Y. Senba

Monochromator for a soft X-ray photochemistry beamline BL27SU of SPring-8

A high-resolution monochromator with varied line space plane gratings (VLSG) and spherical focusing mirrors was installed in one of three branches of BL27SU in SPring-8. The performance of the monochromator was roughly evaluated from the photo ion yield of nitrogen molecule. Furthermore, the kinetic energy of the photoelectron from Xe 5p3/2 orbit was also measured at the same photon energy with the N2 to avoid the influence of natural width. The resolving power over 104 has been confirmed at the N K-edge.

Ultrahigh resolution soft x-ray emission spectrometer at BL07LSU in SPring-8

An extremely high resolution flat field type slit less soft x-ray emission spectrometer has been designed and constructed for the long undulator beamline BL07LSU in SPring-8. By optimizing the ruling parameters of two cylindrical gratings, a high energy resolution ΔE < 100 meV and/or an E∕ΔE ~ 10 000 are expected for the energy range of 350 eV - 750 eV taking into account the broadening by the spatial resolution (25 μm) of a CCD detector. A coma-free operation mode proposed by Strocov et al., is also applied to eliminate both defocus and coma aberrations. The spectrometer demonstrated experimentally that E/ΔE = 10 050 and 8046 for N 1s (402.1 eV) and Mn 2p (641.8 eV) edges, respectively.

Revisiting the valence-band and core-level photoemission spectra of NiO.

We have reexamined the valence-band (VB) and core-level electronic structure of NiO by means of hard and soft x-ray photoemission spectroscopies. The spectral weight of the lowest energy state was found to be enhanced in the bulk sensitive Ni 2p core-level spectrum. A configuration-interaction model including a bound state screening has shown agreement with the core-level spectrum and off- and on-resonance VB spectra. These results identify the lowest energy states in the core-level and VB spectra as the Zhang-Rice (ZR) doublet bound states, consistent with the spin-fermion model and recent ab initio calculations within dynamical mean-field theory. The results indicate that the ZR character first ionization (the lowest hole-addition) states are responsible for transport properties in NiO and doped NiO.

Photoemission evidence for a Mott-Hubbard metal-insulator transition in VO2

The temperature (T) dependent metal-insulator transition (MIT) in VO2 is investigated using bulk sensitive hard x-ray (� 8 keV) valence band, core level, and V 2p-3d resonant photoemission spectroscopy (PES). The valence band and core level spectra are compared with full-multiplet cluster model calculations including a coherent screening channel. Across the MIT, V 3d spectral weight transfer from the coherent (d 1 C final) states at Fermi level to the incoherent (d 0 +d 1 L final) states, corresponding to the lower Hubbard band, lead to gap-formation. The spectral shape changes in V 1s and V 2p core levels as well as the valence band are nicely reproduced from a cluster model calculations, providing electronic structure parameters. Resonant-PES finds that the d 1 L states resonate across the V 2p-3d threshold in addition to the d 0 and d 1 C states. The results support a Mott-Hubbard transition picture for the first order MIT in VO2. PACS numbers: 79.60.-i, 71.30.+h VO2, a d 1 electron system, exhibits a sharp first-order metal-insulator transition (MIT) as a function of temperature (T), at TMI = 340 K. 1 The high-T metal phase has a rutile (R) structure, while the low-T insulating phase has a monoclinic (M1) structure with zig-zag type pairing of V atoms along the c-axis. 2 Magnetically, the metallic R phase shows enhanced susceptibility (�) with an effective mass m ∗ /m � 6, while the insulating M1 phase is non

Performance of a Highly Stabilized and High-resolution Beamline BL17SU for Advanced Soft X-ray Spectroscopy at SPring-8

A new soft x‐ray beamline BL17SU (RIKEN) has been constructed at SPring‐8. The beamline consists of two branches with each varied‐line‐spacing‐plane‐grating‐monochromator. Both monochromators perform high energy resolution (E/ΔE > 10,000) between 0.2 and 1 keV. One of the monochromator achieves high energy stability of 10 meV over a period of half a day.

