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Featured researches published by Takehiko Goto.


Tetrahedron Letters | 1989

First direct synthesis of 4,8-dialkylbenzo[1,2-d;4,5-d′]bis[1,2,3]trithioles and 6,10-dialkyl[1,2,3]trithiolo[5,4-h]benzopentathiepins from 1,4-dialkyl-2,3,5,6-tetrabromobenzenes

Ryu Sato; Takeshi Kimura; Takehiko Goto; Minoru Saito; Chizuko Kabuto

Abstract New cyclic polysulfides, 4,8-dialkylbenzo[1,2-d;4,5-d′]bis[1,2,3]-trithioles ( 2 ) and 6,10-dialkyl[1,2,3]trithiolo[5,4-h]benzopentathiepins ( 3 ), were directly synthesized by nucleophilic substitution of 1,4-dialkyl-2,3,5,6-tetrahalobenzenes ( 1 ) with elemental sulfur in liquid ammonia.


Heterocycles | 1988

Chemistry on benzopentathiepin reactions of benzopentathiepin with aromatic compounds in the presence of lewis acid

Ryu Sato; Akira Onodera; Takehiko Goto; Minoru Saito

Benzopentathiepin (BPT) reacted with many aromatic compounds such as benzene, 1,4-dimethylbenzene, and naphthalene in the presence of Lewis acid to give various thianthrenes in moderate yields. BPT was found to serve as a 1,4-dication synthon


Tetrahedron Letters | 1983

NAD(P)+-NAD(P)H Model. 46. Kinetic study on the reduction with a sulfur-containing NAD(P)H model

Atsuyoshi Ohno; Hisami Kobayashi; Shinzaburo Oka; Takehiko Goto

Abstract Kinetics on the reduction with an NAD(P)H model bearing a divalent sulfur atom in the N-alkyl substituent has been studied. The sulfur atom retards the electron-transfer process.


Tetrahedron Letters | 1988

Synthesis and reactions of new cyclic polysulfides. 6,10-Disubstituted[1,2,3]trithiolo[5,4-h]benzopentathiepins

Ryu Sato; Takeshi Kimura; Takehiko Goto; Minoru Saito


Bulletin of the Chemical Society of Japan | 1988

Synthesis of Cyclic Polysulfides. Reactions of Dithiols and Related Compounds with Elemental Sulfur in Liquid Ammonia

Ryu Sato; Satoru Saito; Hiroshi Chiba; Takehiko Goto; Minoru Saito


Chemistry Letters | 1986

Synthesis of benzopentathiepins. Reactions of 1,3-benzodithiole-2-thione and 1,2-benzenedithiol with elemental sulfur in liquid ammonia

Ryu Sato; Satoru Saito; Hiroshi Chiba; Takehiko Goto; Minoru Saito


Chemistry Letters | 1989

Novel Formations of Unsymmetrical 1,2,5-Benzotrithiepins from Olefins and Benzopentathiepin in the Presence of Lewis Acid. Benzopentathiepin as a Novel 1,5-Dipole Synthon

Ryu Sato; Akira Onodera; Takehiko Goto; Minoru Saito


Bulletin of the Chemical Society of Japan | 1989

Magnesium Ion Assisted Highly Regio- and Chemoselective Reduction of 5H-Pyrrolo[3,4-b]pyridine-5,7(6H)-diones with Sodium Borohydride. A Convenient Synthesis of 6,7-Dihydro-7-hydroxy-5H-pyrrolo[3,4-b]pyridin-5-ones

Takehiko Goto; Michio Konno; Minoru Saito; Ryu Sato


Chemistry Letters | 1987

Benzopentathiepin as sulfurization reagent. Novel synthesis of thiosulfonates from sulfinates

Ryu Sato; Yasuo Akutsu; Takehiko Goto; Minoru Saito


Chemistry Letters | 1984

NOVEL CONVERSION OF AROMATIC THIOAMIDES AND ALDEHYDES INTO NITRILES WITH ELEMENTAL SULFUR AND SODIUM NITRITE IN LIQUID AMMONIA

Ryu Sato; Kaoru Itoh; Kazumi Itoh; Hironori Nishina; Takehiko Goto; Minoru Saito

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