Wanting Zhu

Multi-localization transport behaviour in bulk thermoelectric materials

Simultaneously optimizing electrical and thermal transport properties of bulk thermoelectric materials remains a key challenge due to the conflicting combination of material traits. Here, we have explored the electrical and thermal transport features of In-filled CoSb3 through X-ray absorption fine structure, X-ray photoemission spectra, transport measurement and theoretical calculation. The results provide evidence of three types of coexisting multi-localization transport behaviours in the material; these are heat-carrying phonon-localized resonant scattering, accelerated electron movement and increase in density of states near the Fermi level. The 5p-orbital hybridization between In and Sb is discovered in the In-filled CoSb3 compound, which results in a charge transfer from Sb to In and the enhancement of p–d orbital hybridization between Co and Sb. Our work demonstrates that the electrical and thermal properties of filled skutterudite bulk thermoelectric materials can be simultaneously optimized through the three types of coexisting multi-localization transport behaviours in an independent way.

Superparamagnetic enhancement of thermoelectric performance

The ability to control chemical and physical structuring at the nanometre scale is important for developing high-performance thermoelectric materials. Progress in this area has been achieved mainly by enhancing phonon scattering and consequently decreasing the thermal conductivity of the lattice through the design of either interface structures at nanometre or mesoscopic length scales or multiscale hierarchical architectures. A nanostructuring approach that enables electron transport as well as phonon transport to be manipulated could potentially lead to further enhancements in thermoelectric performance. Here we show that by embedding nanoparticles of a soft magnetic material in a thermoelectric matrix we achieve dual control of phonon- and electron-transport properties. The properties of the nanoparticles—in particular, their superparamagnetic behaviour (in which the nanoparticles can be magnetized similarly to a paramagnet under an external magnetic field)—lead to three kinds of thermoelectromagnetic effect: charge transfer from the magnetic inclusions to the matrix; multiple scattering of electrons by superparamagnetic fluctuations; and enhanced phonon scattering as a result of both the magnetic fluctuations and the nanostructures themselves. We show that together these effects can effectively manipulate electron and phonon transport at nanometre and mesoscopic length scales and thereby improve the thermoelectric performance of the resulting nanocomposites.

Enhanced thermoelectric performance of (Ba,In) double-filled skutterudites via randomly arranged micropores

Porous (Ba,In) double-filled skutterudite materials with pore diameter about 1–4 μm were prepared by the decomposition of metastable ZnSb inclusions induced by the Zn sublimation. Transport measurements revealed that the Seebeck coefficient was increased due to the electron filtering effect induced by nanostructures in the surfaces of pores, the electrical conductivity was almost unchanged because of the percolation effect of conducted network composed of filled skutterudites, and the lattice thermal conductivity was dramatically suppressed due to the enhanced pore-edge boundary scattering of long-wavelength phonons. As a result, a maximum ZT of 1.36 was obtained, increased by 22.5% as compared to that of the bulk material with same chemical composition. This work demonstrates that by introducing porous structures is thought to be an efficient approach to improve the thermoelectric performance of bulk materials.

Nonlinear response behavior of Fe/Bi2Te2.7Se0.3 artificially tilted multilayer thermoelectric devices to thermal contact

The response behavior of artificially tilted multilayer thermoelectric devices (ATMTDs) to thermal radiation has been intensely investigated for remote thermal detection; however, their response behavior to thermal contact is still not well understood. In this letter, Fe/Bi2Te2.7Se0.3 ATMTDs have been fabricated by alternately stacking metallic Fe layers and Bi2Te2.7Se0.3 layers to reveal the response behavior to thermal contact. It was found that the transverse thermoelectric voltages (ΔVx) of the ATMTDs once contacting heat source were rapidly raised in the first seconds and then nonlinearly attenuated after reaching maximum ΔVx. A one-dimensional unsteady heat transfer model was proposed to reveal the attenuation process, which obeys an exponential variation and strongly depends on the heat source temperature. Using the ATMTDs as temperature sensors, the detection uncertainty can be less than 1 K. This work has demonstrated great potential application of the ATMTDs in the field of contact-type temperature detection.The response behavior of artificially tilted multilayer thermoelectric devices (ATMTDs) to thermal radiation has been intensely investigated for remote thermal detection; however, their response behavior to thermal contact is still not well understood. In this letter, Fe/Bi2Te2.7Se0.3 ATMTDs have been fabricated by alternately stacking metallic Fe layers and Bi2Te2.7Se0.3 layers to reveal the response behavior to thermal contact. It was found that the transverse thermoelectric voltages (ΔVx) of the ATMTDs once contacting heat source were rapidly raised in the first seconds and then nonlinearly attenuated after reaching maximum ΔVx. A one-dimensional unsteady heat transfer model was proposed to reveal the attenuation process, which obeys an exponential variation and strongly depends on the heat source temperature. Using the ATMTDs as temperature sensors, the detection uncertainty can be less than 1 K. This work has demonstrated great potential application of the ATMTDs in the field of contact-type temperat...

Simultaneously improved electrical properties of crystalline YbAl3 thin films prepared by co-sputtering technique

With the growing interest in developing miniaturized thermoelectric devices, there has been a strong demand in preparing thermoelectric thin films with high electrical conductivity and large power factors, hence ensuring the miniaturized devices have large cooling capacity and large output powers. This work demonstrated the preparation of intermetallic YbAl3 thin films through a double-target magnetron co-sputtering technique and a subsequent annealing treatment. It was revealed that the subsequent heat treatment of thin films plays a critical role in achieving crystalline, stoichiometric, and nanostructured YbAl3 thin films. Benefiting from the significantly improved crystallinity and stoichiometry, the optimized YbAl3 thin films exhibit extraordinarily high electrical conductivity reaching 1.7 × 106 S m−1 and large power factors around 7.4 mW m−1 K−2. The figure of merit ZT of the annealed thin films is comparable with that of the bulk materials, showing their potential use in miniaturized thermoelectric devices.

Corrigendum: Superparamagnetic enhancement of thermoelectric performance

This corrects the article DOI: 10.1038/nature23667