Svetlana Pukhovskaya

Novel aqueous soluble cobalt(II) phthalocyanines of tetracarboxyl-substituted: Synthesis and catalytic activity on oxidation of sodium diethyldithiocarbamate

Enhancement of the catalytic activity of phthalocyanine catalysts by immobilizing them on polymer matrix has been studied. It has been found that the immobilization of cobalt(II) phthalocyanines on polymers enhances their catalytic activity in the oxidation of sodium diethyldithiocarbamate by air oxygen under mild conditions.

Coordination and acid-base properties of meso-nitro derivatives of β-octaethylporphyrin

Spectrophotometric method is used to study the acid-base and coordination properties of a series of porphyrins with a continuously increasing degree of macrocycle deformation resulting from the introduction of strong electron — withdrawing substituents: 2,3,7,8,12,13,17,18-octaethylporphyrin (1), 5-nitro-2,3,7,8,12,13,17,18-octaethylporphyrin (2), 5,15-dinitro-2,3,7,8,12,13,17,18-octaethylporphyrin (3), 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin (4), and 5,10,15,20-tetranitro-2,3,7,8,12,13,17,18-octaethylporphyrin (5). It is found that the values of total basicity constants obtained for the investigated compounds consistently diminish with an increase in the number of meso-substituents: 11.85 (1) < 10.45 (2) < 10.31 (3) < 10.23 (4) < 9.56 (5). The values of the combined acidity constants of porphyrins (4–5) obtained in acetonitrile-DBU system at 298 K are pKa = 10.90 and 10.40 respectively. The reaction of complex formation between the porphyrins and their dianionic forms with zinc acetate was studied. It is shown that two opposing factors, the steric and electronic effects of the substituents, change the acid-base and coordination properties of the above series of compounds.

Sulfonated Co(II) phthalocyanines covalently anchored at organic polymers as catalyst for mild oxidation of mercaptans

Current work is devoted to covalent immobilization of sulfonated derivatives of cobalt phthalocyanines “Merox catalysts” on the surfaces of polypropylene and polyethylene terephthalate. Their catalytic activity in reaction of mild oxidation of sulfur compounds to disulfides with oxygen of the air was studied. Anchoring of the catalyst on this polymer prevents its leaching and promotes its efficient recovering and recycling without significant loss of catalytic activity.