Thomas P. Guilderson

IntCal04 terrestrial radiocarbon age calibration, 0-26 cal kyr BP.

A new calibration curve for the conversion of radiocarbon ages to calibrated (cal) ages has been constructed and internationally ratified to replace IntCal98, which extended from 0-24 cal kyr BP (Before Present, 0 cal BP = AD 1950). The new calibration data set for terrestrial samples extends from 0-26 cal kyr BP, but with much higher resolution beyond 11.4 cal kyr BP than IntCal98. Dendrochronologically-dated tree-ring samples cover the period from 0-12.4 cal kyr BP. Beyond the end of the tree rings, data from marine records (corals and foraminifera) are converted to the atmospheric equivalent with a site-specific marine reservoir correction to provide terrestrial calibration from 12.4-26.0 cal kyr BP. A substantial enhancement relative to IntCal98 is the introduction of a coherent statistical approach based on a random walk model, which takes into account the uncertainty in both the calendar age and the 14C age to calculate the underlying calibration curve (Buck and Blackwell, this issue). The tree-ring data sets, sources of uncertainty, and regional offsets are discussed here. The marine data sets and calibration curve for marine samples from the surface mixed layer (Marine04) are discussed in brief, but details are presented in Hughen et al. (this issue a). We do not make a recommendation for calibration beyond 26 cal kyr BP at this time; however, potential calibration data sets are compared in another paper (van der Plicht et al., this issue).

Marine04 marine radiocarbon age calibration, 0-26 cal kyr BP

New radiocarbon calibration curves, IntCal04 and Marine04, have been constructed and internationally rati- fied to replace the terrestrial and marine components of IntCal98. The new calibration data sets extend an additional 2000 yr, from 0-26 cal kyr BP (Before Present, 0 cal BP = AD 1950), and provide much higher resolution, greater precision, and more detailed structure than IntCal98. For the Marine04 curve, dendrochronologically-dated tree-ring samples, converted with a box diffusion model to marine mixed-layer ages, cover the period from 0-10.5 cal kyr BP. Beyond 10.5 cal kyr BP, high-res- olution marine data become available from foraminifera in varved sediments and U/Th-dated corals. The marine records are corrected with site-specific 14C reservoir age information to provide a single global marine mixed-layer calibration from 10.5-26.0 cal kyr BP. A substantial enhancement relative to IntCal98 is the introduction of a random walk model, which takes into account the uncertainty in both the calendar age and the 14C age to calculate the underlying calibration curve (Buck and Blackwell, this issue). The marine data sets and calibration curve for marine samples from the surface mixed layer (Marine04) are discussed here. The tree-ring data sets, sources of uncertainty, and regional offsets are presented in detail in a companion paper by Reimer et al. (this issue). ABSTRACT. New radiocarbon calibration curves, IntCal04 and Marine04, have been constructed and internationally rati- fied to replace the terrestrial and marine components of IntCal98. The new calibration data sets extend an additional 2000 yr, from 0-26 cal kyr BP (Before Present, 0 cal BP = AD 1950), and provide much higher resolution, greater precision, and more detailed structure than IntCal98. For the Marine04 curve, dendrochronologically-dated tree-ring samples, converted with a box diffusion model to marine mixed-layer ages, cover the period from 0-10.5 cal kyr BP. Beyond 10.5 cal kyr BP, high-res- olution marine data become available from foraminifera in varved sediments and U/Th-dated corals. The marine records are corrected with site-specific 14C reservoir age information to provide a single global marine mixed-layer calibration from 10.5-26.0 cal kyr BP. A substantial enhancement relative to IntCal98 is the introduction of a random walk model, which takes into account the uncertainty in both the calendar age and the 14C age to calculate the underlying calibration curve (Buck and Blackwell, this issue). The marine data sets and calibration curve for marine samples from the surface mixed layer (Marine04) are discussed here. The tree-ring data sets, sources of uncertainty, and regional offsets are presented in detail in a companion paper by Reimer et al. (this issue).

