William D. Smythe

Hydrated salt minerals on Europa's Surface from the Galileo near-infrared mapping spectrometer (NIMS) investigation

We reported evidence of heavily hydrated salt minerals present over large areas of Europas surface from analysis of reflectance spectra returned by the Galileo mission near infrared mapping spectrometer (NIMS) [McCord et al., 1997a, b, 1998a, b]. Here we elaborate on this earlier evidence, present spatial distributions of these minerals, examine alternate water-ice interpretations, expand on our hydrated-salts interpretation, consider salt mineral stability on Europa, and discuss the implications. Extensive well-defined areas on Europa show distinct, asymmetric water-related absorption bands in the 1 to 2.5-μm region. Radiative transfer modeling of water ice involving different particle sizes and layers at Europa temperatures does not reproduce the distinctive Europa water bands. However, ice near its melting temperature, such as in terrestrial environments, does have some characteristics of the Europa spectrum. Alternatively, some classes of heavily hydrated minerals do exhibit such water bands. Among plausible materials, heavily hydrated salt minerals, such as magnesium and sodium sulfates, sodium carbonate and their mixtures, are preferred. All Europa spectral features are present in some salt minerals and a very good match to the Europa spectrum can be achieved by mixing several salt spectra. However, no single or mix of salt mineral spectra from the limited library available has so far been found to perfectly match the Europa spectrum in every detail. The material is concentrated at the lineaments and in chaotic terrain, which are technically disrupted areas on the trailing side. Since the spectrum of the material on Europa is nearly the same everywhere so-far studied, the salt or salt-mixture composition may be nearly uniform. This suggests similar sources and processes over at least a near-hemispheric scale. This would suggest that an extensive subsurface ocean containing dissolved salts is the source, and several possible mechanisms for deposit emplacement are considered. The hydrogen bonds associated with hydration of these salts are similar or greater in strength and energy to those in pure water ice. Thus, once on the surface, the salt minerals should be as stable to disruption as water ice at the Europa temperatures, and mechanisms are suggested to enhance the stability of both materials. Spectra obtained of MgSO4·6H2O at 77 K show only small differences from room temperature spectra. The main difference is the appearance of the individual absorptions composing the broad, composite water features and associated with the several different H2O sites in the salt hydrate molecule. This suggests that the Europa absorption bands are also composites. Thus higher spectral resolution may reveal these diagnostic features in Europas spectrum. The specific salts present and their relative abundances would be indicators of the chemistry and conditions of an ocean environment, and areas of fresh, heavy concentration of these minerals should make ideal lander mission sampling sites.

Non‐water‐ice constituents in the surface material of the icy Galilean satellites from the Galileo near‐infrared mapping spectrometer investigation

We present evidence for several non-ice constituents in the surface material of the icy Galilean satellites, using the reflectance spectra returned by the Galileo near infrared mapping spectrometer (NIMS) experiment. Five new absorption features are described at 3.4, 3.88, 4.05, 4.25, and 4.57 μm for Callisto and Ganymede, and some seem to exist for Europa as well. The four absorption bands strong enough to be mapped on Callisto and Ganymede are each spatially distributed in different ways, indicating different materials are responsible for each absorption. The spatial distributions are correlated at the local level in complex ways with surface features and in some cases show global patterns. Suggested candidate spectrally active groups, perhaps within larger molecules, producing the five absorptions include C-H, S-H, SO2, CO2, and C≡N. Organic material like tholins are candidates for the 4.57- and 3.4-μm features. We suggest, based on spectroscopic evidence, that CO2 is present as a form which does not allow rotational modes and that SO2 is present neither as a frost nor a free gas. The CO2, SO2, and perhaps cyanogen (4.57 μm) may be present as very small collections of molecules within the crystal structure, perhaps following models for radiation damage and/or for comet and interstellar grain formation at low temperatures. Some of the dark material on these surfaces may be created by radiation damage of the CO2 and other carbon-bearing species and the formation of graphite. These spectra suggest a complex chemistry within the surface materials and an important role for non-ice materials in the evolution of the satellite surfaces.

