Volkmar Trommsdorff

Antigorite polysomatism : behaviour during progressive metamorphism

Antigorite forms a polysomatic series of discrete compositions that are chemographically colinear with chrysotile/lizardite, Mg3Si2O5(OH)4 and talc, Mg3Si4O10(OH)2. The compositional variations of antigorite correspond to discrete changes in the lattice parameter, a. A complete suite of antigorites, collected from a cross-section representing increasing metamorphic grade through the Swiss and Italian Alps, has been studied by optical and transmission electron microscopy (TEM). The specimens within this suite range from those formed near the lower stability limit of antigorite (250 °C) through to those formed near its breakdown temperature (550 °C). The lower grade samples belong to the regionally metamorphosed upper Pennine Ophiolites of the Oberhalbstein-Malenco area, while higher grade antigorites were obtained from regionally metamorphosed Malenco serpentinites. The highest grade samples are also from Malenco. They underwent a later contact metamorphism within the thermal aureole of the Bregaglia Intrusive. The lattice parameter a of antigorites evolves from longer (60 Å) to shorter (35 Å) values with increasing metamorphic grade. However, individual antigorites almost invariably show a heterogeneous distribution of a periodicities with higher values close to grain boundaries or reaction fronts and lower values towards the grain centers. The crystal-chemical evolution of antigorite, expressed by reduction in a, is usually accompanied by increased crystallinity. With the TEM, this is seen as an increase in crystallite size and a decrease in the number of crystal defects (twinning, polysomatic disorder, modulation dislocations, wobbling, offset). The structural and compositional evolution of antigorite requires intracrystalline diffusion and reconstructive transformations at relatively low temperatures. Therefore, the process of evolution is sluggish. Equilibrium is frequently not attained, and relics of longer a periodicities can be observed. In addition, relics of chrysotile may be observed in high-grade metamorphic rocks of the Malenco area, in which antigorite coexists with new-formed olivine. Only at one locality is there evidence of “equilibrium”: antigorite formed at 435 °C has a=43 Å; it shows very little variation in the a periodicity, and it is characterized by a homogeneous annealing texture. A geothermometer based upon a periodicities, as proposed by Kunze (1961) has limited practical applicability.

Geochemistry of high-grade eclogites and metarodingites from the Central Alps

Analyses for major, minor, and trace element contents of metamorphosed, variably rodingitized mafic rocks demonstrate substantial removal of Na and as much as three-fold gains in Ca as a consequence of rodingitization. Modest declines in Si and Fe can be explained in terms of dilution effects. Losses in K and Ba do not correlate with Ca% and may have been caused by an alteration process not related to the rodingitization. The Ca-metasomatism was not accompanied by a gain in Sr. The relative contents of Ti, Zr, Hf, Y, Co, Sc, and heavy REE show no readily detectable changes, despite the rodingitization (±other alteration) and subsequent metamorphisms, namely, eclogite facies (T≧800° C, P≧ 20kbar) followed by amphibolite facies, sillimanite zone. Protoliths were tholeiitic basalt or diabase, and gabbro, with trace element contents indicative of a spreading center origin. Trace element and REE patterns indicate low-pressure fractionation of this magma, with plagioclase stable. This petrogenesis is consistent with prior conclusions on the shallow crustal origin of the protolith of the eclogite-metarodingite-garnet lherzolite suite in the Cima Lunga-Adula nappe, Central Alps. Based on their bulk chemical composition, the mafic rocks in this suite could be the equivalent of Mesozoic ophiolitic rocks in the more external parts of the Alps.

