Xiao Chun He

Nanocomposites of Carbon Nanotube/Polyaniline with Pending Calix[8]Arene and their External Stimuli Response Properties

To functionalize the smart nanocomposites, the nanocomposites of CNTs/polyaniline with pending calix [8] arene were prepared. A series of characterizations were performed by SEM (scanning electron microscopy), the Fourier-Transform Infrared (FTIR) spectra, The UV-Vis (Ultra-violet visible spectroscopy), et al. The photoconductivity response to visible light and 808 nm laser with low-power were studied based on interdigital electrodes of Au on flexible PET (polyethylene terephthalate) film substrate with casting method. The results showed that the nanocomposites of CNTs/polyaniline with pending calix [8] arene exhibited good photoresponse to visible light and weak 808 nm laser, but its recoverability was very slow, it needed several hours, and the film-forming property of nanocomposite was not very good. This may be attributed to the results of increased hydrophobicity of nanocomposite because of introducing the calix [8] arene ring. In order to increase the film-forming technology of nanocomposites, the grapheme oxide were obtained with unzipping method of carbon nanotube (CNTs) for enhancing the hydrophilcity of carbon nanomaterials. The nanocomposites of grapheme oxide/polyaniline with pending calix [8] arene were obtained with similar methods, which showed improved film-forming property. The photoresponses to weak visible light and 808 nm laser also showed the similar results. It may develop the nanocomposite with external stimuli response, and have good potential applications in sensors, organic photocatalyst, et al.

Photo-Induced Charge Generation of TiO 2 Nanotube Modified with Polymer Containing C 60 under Irradiation of Visible Light and its Applications

Due to its excellent physical properties and inert chemical reaction activity of C60, it is possible to synthesize solution-processing polymer containing C60 utilizing the inclusive characteristics of polymer chain segment, and then to prepare organic/inorganic nanocomposites with enhanced some key properties. In order to harvest the visible light of TiO2 effectively the surface modification of TiO2 nanotube with polymer containing C60 was carried out in this study. A series of characterizations were performed by SEM (scanning electron microscopy), TEM (transmission electron microscopy), Fourier-Transform Infrared (FTIR) spectra, UV-Vis (Ultra-violet visible spectroscopy), XRD patterns analysis. The results showed that the UV-Vis of resulting nanocomposite was almost covered the whole region of visible light. The photoconductivity response to visible light with low-power were studied based on interdigital electrodes of Au on flexible PET (polyethylene terephthalate) film substrate with casting method. The results indicated that the photoresponses of two kinds of polymer containing C60 to weak visible light emerged photo-switching behavior, its recoverability was also rapidly, and the photoresponse of TiO2 nanotube modified with two kinds of polymer containing C60 to weak visible light also changed greatly. This illustrated that the organic-inorganic nanocomposites showed good activities to weak visible light. Photocatalytic efficiency was examined by selecting typical organic pollutants, some good results were obtained. It may develop organic-inorganic nanocomposites with external stimuli response, photocatalyst, et al.

Surface Modification of Graphene Oxide with Pyrene Derivatives and their Photo-Switching Behaviors

The characteristics of surface and interface of nanocomposites are favor for exerting some functional properties and widening new applications. Some low-dimensional materials generally have abundant chemical groups and reaction activities. These surface chemical groups of nanomaterials provide a large platform to develop new nanocomposites and applications by surface chemical reaction and surface reconstruction of another kind of materials. Among so many hot-fields materials, graphene and its nanocomposite are developed rapidly. The graphene oxide not only has good charge transferring property, but also has abundant chemical groups on its surface, such as, -COOH, -OH and epoxide group. Therefore, graphene oxide is a good candidate substrate for further constructing other functional materials in nanoscale. The graphene oxide and pyrene derivatives were selected as representative materials for studies. Assembly of pyrene containing –NH2 groups on the surface of graphene oxide was carried out. A series of characterizations were performed by SEM (scanning electron microscopy), TEM (transmission electron microscopy), the FTIR (Fourier-Transform Infrared ) spectra, The UV-Vis (Ultra-violet visible spectroscopy), photoluminescence spectra, et al. The results indicated that the UV-Vis of nanocomposite was almost covered the whole region of visible light, and the results of PL showed strong fluorescence quenching. There was strong interaction between the graphene oxide and pyrene. The photoconductivity response to weak visible light and 808 nm laser were studied based on interdigital electrodes of Au on flexible PET(polyethylene terephthalate) film substrate with casting method. The results showed that graphene oxide modified with pyrene derivatives exhibited that the photocurrent increased obviously to visible light, and photoresponse to weak 808 nm laser emerged photo-switching behavior. It would be developed the light detector to NIR, biomimetic fields or external stimuli driven nanocarriers for biomedical fields, et al.