Near-Infrared Spectroscopy and Spectral Mapping of Jupiter and the Galilean Satellites: Results from Galileo's Initial Orbit

The Near Infrared Mapping Spectrometer performed spectral studies of Jupiter and the Galilean satellites during the June 1996 perijove pass of the Galileo spacecraft. Spectra for a 5-micrometer hot spot on Jupiter are consistent with the absence of a significant water cloud above 8 bars and with a depletion of water compared to that predicted for solar composition, corroborating results from the Galileo probe. Great Red Spot (GRS) spectral images show that parts of this feature extend upward to 240 millibars, although considerable altitude-dependent structure is found within it. A ring of dense clouds surrounds the GRS and is lower than it by 3 to 7 kilometers. Spectra of Callisto and Ganymede reveal a feature at 4.25 micrometers, attributed to the presence of hydrated minerals or possibly carbon dioxide on their surfaces. Spectra of Europas high latitudes imply that fine-grained water frost overlies larger grains. Several active volcanic regions were found on Io, with temperatures of 420 to 620 kelvin and projected areas of 5 to 70 square kilometers.

The opposition effect of the moon - The contribution of coherent backscatter

The opposition effect, the sharp surge in brightness of an astronomical object observed near zero phase angle, which has been known for more than a century, has generally been explained by shadow hiding. The reflectances of several Apollo lunar soil samples have been measured as a function of phase angle in linearly and circularly polarized light. All samples exhibited a decrease in the linear polarization ratio and an increase in the circular polarization ratio in the opposition peak. This provides unequivocal proof that most of the lunar opposition effect is caused by coherent backscatter, not shadow hiding. This result has major implications for the interpretation of photometric observations of bodies in the solar system, including the Earth.

Galileo infrared imaging spectroscopy measurements at Venus

During the 1990 Galileo Venus flyby, the Near Infaied Mapping Spectrometer investigated the night-side atmosphere of Venus in the spectral range 0.7 to 5.2 micrometers. Multispectral images at high spatial resolution indicate substanmial cloud opacity variations in the lower cloud levels, centered at 50 kilometers altitude. Zonal and meridional winds were derived for this level and are consistent with motion of the upper branch of a Hadley cell. Northern and southern hemisphere clouds appear to be markedly different. Spectral profiles were used to derive lower atmosphere abundances of water vapor and other species.

Thermal signature, eruption style, and eruption evolution at Pele and Pillan on Io

The Galileo spacecraft has been periodically monitoring volcanic activity on Io since June 1996, making it possible to chart the evolution of individual eruptions. We present results of coanalysis of Near-Infrared Mapping Spectrometer (NIMS) and solid-state imaging (SSI) data of eruptions at Pele and Pillan, especially from a particularly illuminating data set consisting of mutually constraining, near-simultaneous NIMS and SSI observations obtained during orbit C9 in June 1997. The observed thermal signature from each hot spot, and the way in which the thermal signature changes with time, tightly constrains the possible styles of eruption. Pele and Pillan have very different eruption styles. From September 1996 through May 1999, Pele demonstrates an almost constant total thermal output, with thermal emission spectra indicative of a long-lived, active lava lake. The NIMS Pillan data exhibit the thermal signature of a “Pillanian” eruption style, a large, vigorous eruption with associated open channel, or sheet flows, producing an extensive flow field by orbit C10 in September 1997. The high mass eruption rate, high liquidus temperature (at least 1870 K) eruption at Pillan is the best candidate so far for an active ultramafic (magnesium-rich, “komatiitic”) flow on Io, a style of eruption never before witnessed. The thermal output per unit area from Pillan is, however, consistent with the emplacement of large, open-channel flows. Magma temperature at Pele is ≥1600 K. If the magma temperature is 1600 K, it suggests a komatiitic-basalt composition. The power output from Pele is indicative of a magma volumetric eruption rate of ∼250 to 340 m3 s−1. Although the Pele lava lake is considerably larger than its terrestrial counterparts, the power and mass fluxes per unit area are similar to active terrestrial lava lakes.

