T. G. Graff

Mineralogy at Meridiani Planum from the Mini-TES experiment on the opportunity rover

The Miniature Thermal Emission Spectrometer (Mini-TES) on Opportunity investigated the mineral abundances and compositions of outcrops, rocks, and soils at Meridiani Planum. Coarse crystalline hematite and olivine-rich basaltic sands were observed as predicted from orbital TES spectroscopy. Outcrops of aqueous origin are composed of 15 to 35% by volume magnesium and calcium sulfates [a high-silica component modeled as a combination of glass, feldspar, and sheet silicates (∼20 to 30%)], and hematite; only minor jarosite is identified in Mini-TES spectra. Mini-TES spectra show only a hematite signature in the millimeter-sized spherules. Basaltic materials have more plagioclase than pyroxene, contain olivine, and are similar in inferred mineral composition to basalt mapped from orbit. Bounce rock is dominated by clinopyroxene and is close in inferred mineral composition to the basaltic martian meteorites. Bright wind streak material matches global dust. Waterlain rocks covered by unaltered basaltic sands suggest a change from an aqueous environment to one dominated by physical weathering.

Phyllosilicate-poor palagonitic dust from Mauna Kea Volcano (Hawaii): A mineralogical analogue for magnetic Martian dust?

The mineralogical and elemental composition of dust size fractions (<2 and <5 μm) of eight samples of phyllosilicate-poor palagonitic tephra from the upper slopes of Mauna Kea Volcano (Hawaii) were studied by X-ray diffraction (XRD), X-ray fluorescence (XRF), visible and near-IR reflectance spectroscopy, Mossbauer spectroscopy, magnetic properties methods, and transmission electron microscopy (TEM). The palagonitic dust samples are spectral analogues of Martian bright regions at visible and near-IR wavelengths. The crystalline phases in the palagonitic dust are, in variable proportions, plagioclase feldspar, Ti-containing magnetite, minor pyroxene, and trace hematite. No basal reflections resulting from crystalline phyllosilicates were detected in XRD data. Weak, broad XRD peaks corresponding to X-ray amorphous phases (allophane, nanophase ferric oxide (possibly ferrihydrite), and, for two samples, hisingerite) were detected as oxidative alteration products of the glass; residual unaltered glass was also present. Mossbauer spectroscopy showed that the iron-bearing phases are nanophase ferric oxide, magnetite/titanomagnetite, hematite, and minor glass and ferrous silicates. Direct observation by TEM showed that the crystalline and X-ray amorphous phases observed by XRD and Mossbauer are normally present together in composite particles and not normally present as discrete single-phase particles. Ti-bearing magnetite occurs predominantly as 5–150 nm particles embedded in noncrystalline matrix material and most likely formed by crystallization from silicate liquids under conditions of rapid cooling during eruption and deposition of glassy tephra and prior to palagonitization of glass. Rare spheroidal halloysite was observed in the two samples that also had XRD evidence for hisingerite. The saturation magnetization Js and low-field magnetic susceptibility for bulk dust range from 0.19 to 0.68 Am2/kg and 3.4×10−6 to 15.5×10−6 m3/kg at 293 K, respectively. Simulation of the Mars Pathfinder Magnet Array (MA) experiment was performed on Mauna Kea Volcano in areas with phyllosilicate-poor palagonitic dust and with copies of the Pathfinder MA. On the basis of the magnetic properties of dust collected by all five MA magnets and the observation that the Pathfinder MAs collected dust on the four strongest magnets, the value for the saturation magnetization of Martian dust collected in the MA experiments is revised downward from 4±2 Am2/kg to 2.5±1.5 Am2/kg. The revised value corresponds to 2.7±1.6 wt % magnetite if the magnetic mineral is magnetite (using Js = 92 Am2/kg for pure magnetite, Fe3O4) or to 5.0±3.0 to 3.4±2.0 wt % maghemite if the magnetic mineral is pure maghemite (using Js = 50 to 74 Am2/kg for pure maghemite, γ-Fe2O3). Comparison of the magnetic properties of bulk Mauna Kea palagonitic dust to those for dust collected by MA magnets shows that the MA magnets extracted (culled) a subset (25–34 wt %) of composite magnetic particles from bulk dust. The extent of culling of Martian dust is not well constrained. Because the Mauna Kea palagonitic dust satisfies the essential constraints of the Pathfinder magnetic properties experiment (composite and magnetic particles capable of being collected by five MA magnets), a working hypothesis for the strongly magnetic mineral present in Martian dust and soil is magnetite (possibly Ti-bearing) formed by rapid crystallization from silicate liquids having volcanic and/or impact origins. Subsequent palagonitization of the glass produces the nanophase ferric oxide phases that dominate the spectral properties of Martian bright regions at visible and near-IR wavelengths. Magnetic and phyllosilicate-poor palagonitic dust from Mauna Kea Volcano is thus a spectral and magnetic analogue for magnetic Martian dust.