High performance slit-less spectrometer for soft x-ray emission spectroscopy

We have designed and constructed a new flat-field-type slit-less soft x-ray emission spectrometer that enables high detection efficiency and high energy resolution in the energy range of 250–1000eV. The energy resolution is optimized in the C 1s and O 1s regions, where the maximum energy resolution of 2500 (E∕ΔE) is expected using a focused beam whose spot size is 5μm full width at half maximum in the vertical direction. A distortion of the linear profile of the focused image on the charge-coupled device (CCD) detector is successfully removed by using a cylindrical grating. This enabled us to apply a super-resolution reconstruction technique to compensate for the lack of spatial resolution of the CCD detector.We have designed and constructed a new flat-field-type slit-less soft x-ray emission spectrometer that enables high detection efficiency and high energy resolution in the energy range of 250–1000eV. The energy resolution is optimized in the C 1s and O 1s regions, where the maximum energy resolution of 2500 (E∕ΔE) is expected using a focused beam whose spot size is 5μm full width at half maximum in the vertical direction. A distortion of the linear profile of the focused image on the charge-coupled device (CCD) detector is successfully removed by using a cylindrical grating. This enabled us to apply a super-resolution reconstruction technique to compensate for the lack of spatial resolution of the CCD detector.

New soft X-ray beamline BL07LSU at SPring-8

The design and performance of a new soft X-ray beamline BL07LSU at SPring-8 are described. The combination of a novel segmented cross undulator and beamline monochromator has achieved high energy resolution (E/ΔE > 10000) and high photon flux [>1012 photons s−1 (0.01% bandwidth)−1] in the photon energy range 250–2000 eV with fully controllable polarization.

Coherent and Incoherent Excitations of Electron-Doped SrTiO3

Resonant photoemission at the Ti 2p and O 1s edges on a Nb-doped SrTiO(3) thin film revealed that the coherent state (CS) at the Fermi level (E(F)) had a mainly Ti 3d character whereas the incoherent in-gap state (IGS) positioned approximately 1.5 eV below E(F) had a mixed character of Ti 3d and O 2p states. This indicates that the IGS is formed by a spectral-weight transfer from the CS and subsequent spectral-weight redistribution through d-p hybridization. We discuss the evolution of the excitation spectrum with 3d band filling and rationalize the IGS through a mechanism similar to that proposed by Haldane and Anderson.

Scanning photoelectron microscope for nanoscale three-dimensional spatial-resolved electron spectroscopy for chemical analysis.

In order to achieve nondestructive observation of the three-dimensional spatially resolved electronic structure of solids, we have developed a scanning photoelectron microscope system with the capability of depth profiling in electron spectroscopy for chemical analysis (ESCA). We call this system 3D nano-ESCA. For focusing the x-ray, a Fresnel zone plate with a diameter of 200 μm and an outermost zone width of 35 nm is used. In order to obtain the angular dependence of the photoelectron spectra for the depth-profile analysis without rotating the sample, we adopted a modified VG Scienta R3000 analyzer with an acceptance angle of 60° as a high-resolution angle-resolved electron spectrometer. The system has been installed at the University-of-Tokyo Materials Science Outstation beamline, BL07LSU, at SPring-8. From the results of the line-scan profiles of the poly-Si/high-k gate patterns, we achieved a total spatial resolution better than 70 nm. The capability of our system for pinpoint depth-profile analysis and high-resolution chemical state analysis is demonstrated.

Recoil Effect of Photoelectrons in the Fermi Edge of Simple Metals

High energy resolution photoelectron spectroscopy of conduction electrons in the vicinity of the Fermi edge in Al and Au at excitation energies of 880 and 7940 eV was carried out using synchrotron radiation. For the excitation energy of 7940 eV, the observed Fermi energy of Al shows a remarkable shift to higher binding energy as compared with that of Au, with accompanying broadening. This is due to the recoil effect of the emitted photoelectrons. The observed spectra are well reproduced by a simple model of Bloch electrons based on the isotropic Debye model.