Wei Tu

Effect of mixed fillers on positive temperature coefficient of conductive polymer composites

Abstract This paper investigates the trade-off between low percolation threshold and large positive temperature coefficient (PTC) intensity in conductive polymer composites (CPCs). Conductive particles with low aspect ratios and large dimensions have been demonstrated to induce large PTC intensity in CPCs. Conversely high aspect ratio conductive (nano)particles like carbon nanotubes (CNTs) are desirable because of their extremely low percolation threshold (typically well below 1 wt.%), providing benefits in terms of reduced density, brittleness, costs and improved processability. Herein we report on combinations of different conductive fillers to explore the possibility to obtain both low percolation threshold and high PTC intensity. For the first time we use model systems in which at least one of the two conductive fillers is of relatively homogenous size and shape to facilitate unraveling some of the complicated inter-relationships between (mixed) conductive fillers and the PTC effect. Graphical abstract

Toughening mechanisms in cellulose nanopaper: the contribution of amorphous regions

Cellulose nanopaper is a strong and tough fibrous network composed of hydrogen bonded cellulose nanofibres. Upon loading, cellulose nanopaper exhibits a long inelastic portion of the stress–strain curve which imparts high toughness into the material. Toughening mechanisms in cellulose nanopaper have been studied in the past but mechanisms proposed were often rather speculative. In this paper, we aim to study potential toughening mechanisms in a systematic manner at multiple hierarchical levels in cellulose nanopaper. It was proposed that the toughness of cellulose nanopaper is not, as is often assumed, entirely caused by large scale inter-fibre slippage and reorientation of cellulose nanofibres. Here it is suggested that dominant toughening mechanism in cellulose nanopaper is associated with segmental motion of molecules facilitated by the breakage of hydrogen bonds within amorphous regions .