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Terence M. Barnhart

University of Michigan

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Publication

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Physica B-condensed Matter | 1995

EXAFS characterization of methyl and phenyl cuprates in solution

Terence M. Barnhart; James E. Penner-Hahn

Abstract EXAFS structural characterization of organocuprates formed from copper iodide and 2 and 3 equivalents of either MeLi or PhLi have been performed. Evidence is presented for the formation of an equilibrium between Ph 2 CuLi and Ph 3 CuLi in THF solution which is not present in the methyl analogs.

Journal of the American Chemical Society | 1995

Structural Characterization of Organocuprate reagents. EXAFS Spectroscopy and ab Initio Calculations

Timothy L. Stemmler; Terence M. Barnhart; James E. Penner-Hahn; Charles E. Tucker; Paul Knochel; Marlis Boehme; Gernot Frenking

Journal of Organic Chemistry | 1995

Structural Characterization of Organocopper Complexes by EXAFS and XANES: Evidence that Cyanide Does Not Coordinate to Cu in Dimethyl Cuprate Solutions

Terence M. Barnhart; Hui Huang; James E. Penner-Hahn

Journal of the American Chemical Society | 1996

Infrared Spectroscopic Characterization of Cyanocuprates

Hui Huang; Khris Alvarez; Qiang Lui; Terence M. Barnhart; James P. Snyder; James E. Penner-Hahn

Journal of the American Chemical Society | 1992

Spectroscopic observation of a thermal carbon-hydrogen bond insertion reaction at 5 K: intramolecular rearrangement of Fe(CO)3(.eta.2-C3H6) to produce HFe(CO)3(.eta.3-C3H5)

Terence M. Barnhart; Robert J. McMahon

Inorganic Chemistry | 1992

Isomerism in coordinatively unsaturated tricarbonyl-.eta.2-etheneiron complexes

Terence M. Barnhart; Richard F. Fenske; Robert J. McMahon

Journal of the American Chemical Society | 1995

CONVERSION OF A FE2S2 FERREDOXIN INTO A GA3+ RUBREDOXIN

Sophia Kazanis; Thomas C. Pochapsky; Terence M. Barnhart; James E. Penner-Hahn; Urooj A. Mirza; Brian T. Chait

Journal of the American Chemical Society | 1993

Gas-phase photodissociation of (.eta.5-cyclopentadienyl)Fe(CO)2R and (.eta.5-indenyl)Fe(CO)2R in a molecular beam: competitive loss of alkyl radical and alkene detected by vacuum-ultraviolet ionization and time-of-flight mass spectrometry

Jeffrey A. Bartz; Terence M. Barnhart; Douglas B. Galloway; L. Gregory Huey; Thomas Glenewinkel-Meyer; Robert J. McMahon; F. Fleming Crim

Journal of the American Chemical Society | 1996

Erratum: Infrared spectroscopic characterization of cyanocuprates (J. Am. Chem. Soc. 1996, 118, 8808-8816)

Hui Huang; Khris Alvarez; Qiang Cui; Terence M. Barnhart; James P. Snyder; James E. Penner-Hahn

Journal of the American Chemical Society | 1995

Conversion of a FeS ferredoxin into a Ga{sup 3+} rubredoxin

Sophia Kazanis; Thomas C. Pochapsky; Terence M. Barnhart; James E. Penner-Hahn; Urooj A. Mirza; Brian T. Chait

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James E. Penner-Hahn

University of Michigan

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Robert J. McMahon

University of Wisconsin-Madison

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Hui Huang

University of Michigan

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Brian T. Chait

Rockefeller University

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Douglas B. Galloway

University of Wisconsin-Madison

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F. Fleming Crim

University of Wisconsin-Madison

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James P. Snyder

Emory University

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Jeffrey A. Bartz

University of Wisconsin-Madison

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Khris Alvarez

University of Michigan

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L. Gregory Huey

University of Wisconsin-Madison

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