Yahua Liu

Pancake bouncing on superhydrophobic surfaces

Engineering surfaces that promote rapid drop detachment1,2 is of importance to a wide range of applications including anti-icing3–5, dropwise condensation6, and self-cleaning7–9. Here we show how superhydrophobic surfaces patterned with lattices of submillimetre-scale posts decorated with nano-textures can generate a counter-intuitive bouncing regime: drops spread on impact and then leave the surface in a flattened, pancake shape without retracting. This allows for a four-fold reduction in contact time compared to conventional complete rebound1,10–13. We demonstrate that the pancake bouncing results from the rectification of capillary energy stored in the penetrated liquid into upward motion adequate to lift the drop. Moreover, the timescales for lateral drop spreading over the surface and for vertical motion must be comparable. In particular, by designing surfaces with tapered micro/nanotextures which behave as harmonic springs, the timescales become independent of the impact velocity, allowing the occurrence of pancake bouncing and rapid drop detachment over a wide range of impact velocities.

Bioinspired interfacial materials with enhanced drop mobility: From fundamentals to multifunctional applications

The development of bioinspired interfacial materials with enhanced drop mobility that mimic the innate functionalities of nature will have a significant impact on the energy, environment and global healthcare. Despite extensive progress, state of the art interfacial materials have not reached the level of maturity sufficient for industrial applications in terms of scalability, stability, and reliability. These are complicated by their operating environments and lack of facile approaches to control the local structural texture and chemical composition at multiple length scales. The recent advances in the fundamental understanding are reviewed, as well as practical applications of bioinspired interfacial materials, with an emphasis on the drop bouncing and coalescence-induced jumping behaviors. Perspectives on how to catalyze new discoveries and to foster technological adoption to move this exciting area forward are also suggested.

Symmetry breaking in drop bouncing on curved surfaces

The impact of liquid drops on solid surfaces is ubiquitous in nature, and of practical importance in many industrial processes. A drop hitting a flat surface retains a circular symmetry throughout the impact process. Here we show that a drop impinging on Echevaria leaves exhibits asymmetric bouncing dynamics with distinct spreading and retraction along two perpendicular directions. This is a direct consequence of the cylindrical leaves that have a convex/concave architecture of size comparable to the drop. Systematic experimental investigations on mimetic surfaces and lattice Boltzmann simulations reveal that this novel phenomenon results from an asymmetric momentum and mass distribution that allows for preferential fluid pumping around the drop rim. The asymmetry of the bouncing leads to ∼40% reduction in contact time.

Superhydrophobic-like tunable droplet bouncing on slippery liquid interfaces

Droplet impacting on solid or liquid interfaces is a ubiquitous phenomenon in nature. Although complete rebound of droplets is widely observed on superhydrophobic surfaces, the bouncing of droplets on liquid is usually vulnerable due to easy collapse of entrapped air pocket underneath the impinging droplet. Here, we report a superhydrophobic-like bouncing regime on thin liquid film, characterized by the contact time, the spreading dynamics, and the restitution coefficient independent of underlying liquid film. Through experimental exploration and theoretical analysis, we demonstrate that the manifestation of such a superhydrophobic-like bouncing necessitates an intricate interplay between the Weber number, the thickness and viscosity of liquid film. Such insights allow us to tune the droplet behaviours in a well-controlled fashion. We anticipate that the combination of superhydrophobic-like bouncing with inherent advantages of emerging slippery liquid interfaces will find a wide range of applications.