Silicic volcanism on Mars evidenced by tridymite in high-SiO2 sedimentary rock at Gale crater

Significance Tridymite, a SiO2 mineral that crystallizes at low pressures and high temperatures (>870 °C) from high-SiO2 materials, was detected at high concentrations in a sedimentary mudstone in Gale crater, Mars. Mineralogy and abundance were determined by X-ray diffraction using the Chemistry and Mineralogy instrument on the Mars Science Laboratory rover Curiosity. Terrestrial tridymite is commonly associated with silicic volcanism where high temperatures and high-silica magmas prevail, so this occurrence is the first in situ mineralogical evidence for martian silicic volcanism. Multistep processes, including high-temperature alteration of silica-rich residues of acid sulfate leaching, are alternate formation pathways for martian tridymite but are less likely. The unexpected discovery of tridymite is further evidence of the complexity of igneous petrogenesis on Mars, with igneous evolution to high-SiO2 compositions. Tridymite, a low-pressure, high-temperature (>870 °C) SiO2 polymorph, was detected in a drill sample of laminated mudstone (Buckskin) at Marias Pass in Gale crater, Mars, by the Chemistry and Mineralogy X-ray diffraction instrument onboard the Mars Science Laboratory rover Curiosity. The tridymitic mudstone has ∼40 wt.% crystalline and ∼60 wt.% X-ray amorphous material and a bulk composition with ∼74 wt.% SiO2 (Alpha Particle X-Ray Spectrometer analysis). Plagioclase (∼17 wt.% of bulk sample), tridymite (∼14 wt.%), sanidine (∼3 wt.%), cation-deficient magnetite (∼3 wt.%), cristobalite (∼2 wt.%), and anhydrite (∼1 wt.%) are the mudstone crystalline minerals. Amorphous material is silica-rich (∼39 wt.% opal-A and/or high-SiO2 glass and opal-CT), volatile-bearing (16 wt.% mixed cation sulfates, phosphates, and chlorides−perchlorates−chlorates), and has minor TiO2 and Fe2O3T oxides (∼5 wt.%). Rietveld refinement yielded a monoclinic structural model for a well-crystalline tridymite, consistent with high formation temperatures. Terrestrial tridymite is commonly associated with silicic volcanism, and detritus from such volcanism in a “Lake Gale” catchment environment can account for Buckskin’s tridymite, cristobalite, feldspar, and any residual high-SiO2 glass. These cogenetic detrital phases are possibly sourced from the Gale crater wall/rim/central peak. Opaline silica could form during diagenesis from high-SiO2 glass, as amorphous precipitated silica, or as a residue of acidic leaching in the sediment source region or at Marias Pass. The amorphous mixed-cation salts and oxides and possibly the crystalline magnetite (otherwise detrital) are primary precipitates and/or their diagenesis products derived from multiple infiltrations of aqueous solutions having variable compositions, temperatures, and acidities. Anhydrite is post lithification fracture/vein fill.

Hydrothermal synthesis of hematite spherules and jarosite: Implications for diagenesis and hematite spherule formation in sulfate outcrops at Meridiani Planum, Mars

Abstract We synthesized hematite spherules whose mineralogic, chemical, and crystallographic properties are strikingly similar to those for the hematite-rich spherules in lag deposits on the surface and embedded in outcrops at Meridiani Planum, Mars. The spherules were synthesized in the laboratory along with hydronium jarosite and minor hydronium alunite from Fe-Al-Mg-S-Cl acid-sulfate solutions under hydrothermal conditions. The reaction sequence was (1) precipitation of hydronium jarosite; (2) jarosite dissolution and precipitation of hematite spherules; and (3) precipitation of hydronium alunite upon depletion of hydronium jarosite. The spherules exhibit a radial growth texture with the crystallographic c axis aligned along the radial direction, so that thermal emission spectra have no hematite emissivity minimum at ~390 cm-1. Our experiments show that hydrothermal, acid-sulfate solutions are a pathway for formation of jarosite and the hematite spherules at Meridiani Planum, Mars.

