Tsung-Yi Tang

Strain relaxation and quantum confinement in InGaN/GaN nanoposts

Nanoposts of 10?40?nm top diameter on an InGaN/GaN quantum well structure were fabricated using electron-beam lithography and inductively coupled plasma reactive ion etching. Significant blue shifts up to 130?meV in the photoluminescence (PL) spectrum were observed. The blue-shift range increases with decreasing post diameter. For nanoposts with significant strain relaxation, the PL spectral peak position becomes less sensitive to carrier screening. On the basis of the temperature-dependent PL and time-resolved PL measurements and a numerical calculation of the effect of quantum confinement, we conclude that the optical behaviours of the nanoposts are mainly controlled by the combined effect of 3D quantum confinement and strain relaxation.

Phosphor-free white-light light-emitting diode of weakly carrier-density-dependent spectrum with prestrained growth of InGaN∕GaN quantum wells

The authors grew a white-light InGaN∕GaN quantum-well (QW) light-emitting diode epitaxial structure with its electroluminescence spectrum close to the ideal condition in the Commission International de l’Eclairage chromaticity based on the prestrained metal-organic chemical vapor deposition technique. The prestrained growth leads to the efficient yellow emission from three InGaN∕GaN QWs of increased indium incorporation. The color mixing for white light is implemented by adding a blue-emitting QW at the top of the yellow-emitting QWs. The blueshifts of the blue and yellow spectral peaks of the generated electroluminescence spectra are only 1.67 and 8nm, respectively, when the injection current increases from 10to70mA. Such small blueshifts imply that the piezoelectric fields in their QWs are significantly weaker than those previously reported.

Prestrained effect on the emission properties of InGaN∕GaN quantum-well structures

The authors demonstrate the spectral redshift of the quantum wells (QWs) designated for green emission into the orange range in a light-emitting diode by adding a violet-emitting QW at the bottom in metal-organic chemical vapor deposition. An electroluminescence redshift of 53nm was obtained. The cathodoluminescence spectra indicated that the long-wavelength QWs close to the violet one were strongly influenced by this added QW and mainly emitted the orange photons. Those near the top were less affected. This influence is supposed to originate from the prestrained effect in the barrier layer right above the violet QW. Such a prestrained effect is expected to be more effective when the underlying QW is well shaped and the heterojunction strain is strong, like the case of the violet QW. This effect is weak between the high-indium QWs, in which the formation of indium-rich clusters releases the strain.

Temperature dependence of the surface plasmon coupling with an InGaN∕GaN quantum well

The authors demonstrate the temperature-dependent behavior of the surface plasmon (SP) coupling with two InGaN∕GaN quantum-well (QW) structures of different internal quantum efficiencies. The SP modes are generated at the interface between the QW structures and Ag thin films coated on their tops. It is observed that the SP-QW coupling rate increases with temperature. Such a trend may rely on several factors, including the availability of carriers with sufficient momenta for transferring the energy and momentum into the SP modes and possibly the variation of the SP density of state with temperature. Although the required momentum matching condition only needs the thermal energy corresponding to a few tens of Kelvins, the carrier delocalization process results in a significantly higher probability of SP-carrier momentum matching and hence SP-QW coupling.

Threading dislocation evolution in patterned GaN nanocolumn growth and coalescence overgrowth

Threading dislocation (TD) evolution during patterned GaN nanocolumn (NC) growth and coalescence overgrowth with metal-organic chemical vapor deposition is studied based on the comparisons of NC and coalescence overgrowth samples of different NC cross-section diameters and spacing sizes. From the measurement results of depth-dependent x-ray diffraction and cross-section transmission electron microscopy, it is found that the TD density in an NC depends on the patterned hole size for NC growth. Also, the TD formation at the beginning of coalescence overgrowth is related to the NC spacing size. Although the TD density at the bottom of the overgrown layer is weakly dependent on NC and spacing sizes, at its top surface, the TD density strongly relies on NC size. Among the overgrowth samples of different NC diameters and spacing sizes with a fixed NC diameter/spacing ratio, the one with the smallest size and spacing leads to the lowest TD density, the largest lateral domain size, and the highest photoluminescen...

