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Dive into the research topics where Tsuneo Hagiwara is active.

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Featured researches published by Tsuneo Hagiwara.


Journal of The Chemical Society, Chemical Communications | 1974

Formation of a benzosilacyclopentene. Formation of a silacyclopropane by intramolecular insertion of a silylcarbene

Wataru Ando; Akira Sekiguchi; Tsuneo Hagiwara; Toshihiko Migita

Pyrolysis of phenyltrimethylsilyldiazomethane gave 1,1-dimethyl-2,3-benzo-1-silacyclopent-2-ene and the dimerization product of the silylcarbene, whilst photolysis in benzene, gave only the dimerization product.


Journal of the American Chemical Society | 1973

Formation of an unstable silicon-carbon double bond in the photodecomposition of trimethylsilyldiazoacetate

Wataru Ando; Tsuneo Hagiwara; Toshihiko Migita


Journal of the American Chemical Society | 1979

Photochemical decomposition of trimethylsilyl diazoacetates in alcohols

Wataru Ando; Akira Sekiguchi; Tsuneo Hagiwara; Toshihiko Migita; Vinay Chowdhry; F. H. Westheimer; Seetha Kammula; Marilyn Green; Maitland Jones


Bulletin of the Chemical Society of Japan | 1975

The Photolysis of Dimethyl Diazomalonate in Alcohols. The Detection of Triplet Carbene

Wataru Ando; Tsuneo Hagiwara; Toshihiko Migita


Journal of the American Chemical Society | 1974

Decomposition of diazo compounds in alkylthio- and alkoxytrimethylsilanes. Possible 1,2-trimethylsilyl shift in unstable silylsulfonium and silyloxonium ylides

Wataru Ando; Kenji Konishi; Tsuneo Hagiwara; Toshihiko Migita


Tetrahedron Letters | 1974

Selective carbene insertion into carbon-sulfur bonds in the photodecomposition of silyldiazoacetate. II

Wataru Ando; Tsuneo Hagiwara; Toshihiko Migita


ChemInform | 1974

FORMATION OF AN UNSTABLE SILICON-CARBON DOUBLE BOND IN THE PHOTODECOMPOSITION OF TRIMETHYLSILYLDIAZOACETATE

Wataru Ando; Tsuneo Hagiwara; Toshihiko Migita


ChemInform | 1974

DECOMPOSITION OF DIAZO COMPOUNDS IN ALKYLTHIO- AND ALKOXYTRIMETHYLSILANES, A POSSIBLE 1,2-TRIMETHYLSILYL SHIFT IN UNSTABLE SILYLSULFONIUM AND SILYLOXONIUM YLIDES

Wataru Ando; Kenji Konishi; Tsuneo Hagiwara; Toshihiko Migita


ChemInform | 1975

THE PHOTOLYSIS OF DIMETHYL DIAZOMALONATE IN ALCOHOLS. THE DETECTION OF TRIPLET CARBENE

Wataru Ando; Tsuneo Hagiwara; Toshihiko Migita


ChemInform | 1974

FORMATION OF BENZOSILACYCLOPENTENE, FORMATION OF A SILACYCLOPROPANE BY INTRAMOLECULAR INSERTION OF A SILYLCARBENE

Wataru Ando; Akira Sekiguchi; Tsuneo Hagiwara; Toshihiko Migita

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