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T. D. P. Stack

Stanford University

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Featured researches published by T. D. P. Stack.

Science | 1996

A Trinuclear Intermediate in the Copper-Mediated Reduction of O2: Four Electrons from Three Coppers

Adam P. Cole; David E. Root; Pulakesh Mukherjee; Edward I. Solomon; T. D. P. Stack

The reaction of metal complexes with dioxygen (O2) generally proceeds in 1:1, 2:1, or 4:1 (metal:O2) stoichiometry. A discrete, structurally characterized 3:1 product is presented. This mixed-valence trinuclear copper cluster, which contains copper in the highly oxidized trivalent oxidation state, exhibits O2 bond scission and intriguing structural, spectroscopic, and redox properties. The relevance of this synthetic complex to the reduction of O2 at the trinuclear active sites of multicopper oxidases is discussed.

Science | 1998

Catalytic Galactose Oxidase Models: Biomimetic Cu(II)-Phenoxyl-Radical Reactivity

Yadong Wang; Jennifer L. DuBois; Britt Hedman; Keith O. Hodgson; T. D. P. Stack

Journal of the American Chemical Society | 2003

Efficient Epoxidation of Electron-Deficient Olefins with a Cationic Manganese Complex

Andrew Murphy; Geraud Dubois; T. D. P. Stack

Journal of the American Chemical Society | 1997

Irreversible Reduction of Dioxygen by Simple Peralkylated Diamine−Copper(I) Complexes: Characterization and Thermal Stability of a [Cu2(μ-O)2]2+ Core

Viswanath Mahadevan; Zhiguo Hou; Adam P. Cole; David E. Root; Tapan K. Lal; Edward I. Solomon; T. D. P. Stack

Journal of the American Chemical Society | 2000

A Systematic K-edge X-ray Absorption Spectroscopic Study of Cu(III) Sites

Jennifer L. DuBois; Pulakesh Mukherjee; T. D. P. Stack; Britt Hedman; Edward I. Solomon, ,† and; Keith O. Hodgson

Journal of the American Chemical Society | 1999

SPECTROSCOPIC AND ELECTRONIC STRUCTURAL STUDIES OF THE CU(III)2 BIS-MU -OXO CORE AND ITS RELATION TO THE SIDE-ON PEROXO-BRIDGED DIMER

Mark J. Henson; Pulakesh Mukherjee; David E. Root; T. D. P. Stack; Edward I. Solomon

Journal of the American Chemical Society | 2000

Differential Reactivity between Interconvertible Side-On Peroxo and Bis-μ-oxodicopper Isomers Using Peralkylated Diamine Ligands

Viswanath Mahadevan; Mark J. Henson; Edward I. Solomon; T. D. P. Stack

Journal of the American Chemical Society | 1999

Exogenous substrate reactivity with a [Cu(III){sub 2}O{sub 2}]{sup 2+} core: Structural implications

Viswanath Mahadevan; Jennifer L. DuBois; Britt Hedman; Keith O. Hodgson; T. D. P. Stack

Journal of the American Chemical Society | 1997

Cu K-Edge XAS Study of the [Cu2(μ-O)2] Core: Direct Experimental Evidence for the Presence of Cu(III)

Jennifer L. DuBois; Pulakesh Mukherjee; Andrea M. Collier; James M. Mayer; Edward I. Solomon; Britt Hedman; T. D. P. Stack; Keith O. Hodgson

Journal of the American Chemical Society | 2002

A Stabilized μ-η2:η2 Peroxodicopper(II) Complex with a Secondary Diamine Ligand and Its Tyrosinase-like Reactivity

Liviu M. Mirica; Michael A. Vance; Deanne Jackson Rudd; Britt Hedman; Keith O. Hodgson; Edward I. Solomon; T. D. P. Stack

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Edward I. Solomon

Stanford University

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Britt Hedman

SLAC National Accelerator Laboratory

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Keith O. Hodgson

Stanford University

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Pulakesh Mukherjee

Stanford University

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David E. Root

Stanford University

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Jennifer L. DuBois

Montana State University

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Mark J. Henson

Stanford University

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Viswanath Mahadevan

Stanford University

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Adam P. Cole

Stanford University

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Andrea M. Collier

University of Washington

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