NIR (Near-Infrared) Driven Carbon Nanotube Modified with Dendrimers

Dendrimers and carbon nanotube took an important role in transport and delivery of drugs, gene, et al, however, to improve its functional properties is still a great challenge. Carbon nanotube not only has good biocompatibility but also hold optical adsorption in NIR. In biomimetic and biomedical fields, nanorobots or nanocarriers with external stimuli response for removal the organic pollutants and toxins or drugs in the living body are attractive for research and applications. In this paper, the self-assembly with CNTs containing –COOH and dendrimers having –NH2 groups was carried out. A series of characterizations were performed by SEM (scanning electron microscopy), TEM (transmission electron microscopy), XRD (X-ray diffraction), and Fourier-Transform Infrared (FTIR) spectra. The adsorption properties and releasing characteristics of CNTs modified with dendrimers were performed with simulating drugs. Some meaningful results were obtained. The photoconductivity response to visible light and 808 nm laser with low-power were studied based on interdigital electrodes of Au on flexible PET(polyethylene terephthalate) film substrate. The results indicated that CNTs modified with dendrimers showed good photo-response to visible light and 808 nm laser. It would be developing smart nanorobots with external stimuli response for removal the organic pollutants and toxins or drugs in the living body.

Functionalization of Smart Gels with Beta-Cyclodextrin and Release Characteristics to Simulating Drugs

Smart gels have many applications in sensors, actuators, shape memory intelligent devices, recognition, self-healing, drug release, biomimetic soft robot design, biomimetic tactile, neural regeneration, biomimetic membranes, supercapacitor, dye-sensitized solar cells, advanced lithium polymer batteries, environmental fields, biomedical fields, et al. And that cyclodextrins are one of the typical macrocycles with good recognition ability, and endowed with fascinating hydrophobic cavities and hydrophilic surface, which enable the encapsulation of diverse small organic molecules by forming inclusion complexes. In this paper, grafted copolymerization between acrylic acid and N,N-dimethyl acrylamide in the presence of water-soluble cyclodextrins was carried out. The effect of ratio of copolymerization monomer on the grafted polymer was examined. The results indicated that self-crosslinking smart gel with multi-stimuli responsive was obtained by selecting suitable the ratio of copolymerization monomer, its behaviors of swelling/shrinking were examined. The adsorption properties and releasing characteristics of smart gel were performed with simulating drugs. Some meaningful results were obtained. These series grafted copolymer would also be used to modify the surface and interface properties of low-dimensional functional materials or heterostructured nanocomposites for intelligent organic-inorganic functional nanocomposites, some good results were obtained.

Controlled Morphology of One-Dimensional Manganese Dioxide with Dramatic Enhancing Removal Efficiency to Heavy Metal Ions in Aqueous Solution

To examine the effects of morphologies of one-dimentional metal oxides on their surface properties, two typical morphologies of manganese dioxide (one is nanorod, the other is nanofiber) as a model of metal oxide were prepared with hydrothermal approach under similar conditions. The adsorption properties of Pb2+ in aqueous solution were carried out by using surface active group of MnO2 with different morphologies. The results indicated that the sorption capacities for Pb2+ were dramaticly increased via tailoring the morphology of MnO2. The products were characterized with SEM (Scanning Electron Microscopy), XRD (X-ray Diffraction), FTIR (Fourier-Transform Infrared), atomic absorption spectrophotometer, and so on. These results illustrated that it was feasible to improve the removal efficiency of heavy metal ions dramatically in aqueous solution by tailoring the morphology of nanostructured MnO2.

Organic Functionalization and Properties of ZnO Nanosheets with Polymer Containing N-Vinyl Carbazole

To make full use of the visible light more effectively, many studies are focuses on ZnO baesd nanocomposites. To modify the surface of ZnO with functional polymer is a very simple and effective approach. PVK (N-vinyl carbazole polymer) is one of typical organic functional materials, which is generally used as charge transfer materials for the applications of several organic electronic devices. Surface modification of ZnO nanosheets with polymer containing –COOH and N-vinyl carbazole group was performed with self-assembly process for improving the adsorption to visible light and properties of charge transfer in nanoscale. A series of characterizations were carried out by SEM (scanning electron microscopy), Fourier-Transform Infrared (FTIR) spectra, UV-Vis (Ultra-violet visible spectroscopy), et al. The adsorption of the nanocomposite was extended to the region of visible light. The photoconductivity response to weak visible light was studied based on interdigital electrodes of Au on flexible PET (polyethylene terephthalate) film substrate with casting method. The photocurrent of ZnO nanosheets modified with the polymer containing N-vinyl carbazole to weak visible light was changed greatly. The organic-inorganic nanocomposite showed good activities to visible light, with which it can be easily produced photo-induced charges, avoiding the recombination of charges produced by visible light. Photocatalytic efficiency was examined by selecting typical organic pollutants and some good results were obtained, showing much prospect in the fields of photocatalysts, nanoreactors, self-cleaning films, coatings, and organic pollutants treatment of environmental.

