Wenyao Wang

Effect of local structures and atomic packing on glass forming ability in CuxZr100−x metallic glasses

Molecular dynamics simulations are performed for CuZr metallic alloys to study the structural and dynamical features for glass forming ability (GFA). Our analysis shows that in CuZr metallic system, although ⟨0,0,12,0⟩ icosahedral clusters are important, some Zr-centered clusters such as ⟨0,1,10,4⟩ and ⟨0,1,10,5⟩ play a key role in slowing down the dynamics. It is found that these Zr-centered clusters are intrinsically slow and fundamentally determine the stability and slow dynamics. Due to the strong spatial correlation between ⟨0,0,12,0⟩ and Zr-centered clusters, their relative population influences the dense packing and dynamics in metallic glasses, and further the GFA.

Coexistence of reentrant-spin-glass and ferromagnetic martensitic phases in the Mn2Ni1.6Sn0.4 Heusler alloy

A giant exchange bias field of up to 1170 Oe was observed in the Mn2Ni1.6Sn0.4 Heusler alloy. A reentrant spin glass phase and a ferromagnetic martensitic phase coexist below the blocking temperature as confirmed by dc magnetization and ac susceptibility measurements. Exchange bias in Mn2Ni1.6Sn0.4 is thought to originate from the interface exchange interaction between the reentrant spin glass phase and the ferromagnetic martensitic phase. X-ray diffraction and selected area electron diffraction results demonstrate that excess Mn atoms occupy Ni and Sn sites randomly. In this way, Mn-Mn clusters are formed and constitute the reentrant-spin-glass phase.

Understanding glass-forming ability through sluggish crystallization of atomically thin metallic glassy films

The glass-forming ability (GFA) of an alloy, closely related to its ability to resist crystallization, is a crucial issue in condensed matter physics. So far, the studies on GFA are mostly statistical and empirical guides. Benefiting from the ultrahigh thermal stability of ultrathin metallic glassy film and high resolution spherical aberration-corrected transmission electron microscope, the crystallization of atomically thin ZrCu and its microalloyed ZrCuAl glasses with markedly different GFA was investigated at the atomic scale. We find the Zr diffusivity estimated from the density of nuclei is dramatically decreased by adding of Al, which is the major reason for the much better GFA of the ZrCuAl metallic glass.

Ultrahigh stability of atomically thin metallic glasses

We report the fabrication and study of thermal stability of atomically thin ZrCu-based metallic glass films. The ultrathin films exhibit striking dynamic properties, ultrahigh thermal stability, and unique crystallization behavior with discrete crystalline nanoparticles sizes. The mechanisms for the remarkable high stability and crystallization behaviors are attributed to the dewetting process of the ultrathin film. We demonstrated a promising avenue for understanding some fundamental issues such as glassy structure, crystallization, deformation, and glass formation through atomic resolution imaging of the two dimensional like metallic glasses.

Role of low melting point element Ga in pronounced β-relaxation behaviors in LaGa-based metallic glasses

In contrast to most metallic glasses (MGs) which exhibit weak β-relaxation peak in their dynamic mechanical spectra, the LaGa-based MGs we report here show a distinct β-relaxation peak with the ratio of β/α-relaxation peaks up to ∼0.32 in the mechanical relaxation measurements. Moreover, the β-relaxation behavior can be tuned by modification of the chemical composition and the concentration of flow units. The effects of gallium and structural origin of the β-relaxation in the MGs have been discussed. The LaGa-based MGs with pronounced slow β-relaxation could provide a model system to investigate some underlying issues of the relaxation and plastic mechanism of MGs.

Microscopic insight into the origin of enhanced glass-forming ability of metallic melts on micro-alloying

Extensive efforts have been made to develop metallic-glasses with large casting diameter. Such efforts were hindered by the poor understanding of glass formation mechanisms and the origin of the glass-forming ability (GFA) in metallic glass-forming systems. In this work, we have investigated relaxation dynamics of a model bulk glass-forming alloy system that shows the enhanced at first and then diminished GFA on increasing the percentage of micro-alloying. The micro-alloying did not have any significant impact on the thermodynamic properties. The GFA increasing on micro-alloying in this system cannot be explained by the present theoretical knowledge. Our results indicate that atomic caging is the primary factor that influences the GFA. The composition dependence of the atomic caging time or residence time is found to be well correlated with GFA of the system.

Improvement of the large aperture Ti:sapphire amplifiers in the petawatt femtosecond laser system at SIOM

We report the recent improvement on the petawatt (PW) femtosecond Ti:sapphire chirped pulse amplification (CPA) laser system at Shanghai Institute of Optics and Fine Mechanics (SIOM), Chinese Academy of Sciences. By enlarging the sizes of the pump and signal beams in the large aperture Ti:sapphire amplifiers and optimizing the whole laser system, the output laser energy before the pulse compressor is upgraded to 42.6 J. Accordingly, the peak power of the laser system exceeds 1 PW. The shot-to-shot instability of the output laser energy at about 40 J is less than ?%.

The equipment for the preparation of micro and nanoscale metallic glassy fibers

A supercooled liquid extraction method and apparatus for micro and nanoscale metallic glassy fiber preparation was developed. Using the fiber fabrication equipment, micro to nanoscale metallic glassy fibers with diameter ranging from 70 nm to 300 μm can be obtained by wire drawing in the supercooled liquid region of metallic glasses via superplastic deformation. The obtained metallic glassy fibers possess precisely designed and controlled sizes, high structural uniformity and high degree of surface smoothness.

Compact 120 TW Ti:sapphire laser with a high gain final amplifier

A compact 120 TW/36 fs Ti:sapphire chirped pulse amplification laser was established. Using the pumping pulse with accurate synchronization in final amplifier, 5.98 J/220 ps output was achieved for /spl sim/300 mJ incident pulse, the single amplifier gain reaches /spl sim/20.

Broadband spectral shaping in a Ti:sapphire regenerative amplifier

A 0.34-mm thick quartz plate is used in a Ti:sapphire regenerative amplifier for spectral shaping, the bandwidth of the amplified pulse is increased from /spl sim/18 nm to /spl sim/35 nm, and the amplified pulse is compressed to /spl sim/35 fs.