Vapour loss (" Boiling") as a mechanism for fluid evolution in metamorphic rocks

The calculation of fluid evolution paths during reaction progress is considered for multicomponent systems and the results applied to the ternary system, CO2-H2O-NaCl. Fluid evolution paths are considered for systems in which a CO2-rich phase of lesser density (vapour) is preferentially removed from the system leaving behind a saline aqueous phase (liquid). Such “boiling” leads to enrichment of the residual aqueous phase in dissolved components and, for certain reaction stoichiometries, to eventual saturation of the fluids in salt components. Distinctive textures, particularly radiating growths of prismatic minerals such as tremolite or diopside, are associated with saline fluid inclusions and solid syngenetic salt inclusions at a number of field localities. The most thoroughly studied of these localities is Campolungo, Switzerland, where metasomatic rocks have developed in association with fractures and veins at 500° C and 2,000 bars of pressure. The petrography of these rocks suggests that fluid phase separation into liquid and vapour has been an important process during metasomatism. Fracture systems with fluids at pressure less than lithostatic may facilitate the loss of the less dense vapour phase to conditions of the amphibolite facies.

Terrestrial metamorphic clinoenstatite in kinks of bronzite crystals

Bronzite in a highly deformed and partially metamorphosed gabbro from Central Australia shows intensive bending and kinking. The optical properties of some kinked and deformed areas differ significantly from those of the original bronzite. Single crystal X-ray and optical investigations show that some highly strained areas of bronzite have inverted to clinoenstatite (2V=50±6°; sign +;ZΛc=32±2°). Mixed phases of both also occur. The new clinoenstatite lattice is untwinned.

On phase equilibria in metamorphosed siliceous dolomites

Basing on calculations and experiments the equilibrium curves of 15 reactions occuring during metamorphism of siliceous dolomites are presented. In a T—XCO2 diagram these curves intersect at four isobaric invariant points. This is consistent with the fact, that different reaction sequences are known from the nature.

Halite and sylvite as solid inclusions in high-grade metamorphic rocks

Solid inclusions of halite and sylvite, formed during regional and contact metamorphism have been identified by microscopy and by electron microprobe analysis in rocks from Campolungo, Switzerland and Cornone di Blumone, Italy. The solid inclusions occur in several of the major minerals crystallized during metamorphism and have been observed as idiomorphic crystals and dendrites. The compositions measured in 100 analyses from Campolungo, Switzerland and 40 analyses from Cornone di Blumone, Italy extend across the two-phase region in the system, KCl-NaCl, indicating that the salt inclusions are high temperature precipitates. In both localities compositionally zoned and unzoned crystals have been found. Measured compositions on the temperature maximum of the two-phase region indicate at least 500° C which can be compared with 500°±20° C determined by Mercolli (1982) and Walther (1983) from the Mg content of calcites from Campolungo. The solid inclusions have been trapped apart from CO2-rich and saline, H2O-rich fluid inclusions which have been described by Mercolli (1982) as the earliest preserved fluid inclusions in the rocks. The early precipitation of salt minerals at Campolungo indicates that fluids were saturated with NaCl and KCl at 500° C and pressures of 2,000 bars or higher. Similar relationships exist between solid and fluid inclusions in the rocks of Cornone di Blumone which formed at temperatures as high as 800° C and pressures between 0.5 and 1 kilobar (Ulmer 1983). The entrapment of halite and sylvite as solid inclusions preserves the composition of the minerals which may therefore be useful as geothermometers.

Assemblages among tephroite, pyroxmangite, rhodochrosite, quartz: Experimental data and occurrences in the Rhetic Alps

AbstractReactions involving the phases quartz-rhodochrosite-tephroite-pyroxmangite-fluid have been studied experimentally in the system MnO-SiO2-CO2-H2O at a pressure of 2 000 bars and resulted in the following expressions 1

Olivine [100] normal to foliation: lattice preferred orientation in prograde garnet peridotite formed at high H2O activity, Cima di Gagnone (Central Alps)

\begin{gathered} {\text{Rhodochrosite + Quartz = Pyroxmangite + CO}}_2 \hfill \\ {\text{ log}}_{{\text{10}}} K^{{\text{2000 bars}}} = - \frac{{11.765}}{T} + 18.618. \hfill \\ {\text{Rhodochrosite + Pyroxmangite = Tephroite + CO}}_2 \hfill \\ {\text{ log}}_{{\text{10}}} K^{{\text{2000 bars}}} = - \frac{{7.083}}{T} + 11.870. \hfill \\ \end{gathered}