Vincenzo La Rocca

Thin Film CIGS Solar Cells, Photovoltaic Modules, and the Problems of Modeling

Starting from the results regarding a nonvacuum technique to fabricate CIGS thin films for solar cells by means of single-step electrodeposition, we focus on the methodological problems of modeling at cell structure and photovoltaic module levels. As a matter of fact, electrodeposition is known as a practical alternative to costly vacuum-based technologies for semiconductor processing in the photovoltaic device sector, but it can lead to quite different structural and electrical properties. For this reason, a greater effort is required to ensure that the perspectives of the electrical engineer and the material scientist are given an opportunity for a closer comparison and a common language. Derived parameters from ongoing experiments have been used for simulation with the different approaches, in order to develop a set of tools which can be used to put together modeling both at single cell structure and complete module levels.

Graded Carrier Concentration Absorber Profile for High Efficiency CIGS Solar Cells

We demonstrate an innovative CIGS-based solar cells model with a graded doping concentration absorber profile, capable of achieving high efficiency values. In detail, we start with an in-depth discussion concerning the parametrical study of conventional CIGS solar cells structures. We have used the wxAMPS software in order to numerically simulate cell electrical behaviour. By means of simulations, we have studied the variation of relevant physical and chemical parameters—characteristic of such devices—with changing energy gap and doping density of the absorber layer. Our results show that, in uniform CIGS cell, the efficiency, the open circuit voltage, and short circuit current heavily depend on CIGS band gap. Our numerical analysis highlights that the band gap value of 1.40 eV is optimal, but both the presence of Molybdenum back contact and the high carrier recombination near the junction noticeably reduce the crucial electrical parameters. For the above-mentioned reasons, we have demonstrated that the efficiency obtained by conventional CIGS cells is lower if compared to the values reached by our proposed graded carrier concentration profile structures (up to 21%).

Parametrical study of multilayer structures for CIGS solar cells

In this paper, a numerical analysis of relevant electrical parameters of multilayer structures for CIGS-based solar cells was carried out, employing the simulation software wxAMPS. In particular, we have focused on thin film cells having a ZnO:Al/ZnO/CdS/CIGS structure with a Molybdenum back contact. The aim of this work is to establish good theoretical reference values for an ongoing experimental activity, where our technology of choice is the single-step electrodeposition. In detail, we have analyzed how the main electrical properties change with the bang gap and the thickness of the absorber layer, for such a type of solar cell structure. Our results show that both efficiency and fill factor strongly depend on the energy gap. Instead, the absorber thickness plays a role up to a few microns, after which the cell parameters remain almost constant. As expected, the theoretical peak efficiency was found for a band gap value of 1.40 eV, corresponding to a Ga/(In+Ga) ratio of 0.66.

Environmental Implications of Traffic Flow Delays: a Model for Urban Streets

In this paper the problem of roads capacity is dealt in presence of perturbations of the vehicular flow. In particular, among the different disturbing causes, it is here considered the presence of vehicles parked along the road in relation to their parking activity. Having already established the delay, caused by those vehicles leaving their stationary positions and entering the traffic flow or by those who slow down the flow to park, it is possible to evaluate the changes in time running values. Related to these times delay, the extra pollutant emissions by a given urban running fleet is also evaluated, by utilizing emission factors depending on age, type, volume capacity and engine of the vehicles.

Photovoltaic module characteristics from CIGS solar cell modelling

We describe our approach to the task of modelling, both at single cell structure and complete module levels, during the solar cell technology development process. This can give very helpful indications, in terms of global photovoltaic module characteristics, for the assessment of intermediate research results and planning of further experiments. We make reference specifically to the fabrication of thin film CIGS solar cells by means of single-step electrodeposition, a technique which appears fairly easy and low-cost but, at the same time, can lead to quite different structural and electrical properties.