Ferrian saponite from the Santa Monica Mountains (California, U.S.A., Earth): Characterization as an analog for clay minerals on Mars with application to Yellowknife Bay in Gale Crater

Abstract Ferrian saponite from the eastern Santa Monica Mountain, near Griffith Park (Los Angeles, California), was investigated as a mineralogical analog to smectites discovered on Mars by the CheMin X-ray diffraction instrument onboard the Mars Science Laboratory (MSL) rover. The martian clay minerals occur in sediment of basaltic composition and have 02l diffraction bands peaking at 4.59 Å, consistent with tri-octahedral smectites. The Griffith saponite occurs in basalts as pseudomorphs after olivine and mesostasis glass and as fillings of vesicles and cracks and has 02l diffraction bands at that same position. We obtained chemical compositions (by electron microprobe), X-ray diffraction patterns with a lab version of the CheMin instrument, Mössbauer spectra, and visible and near-IR reflectance (VNIR) spectra on several samples from that locality. The Griffith saponite is magnesian, Mg/(Mg+SFe) = 65-70%, lacks tetrahedral Fe3+ and octahedral Al3+, and has Fe3+/SFe from 64 to 93%. Its chemical composition is consistent with a fully tri-octahedral smectite, but the abundance of Fe3+ gives a nominal excess charge of +1 to +2 per formula unit. The excess charge is likely compensated by substitution of O2- for OH-, causing distortion of octahedral sites as inferred from Mössbauer spectra. We hypothesize that the Griffith saponite was initially deposited with all its iron as Fe2+ and was oxidized later. X‑ray diffraction shows a sharp 001 peak at 15 Å, 00l peaks, and a 02l diffraction band at the same position (4.59 Å) and shape as those of the martian samples, indicating that the martian saponite is not fully oxidized. VNIR spectra of the Griffith saponite show distinct absorptions at 1.40, 1.90, 2.30-2.32, and 2.40 mm, arising from H2O and hydroxyl groups in various settings. The position of the ~2.31 mm spectral feature varies systematically with the redox state of the octahedrally coordinated Fe. This correlation may permit surface oxidation state to be inferred (in some cases) from VNIR spectra of Mars obtained from orbit, and, in any case, ferrian saponite is a viable assignment for spectral detections in the range 2.30-2.32 mm.

Redox systematics of martian magmas with implications for magnetite stability

Abstract Magnetite is commonly found at sites on Mars explored by robotic spacecraft, yet is rare in martian meteorites and in experimental studies of martian magma compositions. Iron redox systematics of the high-FeO shergottitic liquids are poorly known, yet have a fundamental control on stability of phases such as magnetite, ilmenite, and pyroxenes. We undertook experiments to constrain the Fe3+/ ΣFe in high-FeO (15-22 wt%) glasses as a function of fO2, melt P2O5, temperature and pressure. We also performed a series of sub-liquidus experiments between 1100 and 1000 °C and FMQ+0.5 to FMQ-1 to define magnetite stability. Run products were analyzed for Fe3+ and Fe2+ by Mössbauer spectroscopy and micro-X-ray absorption near edge structure (micro-XANES) spectroscopy. One bar liquids equilibrated at FMQ-3 to FMQ+3 show a much lower Fe3+/ΣFe than terrestrial basalts at the same conditions. As melt P2O5 contents increase from 0 to 3 wt% (at fixed pressure, temperature, and fO2), Fe3+/ΣFe decreases from 0.07 to 0.05, but this is within error on the measurements. Temperature increases between 1200 and 1500 °C cause little to no variation in Fe3+/ΣFe. Pressure increases from 1 to 4 GPa cause a 0.06 decrease in Fe3+/ΣFe. The trends with pressure and temperature are in agreement with results of previous studies. Combining our new series of data allows derivation of an expression to calculate Fe3+/Fe2+ for high-FeO melts such as martian magmas. ln(XFe3+/XFe2+) = a lnfO2 + b/T + cP/T + dXFeO + eXAl2O3 + fXCaO + gXNa2O + hXK2O + iXP2O5 + j This expression can be used to show that decompressed melts become slightly more oxidized at the surface (compared to 4 GPa). Magnetite stability is suppressed by the lower Fe3+/Fe2+ of the high- FeO melts. Magnetite stability is a function of Fe2O3 and temperature and is stable ~50 °C lower than typical terrestrial basalt. Difficulty in producing magnetite as a liquidus phase in magmatic systems suggests either that many martian basalts are more oxidized than FMQ (but not represented among meteorite collections), that the titano-magnetite only forms upon cooling below ~1000 °C at FMQ, or that the magnetite has a secondary origin.

