both cases small-scale secondary ozone maxima shortly after the aircraft ascended past the topside of the fold that corresponded to regions of convective instability. We interpreted this phenomenon as convectively breaking gravity waves. Therefore we posit that convectively breaking gravity waves acting on tropopause folds must be added to the list of important irreversible mixing mechanisms leading to stratosphere-troposphere exchange.

Revealing important nocturnal and day-to-day variations in fire smoke emissions through a multiplatform inversion

We couple airborne, ground-based, and satellite observations; conduct regional simulations; and develop and apply an inversion technique to constrain hourly smoke emissions from the Rim Fire, the third largest observed in California, USA. Emissions constrained with multiplatform data show notable nocturnal enhancements (sometimes over a factor of 20), correlate better with daily burned area data, and are a factor of 2–4 higher than a priori estimates, highlighting the need for improved characterization of diurnal profiles and day-to-day variability when modeling extreme fires. Constraining only with satellite data results in smaller enhancements mainly due to missing retrievals near the emissions source, suggesting that top-down emission estimates for these events could be underestimated and a multiplatform approach is required to resolve them. Predictions driven by emissions constrained with multiplatform data present significant variations in downwind air quality and in aerosol feedback on meteorology, emphasizing the need for improved emissions estimates during exceptional events.

LASE Measurements of Water Vapor, Aerosol, and Cloud Distributions in Saharan Air Layers and Tropical Disturbances

Abstract The Lidar Atmospheric Sensing Experiment (LASE) on board the NASA DC-8 measured high-resolution profiles of water vapor and aerosols, and cloud distributions in 14 flights over the eastern North Atlantic during the NASA African Monsoon Multidisciplinary Analyses (NAMMA) field experiment. These measurements were used to study African easterly waves (AEWs), tropical cyclones (TCs), and the Saharan air layer (SAL). These LASE measurements represent the first simultaneous water vapor and aerosol lidar measurements to study the SAL and its interactions with AEWs and TCs. Three case studies were selected for detailed analysis: (i) a stratified SAL, with fine structure and layering (unlike a well-mixed SAL), (ii) a SAL with high relative humidity (RH), and (iii) an AEW surrounded by SAL dry air intrusions. Profile measurements of aerosol scattering ratios, aerosol extinction coefficients, aerosol optical thickness, water vapor mixing ratios, RH, and temperature are presented to illustrate their characte...