Two-Dimensional Composite Biomimetic Films with Wide Optical Spectrum Response and their Properties

Since graphene was discovered, the biomimetic materials with laminated structure (such as, shellfish) had become one of the research-hot fields. Chitosan comes from shellfish, and was considered as a very promising abundant natural biopolymer. It holds not only outstanding mechanical properties, film-forming technology and low cost, but also has good applications in environmental fields due to its excellent adsorption properties to a broad range of organic pollutants and some heavy metal ions. Preparation of biomimetic materials with laminated structure utilizing chitosan have many advantages, however, to improve functional properties of chitosan based biomimetic materials is still a great challenge. Graphene has various applications, including storage energy devices, hydrogen production with photo-catalysts, and environmental fields because of its high charge mobility and good mechanical properties. However, graphene and its oxide have difficult re-dispersion properties in fabrication of nanocomposite. In this paper, the nanosheets stacking of metal oxide and grapheme oxide with aid of chitosan was carried out. Several characterizations were examined by SEM (scanning electron microscopy), XRD (X-ray diffraction), ultraviolet-visible spectroscopy (UV-Vis), and Fourier-Transform Infrared (FTIR) spectra. Photocatalytic tests were examined by selecting typical organic pollutants. The photoconductivity response of nanocomposite film to visible light and 808 nm laser with low-power were investigated based on interdigital electrodes of Au on flexible PET (polyethylene terephthalate) film substrate. The results indicated that the organic-inorganic film not only had wide visible light and NIR (near-infrared) responses, but also had good removal ability to organic pollutants. The nanocomposite film also exhibited clearly photo-response to visible light and 808 nm laser. It would be potential good applications in self-cleaning film, nanocoating, et al.

Surface Modification of Low-Dimensional Heterostructured Functional Materials with Dendrimers and their Properties of Organic-Inorganic Nanocomposites

Low-dimensional heterostructured functional materials have been widely applied in new energy materials, catalysts, et al. However, to enhance photo-response in visible light and the biocompatibility improvement are still the great challenges faced. And the dendrimers act good roles in transferring the drug and gene, and has good biocompatibility. Self-assembly on the surface of low-dimensional heterostructured functional materials with dendrimers holding-COOH groups was carried out in this paper. The characterizations of the materials were examined by SEM (scanning electron microscopy), XRD (X-ray diffraction), the Fourier-Transform Infrared (FTIR) spectra, ultraviolet-visible spectroscopy (UV-Vis) and so on. The photoconductivity response to visible light and 808 nm laser with low-power were studied based on interdigital electrodes of Au on flexible PET (polyethylene terephthalate) film substrate. The results indicated that ZnO/CuS modified with dendrimers showed good photo-response to visible light and 808 nm laser, the photo-response properties enhanced greatly by adding some small amount of grapheme oxide. Photocatalytic efficiency was examined by selecting typical organic pollutants, some good results were obtained. The external stimuli driven nanorobots for removal the organic pollutants or toxins in the living body have been developed.

Charge Behavior of Low-Dimensional V2O5/Graphene Nanoribbons Oxides Nanocomposites under Irradiation of Visible Light and its Application

Due to its outstanding photo-catalysis properties, low-dimensional V2O5 has many important applications in lithium ion batteries, supercapacitors, electrochromic devices, photocatalysts, sensors, et al. As good photocatalysts for organic pollutants, some key issues of photocatalysts are charge generation, separation, transfer of nanocomposites under irradiation of visible light. To improve their important properties and pave the effective conductive channels for charge transfer and separation, low-dimensional V2O5/graphene nanoribbons nanocomposites were prepared. The emphasis is put on adsorption response to VOC of nanocomposite based on the QCM (quartz crystal microbalance) device. In order to investigate the mechanism of charge-generated by visible light, the photoconductivity response to visible light and 808 nm laser with low-power were studied based on interdigital electrodes of Au on flexible PET (polyethylene terephthalate) film substrate. Some good results were obtained. This illustrates that this nanocomposite can easily produce the charge-generate with visible light and 808 nm laser with low-power, avoiding the recombination of charge-generate by light. It would be good applications in remove the organic pollutants with photocatalysis effects.