Cluster size and composition variations in yellow and red light-emitting InGaN thin films upon thermal annealing

We study thermal annealing effects on the size and composition variations of indium-aggregated clusters in two InGaN thin films with photoluminescence (PL) in the yellow and red ranges. The methods of investigation include optical measurement, nanoscale material analysis, and theoretical calculation. Such a study is important for determining the relation between the band gap and the average indium content of InGaN. In one of the samples, the major part of the PL spectrum is shifted from the yellow band into the blue range upon thermal annealing. In the other sample, after thermal annealing, a broad spectrum covering the whole visible range is observed. Cathodo-luminescence (CL) spectra show that the spectral changes occur essentially in the photons emitted from the shallow layers of the InGaN films. Photon emission spectra from the deeper layers are essentially unaffected by thermal annealing. The spectral changes upon thermal annealing are mainly attributed to the general trend of cluster size reduction....

Nitride Nanocolumns for the Development of Light-Emitting Diode

The progress of light-emitting-diode (LED) development based on nitride nanocolumn (NC) growth, including InGaN/GaN quantum-well (QW) growth on NCs and regularly arranged GaN NC growth, is first reviewed. Then, the coalescence-overgrowth results based on patterned GaN NC growth are introduced. The overgrowth quality dependence on NC cross-sectional size and NC spacing size is discussed. Generally, a smaller NC dimension and spacing size lead to higher overgrowth quality, including lower threading dislocation (TD) density and larger lateral domain size. Next, the emission enhancement results of blue- and green-emitting InGaN/GaN QW and LED structures based on NC growth and coalescence overgrowth are presented. Significant enhancements (up to ~100% output intensity increase in a blue LED) are demonstrated. For LED applications, the TD density reduction in an overgrown GaN template can more effectively enhance the emission efficiency of a blue LED, when compared with a green LED.

Thermal annealing effects on an InGaN film with an average indium mole fraction of 0.31

We compared the optical and material properties of an InGaN thin film with an average indium content at 0.31 between as-grown and postgrowth thermally annealed conditions. The major part of the photoluminescence spectrum was shifted from the original yellow band into the blue range upon thermal annealing. Cathodoluminescence (CL) spectra showed that the spectral shift occurred essentially in a shallow layer of the InGaN film. The deeper layer in the as-grown sample contributed blue emission because it had been thermally annealed during the growth of the shallow layer. The spectral change was attributed to the general trends of cluster size reduction and possibly quantum-confined Stark effect relaxation upon thermal annealing. The attribution was supported by the observations in the CL, x-ray diffraction, and high-resolution transmission electron microscopy results.

Improved a-plane GaN quality grown with flow modulation epitaxy and epitaxial lateral overgrowth on r-plane sapphire substrate

The authors demonstrate superior crystal quality of a-plane GaN grown on r-plane sapphire substrate based on the flow modulation epitaxy (FME) technique, in which the Ga atom supply is alternatively switched on and off with continuous nitrogen supply. With the FME technique, a high growth rate of 2.3μm∕h can still be achieved. With or without epitaxial lateral overgrowth (ELOG), either c- or m-mosaic condition is significantly improved in the samples of using FME. With ELOG, the surface roughness can be reduced from 1.58to0.647nm in an area of 10×10μm2 microns by using the FME technique. Based on the results of photoluminescence measurement, one can also conclude the better optical property of the FME-grown a-plane GaN thin films. Besides, it is shown that tensile strain is more relaxed in the FME samples.

Surface plasmon leakage in its coupling with an InGaN∕GaN quantum well through an Ohmic contact

We demonstrate the loss of surface plasmon (SP) energy through oscillating electron leakage via the ohmic contact of either p-type or n-type GaN layer in the coupling process between SP and an InGaN/GaN quantum well (QW). The observation implies that in using the SP-QW coupling for enhancing emission in a light-emitting diode, the metals for ohmic contact and SP generation must be separated. A thin dielectric interlayer is required in the region for SP-QW coupling to avoid the leakage of SP energy.