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The 13th international winterschool on electronic properties of novel materials- science and technology of molecular nanostructures | 1999

Preparation of carbyne-like films by dehydrochlorination of poly(vinylidene chloride)

Tetsuya Danno; Kaori Murakami; Ruriko Ishikawa

Films of conjugated carbyne-like system was obtained by dehydrochlorination of poly(vinylidene chloride) (PVDC) by the two step treatments with 1,8-diazabicyclo [5,4,0]undec-7-ene (DBU). Amorphous region of PVDC was dehydrochlorinated in the proper swelling solution at the first step treatment and the crystalline region was treated in the pure solvent at the second step, so that the film shape was kept after the whole treatments. Two characteristic IR absorption bands were observed at ca. 2000 and ca. 1650 cm−1 which are assigned to stretching vibration of polyyne structure (VC=C) and that of polyene structure (VC=C), respectively. The intensity of VC=C decreased with time upon storage even under the inert atmosphere.


Journal of Polymer Science Part B | 2006

Control of diameter, morphology, and structure of PVDF nanofiber fabricated by electrospray deposition

Muhamad Nasir; Hidetoshi Matsumoto; Tetsuya Danno; Mie Minagawa; Toshihira Irisawa; Masatoshi Shioya; Akihiko Tanioka


Polymer Journal | 2007

Formation of β-Phase Crystalline Structure of PVDF Nanofiber by Electrospray Deposition: Additive Effect of Ionic Fluorinated Surfactant

Muhamad Nasir; Hidetoshi Matsumoto; Mie Minagawa; Akihiko Tanioka; Tetsuya Danno; Hideo Horibe


Polymer Journal | 2007

Preparation of Porous PVDF Nanofiber from PVDF/PVP Blend by Electrospray Deposition

Muhamad Nasir; Hidetoshi Matsumoto; Mie Minagawa; Akihiko Tanioka; Tetsuya Danno; Hideo Horibe


Journal of Applied Polymer Science | 2009

PVDF/PMMA composite nanofiber fabricated by electrospray deposition: Crystallization of PVDF induced by solvent extraction of PMMA component

Tetsuya Danno; Hidetoshi Matsumoto; Muhamad Nasir; Mie Minagawa; Hideo Horibe; Akihiko Tanioka


Polymer Journal | 2009

Preparation of PVDF/PMMA Blend Nanofibers by Electrospray Deposition: Effects of Blending Ratio and Humidity

Muhamad Nasir; Hidetoshi Matsumoto; Mie Minagawa; Akihiko Tanioka; Tetsuya Danno; Hideo Horibe


Journal of Polymer Science Part B | 2008

Fine structure of PVDF nanofiber fabricated by electrospray deposition

Tetsuya Danno; Hidetoshi Matsumoto; Muhamad Nasir; S. Shimizu; Mie Minagawa; J. Kawaguchi; Hideo Horibe; Akihiko Tanioka


Polymer Journal | 2013

Effect of heat-treatment temperature after polymer melt and blending ratio on the crystalline structure of PVDF in a PVDF/PMMA blend

Hideo Horibe; Yukari Hosokawa; Hironori Oshiro; Yasutaka Sasaki; Seiji Takahashi; Akihiko Kono; Takashi Nishiyama; Tetsuya Danno


Kobunshi Ronbunshu | 2012

Crystal Structure Control of Poly(vinylidene fluoride) (PVDF) in the Blend Films of PVDF and Poly(methyl methacrylate) (PMMA) Prepared by Solvent Casting

Hironori Oshiro; Akihiko Kono; Tetsuya Danno; Hideo Horibe


Kobunshi Ronbunshu | 2010

Crystal Structure Control of Poly(vinylidene fluoride) Using Solvent Casting

Hironori Oshiro; Tubasa Sato; Masashi Yamamoto; Akihiko Kono; Hideo Horibe; Hiroyasu Masunaga; Tetsuya Danno; Hidetoshi Matumoto; Akihiko Tanioka

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Akihiko Tanioka

Tokyo Institute of Technology

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Hidetoshi Matsumoto

Tokyo Institute of Technology

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Mie Minagawa

Tokyo Institute of Technology

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Muhamad Nasir

Tokyo Institute of Technology

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Akihiko Kono

Kanazawa Institute of Technology

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Fuki Kanosue

Kochi Women's University

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Masahiro Goto

Kochi Women's University

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