The Cause of the Hot Spot in Vegetation Canopies and Soils: Shadow-Hiding Versus Coherent Backscatter

Two different mechanisms, shadow-hiding and coherent backscatter, can cause a hot spot, or opposition effect, in the bidirectional reflectance of vegetation and soils. Because the two mechanisms sample different properties, it is important to know which one is primarily responsible in a given medium. This question can be answered by measuring the bidirectional reflectance in circularly polarized light. If the results of the limited experiments reported here can be extrapolated to a wider range of materials, it appears that the primary cause of the hot spot in most vegetation canopies and in moist, clumpy soils is shadow-hiding. However, in vegetation with large numbers of wavelength-sized structures, such as mosses, and in dry, fine-grained soils, the hot spot is dominated by coherent backscatter.

The distribution of sulfur dioxide and other infrared absorbers on the surface of Io

The Galileo Near Infrared Mapping Spectrometer was used to investigate the distribution and properties of sulfur dioxide over the surface of Io, and qualitative results for the anti-Jove hemisphere are presented here. SO2, existing as a frost, is found almost everywhere, but with spatially variable concentration. The exceptions are volcanic hot spots, where high surface temperatures promote rapid vaporization and can produce SO2-free areas. The pervasive frost, if fully covering the cold surface, has characteristic grain sizes of 30 to 100 µm, or greater. Regions of greater sulfur dioxide concentrations are found. The equatorial Colchis Regio area exhibits extensive snowfields with large particles (250 to 500 µm diameter, or greater) beneath smaller particles. A weak feature at 3.15 µm is observed and is perhaps due to hydroxides, hydrates, or water. A broad absorption in the 1 µm region, which could be caused by iron-containing minerals, shows a concentration in Ios southern polar region, with an absence in the Pele plume deposition ring.

Hot spots on Io: Initial results from Galileo's near infrared mapping spectrometer

The Near-Infrared Mapping Spectrometer on Galileo has monitored the volcanic activity on Io since June 28, 1996. This paper presents preliminary analysis of NIMS thermal data for the first four orbits of the Galileo mission. NIMS has detected 18 new hot spots and 12 others which were previously known to be active. The distribution of the hot spots on Ios surface may not be random, as hot spots surround the two bright, SO2-rich regions of Bosphorus Regio and Colchis Regio. Most hot spots seem to be persistently active from orbit to orbit and 10 of those detected were active in 1979 during the Voyager encounters. We report the distribution of hot spot temperatures and find that they are consistent with silicate volcanism.

Temperature and area constraints of the South Volund Volcano on Io from the NIMS and SSI instruments during the Galileo G1 orbit

Analysis of data from darkside and eclipse observations of Io by the NIMS and SSI instruments show that the South Volund hot spot is a manifestation of high temperature active silicate volcanism. The NIMS data are fitted with a two temperature model (developed from modelling terrestrial lavas) which yields a better fit to the data than a single temperature fit. The multispectral color temperatures obtained from NIMS are compared with the brightness temperatures obtained from the SSI instrument, and show excellent agreement for the hotter of the two components fitted to the NIMS data. The two components might correspond to a cooled crust which has formed on the surface of an active flow or lava lake, at a temperature of approximately 450 K, and covering an area of about 50 km², and a hotter and much smaller component, at a temperature of approximately 1100 K and an area of less than 0.1 km². The hot component implies the existence of cracks in the surface crust of a flow or lake through which the hot interior radiates, a hot vent area, or breakouts of lava forming new flow lobes. The ratio of these areas is consistent with the crack-to-crust ratio of some lava flows and lava lakes on Earth.