Old radiocarbon ages in the southwest Pacific Ocean during the last glacial period and deglaciation

Marine radiocarbon (14C) dates are widely used for dating oceanic events and as tracers of ocean circulation, essential components for understanding ocean–climate interactions. Past ocean ventilation rates have been determined by the difference between radiocarbon ages of deep-water and surface-water reservoirs, but the apparent age of surface waters (currently ∼400 years in the tropics and ∼1,200 years in Antarctic waters) might not be constant through time, as has been assumed in radiocarbon chronologies and palaeoclimate studies. Here we present independent estimates of surface-water and deep-water reservoir ages in the New Zealand region since the last glacial period, using volcanic ejecta (tephras) deposited in both marine and terrestrial sediments as stratigraphic markers. Compared to present-day values, surface-reservoir ages from 11,900 14C years ago were twice as large (800 years) and during glacial times were five times as large (2,000 years), contradicting the assumption of constant surface age. Furthermore, the ages of glacial deep-water reservoirs were much older (3,000–5,000 years). The increase in surface-to-deep water age differences in the glacial Southern Ocean suggests that there was decreased ocean ventilation during this period.

Extreme longevity in proteinaceous deep-sea corals

Deep-sea corals are found on hard substrates on seamounts and continental margins worldwide at depths of 300 to ≈3,000 m. Deep-sea coral communities are hotspots of deep ocean biomass and biodiversity, providing critical habitat for fish and invertebrates. Newly applied radiocarbon age dates from the deep water proteinaceous corals Gerardia sp. and Leiopathes sp. show that radial growth rates are as low as 4 to 35 μm year−1 and that individual colony longevities are on the order of thousands of years. The longest-lived Gerardia sp. and Leiopathes sp. specimens were 2,742 years and 4,265 years, respectively. The management and conservation of deep-sea coral communities is challenged by their commercial harvest for the jewelry trade and damage caused by deep-water fishing practices. In light of their unusual longevity, a better understanding of deep-sea coral ecology and their interrelationships with associated benthic communities is needed to inform coherent international conservation strategies for these important deep-sea habitat-forming species.

Sequence of events during the last deglaciation in Southern Ocean sediments and Antarctic ice cores

variation depends on the age model as 14 C determinations cannot be obtained for the time interval of 29.5–14.5 ka. Assuming a constant sedimentation rate for this interval, our data suggest that sea ice and nutrient changes at about 19 ka B.P. lead the increase in atmospheric pCO2 by approximately 2000 years. Our diatom-based sea ice record is in phase with the sodium record of the Vostok ice core, which is related to sea ice cover and similarly leads the increase in atmospheric CO2. If gas exchange played a major role in determining glacial to interglacial CO2 variations, then a delay mechanism of a few thousand years is needed to explain the observed sequence of events. Otherwise, the main cause of atmospheric pCO2 change must be sought elsewhere, rather than in the Southern Ocean. INDEX TERMS: 3344 Meteorology and Atmospheric Dynamics: Paleoclimatology; 4267 Oceanography: General: Paleoceanography; 4845 Oceanography: Biological and Chemical: Nutrients and nutrient cycling; 4870 Oceanography: Biological and Chemical: Stable isotopes; 9325 Information Related to Geographic Region: Atlantic Ocean; KEYWORDS: biogenic opal, stable isotopes, diatoms, IRD, last glacial, Southern Ocean

Reliability of coral isotope records from the western Pacific warm pool: A comparison using age-optimized records

Stable isotope analysis of two separate corals from Nauru Island in the warm pool of the western tropical Pacific confirm that coral oxygen isotopes are a robust recorder of environmental variables. Coral delta(18)O faithfully records interannual variability even when strongly influenced by kinetic effects. Interannual to decadal variability of coral delta(13)C remains enigmatic; only one of the two corals exhibits the expected light-delta(13)C response in the interannual band. Coral delta(18)O from this region has a great similarity to global instrumental temperature records reflecting the impact of the Pacific warm pool and variations of the Indonesian Low in concert with El Nino-Southern Oscillation on global climate. Since 1896, coral delta(18)O has exhibited a cumulative decrease of 0.7 parts per thousand, which reflects a combination of warming and more frequent El Nino events (precipitation) affecting the surface waters of this region.

Southwest Subtropical Pacific Surface Water Radiocarbon In A High-Resolution Coral Record

We have generated a high-resolution coral 6,14(: record from the southwest subtropical Pacific spanning the last 50 yr. Prebomb (1950-1956) 6,t4C values average -52%0. Values begin to increase in 1957, reaching a maximum in the early 1970s, about 10 yr after the atmospheric peale There is a consistent 10-15%0 seasonal cycle whose relationship with vertical mixing evol ves as a consequence of the penetration of the bomb transient into subsurface waters. Comparison of this record with that simulated in an ocean general circulation model highlights the difficulty in modeling vertical exchange processes.