Electrowetting on liquid-infused film (EWOLF): Complete reversibility and controlled droplet oscillation suppression for fast optical imaging

Electrowetting on dielectric (EWOD) has emerged as a powerful tool to electrically manipulate tiny individual droplets in a controlled manner. Despite tremendous progress over the past two decades, current EWOD operating in ambient conditions has limited functionalities posing challenges for its applications, including electronic display, energy generation, and microfluidic systems. Here, we demonstrate a new paradigm of electrowetting on liquid-infused film (EWOLF) that allows for complete reversibility and tunable transient response simultaneously. We determine that these functionalities in EWOLF are attributed to its novel configuration, which allows for the formation of viscous liquid-liquid interfaces as well as additional wetting ridges, thereby suppressing the contact line pinning and severe droplet oscillation encountered in the conventional EWOD. Finally, by harnessing these functionalities demonstrated in EWOLF, we also explore its application as liquid lens for fast optical focusing.

Controlling drop bouncing using surfaces with gradient features

Drop hitting on superhydrophobic surfaces usually undergoes spreading and retraction stages before its complete rebound and there exists a minimum amount of time for the spreading and retraction processes. Impressively, it was recently shown that the so-called contact time can be significantly reduced by engineering surfaces with millimeter-scale tapered post arrays that allow the impinging drop to leave the surfaces in a pancake shape at the end of lateral spreading (pancake bouncing). Despite exciting progress, it remains elusive to rationally control the contact time and quantitatively predict the critical Weber number for the occurrence of pancake bouncing. Here, we experimentally demonstrated that the drop bouncing is intricately modulated by the surface morphology. Under the same centre-to-centre post spacing, surfaces with a larger apex angle could give rise to more robust pancake bouncing, which is characterized by significant contact time reduction, smaller critical Weber number, and wider Weber number range. We also developed simple harmonic spring models and theoretically revealed the dependence of timescales associated with the impinging drop and the critical Weber number for pancake bouncing on the surface morphology. The insights learned from this work will allow us to rationally design various surfaces for many practical applications.

Superhydrophobic porous networks for enhanced droplet shedding.

Recent research has shown that the use of submillimeter-scale tapered post arrays could generate the so-called pancake bouncing, which is characterized by the fast shedding of impinging drops from the surface in a pancake shape without undergoing the retraction stage as observed on conventional superhydrophobic surfaces. Despite this exciting discovery, the fabrication of this unique superhydrophobic surface with tapered post arrays involves complex processes, hindering its wide applications in practical sectors. Here, we report on the facile strategy to prepare a new hierarchical multilayered superhydrophobic surface directly from commercially available porous matrix that allows for efficient drop shedding. Further study shows that the enhanced drop mobility observed on such a surface is attributed to the synergistic cooperation of hierarchical structures endowing an adequate energy storage and effective energy release. The facile fabrication of superhydrophobic surface with enhanced drop mobility may find many practical applications including anti-icing, dropwise condensation and self-cleaning.

Bioinspired Materials: Bioinspired Interfacial Materials with Enhanced Drop Mobility: From Fundamentals to Multifunctional Applications (Small 14/2016).

The development of bioinspired interfacial materials with enhanced drop mobility that mimic the innate functionalities of nature will have significant impact on energy, environment, and global healthcare. On page 1825, Z. Wang and co-workers highlight recent advances in the fundamental understanding, as well as practical applications of bio-inspired interfacial materials, with an emphasis on drop bouncing and jumping behaviors.

Variation of the Contact Time of Droplets Bouncing on Cylindrical Ridges with Ridge Size

Reducing the contact time between bouncing droplets and an underlying solid surface is relevant to a broad range of industrial applications, such as anti-icing and self-cleaning. Previous work has found that placing cylindrical obstacles on the substrate leads to a reduction in contact time. For obstacles large compared to the drop, this is a result of hydrodynamic coupling between the azimuthal and axial spreading directions. For obstacles small compared to the drop, the reduction in contact time is interpreted as being due to fast retraction along the cylindrical ridge, followed by drop breakup. Here we use simulations to discuss in greater detail the effect of varying the obstacle size on the dynamics of the drop bouncing. We investigate the crossover between the two regimes and explain why the contact time is minimized when the radii of the drop and the cylindrical obstacle are comparable.