NEEMO 18–20: Analog testing for mitigation of communication latency during human space exploration

NASA Extreme Environment Mission Operations (NEEMO) is an underwater spaceflight analog that allows a true mission-like operational environment and uses buoyancy effects and added weight to simulate different gravity levels. Three missions were undertaken from 2014-2015, NEEMO 18-20. All missions were performed at the Florida International Universitys Aquarius Reef Base, an undersea research habitat. During each mission, the effects of communication latencies on operations concepts, timelines, and tasks were studied METHODS: Twelve subjects (4 per mission) were weighed out to simulate near-zero or partial gravity extravehicular activity (EVA) and evaluated different operations concepts for intergration and management of a simulated Earth-based science team (ST) to provide input and direction during exploration activities. Exploration traverses were preplanned based on precursor data. Subjects completed science-related tasks including presampling surveys, geologic-based sampling, and marine-based sampling as a portion of their tasks on saturation dives up to 4 hours in duration that were designed to simulate EVA on Mars or the moons of Mars. One-way communication latencies, 5 and 10 minutes between space and mission control, were simulated throughout the missions. Objective data included task completion times, total EVA times, crew idle time, translation time, ST assimilation time (defined as time available for ST to discuss data/imagery after data acquisition). Subjective data included acceptability, simulation quality, capability assessment ratings, and comments. RESULTS: Precursor data can be used effectively to plan and execute exploration traverse EVAs (plans included detailed location of science sites, high-fidelity imagery of the sites, and directions to landmarks of interest within a site). Operations concepts that allow for presampling surveys enable efficient traverse execution and meaningful Mission Control Center (MCC) interaction across communication latencies and can be done with minimal crew idle time. Imagery and contextual information from the EVA crew that is transmitted real-time to the intravehicular activity (IVA) crewmember(s) can be used to verify that exploration traverse plans are being executed correctly. That same data can be effectively used by MCC (across comm latency) to provide meaningful feedback and instruction to the crew regarding sampling priorities, additional tasks, and changes to the EVA timeline. Text / data capabilities are preferred over voice capabilities between MCC and IVA when executing exploration traverse plans over communication latency.

Mauna Kea, Hawaii, as an Analog Site for Future Planetary Resource Exploration: Results from the 2010 ILSO-ISRU Field-Testing Campaign

The major advances in knowledge of extraterrestrial bodies come from in situ measurements on robotized measuring devices deployed by international space missions, for example, on the Moon and Mars. It is essential to test these instruments in environments on Earth thatbearacloseresemblancetoplanetaryconditions.Withintheframeworkofthe2010InternationalLunarSurfaceOperationInSituResource Utilization (2010 ILSO-ISRU) Analog Test, a suite of scientific instruments developed for in situ lunar research was field tested and cali- brated on the Mauna Kea volcano in Hawaii on January 27 to February 11, 2010. This site will beused as one ofthe future standard test sites to calibrate instruments forin situ lunarresearch.In 2010, atotalof eight scientificteams tested instrument capabilities at the test site.In this paper, a geological setting for this new field-test site, a description of the instruments that were tested during the 2010 ILSO-ISRU field campaign, and a short discussion of each instrument about the validity and use of the results obtained during the test are provided. These results will serve as reference for future test campaigns. DOI: 10.1061/(ASCE)AS.1943-5525.0000200.

Moon and Mars Analog Mission Activities for Mauna Kea 2012

Rover-based 2012 Moon and Mars Analog Mission Activities (MMAMA) scientific investigations were recently completed at Mauna Kea, Hawaii. Scientific investigations, scientific input, and science operations constraints were tested in the context of an existing project and protocols for the field activities designed to help NASA achieve the Vision for Space Exploration. Initial science operations were planned based on a model similar to the operations control of the Mars Exploration Rovers (MER). However, evolution of the operations process occurred as the analog mission progressed. We report here on the preliminary sensor data results, an applicable methodology for developing an optimum science input based on productive engineering and science trades and the science operations approach for an investigation into the valley on the upper slopes of Mauna Kea identified as “Apollo Valley.”