CHANGES OF SUBTROPICAL NORTH PACIFIC RADIOCARBON AND CORRELATION WITH CLIMATE VARIABILITY

We show that high-precision radiocarbon (∆14C) measurements from annual bands of a Hawaiian surface coral decreased by 7‰ from AD 1893 to 1952. This decrease is coincident with the Suess Effect, which is mostly due to the dilution of natural levels of 14C by 14C-free fossil fuel CO2. This decrease is equal to that expected in surface waters of the subtropical gyres, and indicates that the surface waters of the North Pacific were in steady state with respect to long term mixing of CO2 during the past century. Correlation between ∆ 14 C and North Pacific gyre sea surface temperatures indicates that vertical mix- ing local to Hawaii and the North Pacific gyre as a whole is the likely physical mechanism to result in variable ∆14C. Prior to 1920, this correlation starts to break down; this may be related to the non-correlation between biennial ∆14C values in corals from the southwest Pacific and El Nino events observed during this period as well.

Upper-ocean-to-atmosphere radiocarbon offsets imply fast deglacial carbon dioxide release

Radiocarbon in the atmosphere is regulated largely by ocean circulation, which controls the sequestration of carbon dioxide (CO2) in the deep sea through atmosphere–ocean carbon exchange. During the last glaciation, lower atmospheric CO2 levels were accompanied by increased atmospheric radiocarbon concentrations that have been attributed to greater storage of CO2 in a poorly ventilated abyssal ocean. The end of the ice age was marked by a rapid increase in atmospheric CO2 concentrations that coincided with reduced 14C/12C ratios (Δ14C) in the atmosphere, suggesting the release of very ‘old’ (14C-depleted) CO2 from the deep ocean to the atmosphere. Here we present radiocarbon records of surface and intermediate-depth waters from two sediment cores in the southwest Pacific and Southern oceans. We find a steady 170 per mil decrease in Δ14C that precedes and roughly equals in magnitude the decrease in the atmospheric radiocarbon signal during the early stages of the glacial–interglacial climatic transition. The atmospheric decrease in the radiocarbon signal coincides with regionally intensified upwelling and marine biological productivity, suggesting that CO2 released by means of deep water upwelling in the Southern Ocean lost most of its original depleted-14C imprint as a result of exchange and isotopic equilibration with the atmosphere. Our data imply that the deglacial 14C depletion previously identified in the eastern tropical North Pacific must have involved contributions from sources other than the previously suggested carbon release by way of a deep Southern Ocean pathway, and may reflect the expanded influence of the 14C-depleted North Pacific carbon reservoir across this interval. Accordingly, shallow water masses advecting north across the South Pacific in the early deglaciation had little or no residual 14C-depleted signals owing to degassing of CO2 and biological uptake in the Southern Ocean.

Climate change in lowland Central America during the late deglacial and early Holocene

The transition from arid glacial to moist early Holocene conditions represented a pro- found change in northern lowland Neotropical climate. Here we report a detailed record of changes in moisture availability during the latter part of this transition ( � 11 250 to 7500 cal. yr BP) inferred from sediment cores retrieved in Lake Peten Itza ´, northern Guatemala. Pollen assemblages demon- strate that a mesic forest had been largely established by � 11 250 cal. yr BP, but sediment properties indicate that lake level was more than 35 m below modern stage. From 11 250 to 10 350 cal. yr BP, during the Preboreal period, lithologic changes in sediments from deep-water cores (>50 m below modern water level) indicate several wet-dry cycles that suggest distinct changes in effective moisture. Four dry events (designated PBE1-4) occurred centred at 11 200, 10 900, 10 700 and 10 400 cal. yr BP and correlate with similar variability observed in the Cariaco Basin titanium record and glacial meltwater pulses into the Gulf of Mexico. After 10 350 cal. yr BP, multiple sediment proxies suggest a shift to a more persistently moist early Holocene climate. Comparison of results from Lake Peten Itzawith other records from the circum-Caribbean demonstrates a coherent climate response during the entire span of our record. Furthermore, lowland Neotropical climate during the late deglacial and early Holocene period appears to be tightly linked to climate change in the high- latitude North Atlantic. We speculate that the observed changes in lowland Neotropical precipitation were related to the intensity of the annual cycle and associated displacements in the mean latitudinal position of the Intertropical Convergence Zone and Azores-Bermuda high-pressure system. This mechanism operated on millennial-to-submillennial timescales and may have responded to changes in solar radiation, glacial meltwater, North Atlantic sea ice, and the Atlantic meridional overturning circulation (MOC). Copyright 2005 John Wiley & Sons, Ltd.