Wade A. Neiwert
Emory University
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Featured researches published by Wade A. Neiwert.
Dalton Transactions | 2003
Israel Martyr Mbomekalle; Bineta Keita; Louis Nadjo; P. Berthet; Wade A. Neiwert; Craig L. Hill; Michelle D. Ritorto; Travis M. Anderson
A tetranuclear manganous Wells–Dawson sandwich-type polyoxometalate has been synthesized by the reaction of α-Na12(As2W15O56) with an aqueous solution of MnCl2·4H2O. The structure of this complex, αββα-Na16(MnIIOH2)2MnII2(As2W15O56)2·55H2O (Na1), was determined by single-crystal X-ray crystallography (a = 14.5230(12) A, b = 14.7104(13) A, c = 19.8927(17) A, α = 84.326(2)°, β = 81.709(2)°, γ = 65.584(2)°, triclinic, R1 = 6.2%, based on 26721 independent reflections) and is similar to the phosphorus analogue, αββα-Na16(MnIIOH2)2MnII2(P2W15O56)2 (Na2). Magnetization studies confirm that both Na1 and Na2 show antiferromagnetic coupling of the four Mn(II) centers. Despite the structural similarities, electrochemical studies reveal that the presence of arsenic shifts the Mn waves to more positive potentials. Catalytic studies confirm that 1 is a significantly better catalyst than 2 for the H2O2-based epoxidation of cis-cyclooctene, cyclohexene, and 1-hexene.
Journal of the American Chemical Society | 2001
Jeffrey T. Rhule; Wade A. Neiwert; Kenneth I. Hardcastle; Bao T. Do; Craig L. Hill
Science | 2004
Travis M. Anderson; Wade A. Neiwert; Martin L. Kirk; Paula M. B. Piccoli; Arthur J. Schultz; Thomas F. Koetzle; Djamaladdin G. Musaev; Keiji Morokuma; Rui Cao; Craig L. Hill
Inorganic Chemistry | 2004
Michelle D. Ritorto; Travis M. Anderson; Wade A. Neiwert; Craig L. Hill
Inorganic Chemistry | 2003
Xikui Fang; Travis M. Anderson; Wade A. Neiwert; Craig L. Hill
Journal of the American Chemical Society | 2005
Travis M. Anderson; Rui Cao; Elena Slonkina; Britt Hedman; Keith O. Hodgson; Kenneth I. Hardcastle; Wade A. Neiwert; Shaoxiong Wu; Martin L. Kirk; Sushilla Z. Knottenbelt; Ezra C. Depperman; Bineta Keita; Louis Nadjo; Djamaladdin G. Musaev; Keiji Morokuma; Craig L. Hill
Inorganic Chemistry | 2004
Oxana A. Kholdeeva; Tatiana A. Trubitsina; Raisa I. Maksimovskaya; Anatolii V. Golovin; Wade A. Neiwert; Boris A. Kolesov; Xavier López; Josep M. Poblet
Journal of Organic Chemistry | 2002
Frank E. McDonald; Fernando Bravo; Xia Wang; Xudong Wei; Motoki Toganoh; J. Ramon Rodriguez; Bao Do; Wade A. Neiwert; Kenneth I. Hardcastle
Inorganic Chemistry | 2005
Oxana A. Kholdeeva; Maria N. Timofeeva; Gennadii M. Maksimov; Raisa I. Maksimovskaya; Wade A. Neiwert; Craig L. Hill
Inorganic Chemistry | 2012
Kevin P. O’Halloran; Chongchao Zhao; Nicole S. Ando; Arthur J. Schultz; Thomas F. Koetzle; Paula M. B. Piccoli; Britt Hedman; Keith O. Hodgson; Elena Bobyr; Martin L. Kirk; Sushilla Z. Knottenbelt; Ezra C. Depperman; Benjamin W. Stein; Travis M. Anderson; Rui Cao; Yurii V. Geletii; Kenneth I. Hardcastle; Djamaladdin G. Musaev; Wade A. Neiwert; Xikui Fang; Keiji Morokuma; Shaoxiong Wu; Paul Kögerler; Craig L. Hill
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