Advanced Refrigerating Plants Based on Transcritical Cycles Working with Carbon Dioxide for Commercial Refrigeration

Supermarkets and hypermarkets require a huge amount of energy to maintain chilled and frozen food in product display cases and cold storage rooms and thermal comfort in the whole building. Systems exploited require very large refrigerant charges for operation and suffer significant leakages. The challenge for advanced systems, based on equipment which reduce TEWI, suggests the proposal of carbon dioxide: a natural working fluid. This paper deals with a feasibility study of a refrigerating system for a big hypermarket in Sicily based on a three-stage transcritical cycle working with carbon dioxide which is compared with an alternative system composed of two cycles operating as a binary refrigerating plant: a top cycle working with propane and a bottom cycle working with carbon dioxide. The cold is produced at two temperature: - 15°C and -35°C. In both alternative systems, cold at -15°C will be delivered to display cases, cold stores etc. by means of a secondary loop into which circulates a refrigerant fluid (e.g. an ethylene-glycol solution), while cold at -35°C will be delivered by another loop into which circulates directly liquid carbon dioxide. Main results obtained demonstrate the effective feasibility of plants which seem suitable for commercial refrigeration, bearing in mind that is of capital relevance the best operating efficiency of the secondary loop system. This depends mainly on thorough design and building of the secondary loops, especially for those which op erate at lower temperature.

CIGS PV module characteristic curves under chemical composition and thickness variations

This paper analyzes how the electrical characteristics of a CIGS photovoltaic module are affected by the chemical composition and by the thickness variations of the CIGS absorber. The electrical characteristics here considered are the short circuit current, the open circuit voltage, the efficiency and the power peak. The chemical composition is varied by tuning the ratio between gallium and indium. This analysis has been performed by means of the wxAMPS software, developed by the University of Illinois. The above variations have been taken into account on a PV module made of 72 cells. This analysis has been carried out employing a PV module mathematical model developed and implemented by the Authors in Matlab environment.

Characterization of Biodiesel from Vegetable Oil Using Comprehensive Two-Dimensional Gas Chromatography

Biodiesel from vegetable oils has been analyzed and its suitability for internal combustion engines has been assessed. The Standard biofuel’s characteristics have been investigated. Gas chromatography (GC) tests were carried out to characterize the fatty acid behavior. It was found that the mass percentage of saturated fatty acids did not change substantially with time, while unsaturated fatty acids increased with time for both B100 and B30. An increase in density for B100 and B30 with time was noted. Biodiesel density was within the standardization. The calorific values of biodiesel and its blend increased with time. Higher heating value for B100 increased from 41 to 43 MJ/kg while B30 increased from 44 to 45 MJ/kg.

Energy and economic assessment of a small domestic wind turbine in Palermo

The cost effectiveness of micro-wind technology is closely linked to the annual energy production plants, which strongly depends on the wind characteristics and on the morphological properties of the installation site. The power curve of a wind turbine, supplied by manufacturers, characterizes the theoretical energy performance that it should have at a particular site. The behavior of a wind turbine in the field is affected by the speed but also by wind direction variations. At each change of direction and speed, the turbine will try to adapt to new conditions and the phase transition negatively influences the energy production. In order to experimentally confirm what above mentioned, the authors have built up a test facility and started a monitoring campaign in the urban area of Palermo. In particular, a micro wind turbine and a weather station were installed at the solar laboratory of DEIM. Thanks to data monitoring was possible a climate characterization of the site, and the evaluation of the experimental power curve of the turbine. The experimental data were discussed and compared to the manufactured data.

Analysis of Air Cycle and Efficiency Evaluation for a Blast Freezing Tunnel Plant

Air refrigerating systems offer a suitable alternative to vapour compression systems. Air can be used as working fluid in gas compression cycles for refrigeration, air conditioning and heat pump systems. This paper gives some results of theoretical investigation into improved air cycles for refrigeration systems and a comparison is made with their performances. The case-study relates to a dual purpose refrigerating plant. A blast freezing tunnel gives the coldest air stream and, in cascade, the air coming out from the tunnel is used in a channel network for feeding a lot of chilling cells. The case-study analysed indicates that there is a real possibility to build plants which will be equipped with air inverse cycles.