Yoshimune Nonomura

Phase inversion of the Pickering emulsions stabilized by plate-shaped clay particles.

We investigated the phase inversion of Pickering emulsions stabilized by plate-shaped clay particles. Addition of water induced a phase inversion from a water-in-oil (W/O) emulsion to an oil-in-water (O/W) emulsion when the amount of the oil phase exceeded a limiting amount of oil absorption to solid particles. On the other hand, a phase inversion from a powdery state to an O/W emulsion state through an oil-separated state is observed when the amount of an oil phase is less than the limiting amount of the oil absorption. Interestingly, the oil separated is re-dispersed as emulsion droplets into the O/W emulsion phase. This type of phase inversion, which is a feature of the Pickering emulsions stabilized by the clay particles, is caused by a change in the aggregate structures of particles.

Tactile Impression and Friction of Water on Human Skin

Water has a unique touch as well as characteristic physical properties. However, nobody knows the real identity of its touch. Here, we show that water creates a stick-slip feel when a small amount is rubbed using fingertip on an artificial skin that mimics the structure of human skin. The results of frictional analyses predict that this stick-slip feel is caused by a drastic change in frictional resistance. The present result is valuable for biologists and robot engineers as well as cognitive scientists and tribologists, because it is a new example of stick-slip phenomena on biological surfaces. The tactile texture of this most familiar material could also be applied to consumer products or virtual reality systems.

Theoretical Explanation of the Lotus Effect: Superhydrophobic Property Changes by Removal of Nanostructures from the Surface of a Lotus Leaf.

Theoretical study is presented on the wetting behaviors of water droplets over a lotus leaf. Experimental results are interpreted to clarify the trade-offs among the potential energy change, the local pinning energy, and the adhesion energy. The theoretical parameters, calculated from the experimental results, are used to qualitatively explain the relations among surface fractal dimension, surface morphology, and dynamic wetting behaviors. The surface of a lotus leaf, which shows the superhydrophobic lotus effect, was dipped in ethanol to remove the plant waxes. As a result, the lotus effect is lost. The contact angle of a water drop decreased dramatically from 161° of the original surface to 122°. The water droplet was pinned on the surface. From the fractal analysis, the fractal region of the original surface was divided into two regions: a smaller-sized roughness region of 0.3-1.7 μm with D of 1.48 and a region of 1.7-19 μm with D of 1.36. By dipping the leaf in ethanol, the former fractal region, characterized by wax tubes, was lost, and only the latter large fractal region remained. The lotus effect is attributed to a surface structure that is covered with needle-shaped wax tubes, and the remaining surface allows invasion of the water droplet and enlarges the interaction with water.

Theoretical Consideration of Wetting on a Cylindrical Pillar Defect: Pinning Energy and Penetrating Phenomena

Wetting on a cylindrical pillar defect is discussed in terms of the free-energy difference ΔG. Wetting is divided into wetting on a flat surface, a pinning effect at the apex of the defect, and wetting on a pillar wall. First, we confirmed that ΔG between before and after ideal wetting on a flat surface can be derived as a function of the contact angle θ in which the free-energy minimum is obtained as the equilibrium contact angle θ(eq) described by Youngs and Wenzels laws. Second, the pinning effect at the apex in the cross section of the pillar defect is discussed in ΔG, where the pinning effect is shown to originate from the energy barrier by an increase in the air-liquid interfacial area of a pinned droplet induced by deformation. Next, the ΔG profiles of wetting on the pillar wall are drawn based on the theory of Carroll (Carroll, B. J. J. Colloid Interface Sci.1976, 57, 488-495) to better understand the ΔG profile during penetration. Differences in the manner of wetting between the wetting state on a flat surface and the pillar wall are reflected in ΔG. Finally, penetration of a droplet into a pillar defect is comprehensively discussed on the basis of wetting on a flat surface and a pillar wall. If we consider a simple manner of penetration, another type of energy barrier resulting from an anomalous deformation of the air-liquid interface of the penetrating droplet can be theoretically suggested. Consequently, two types of energy barrier are found. These energy barriers should play a significant role in the hysteresis of wetting, the liquid-repellent Cassie-Baxter state (CB), and the CB-Wenzel wetting transition on a microtextured surface.

Fractal Surfaces of Molecular Crystals Mimicking Lotus Leaf with Phototunable Double Roughness Structures

Double roughness structure, the origin of the lotus effect of natural lotus leaf, was successfully reproduced on a diarylethene microcrystalline surface. Static superwater-repellency and dynamic water-drop-bouncing were observed on the surface, in the manner of natural lotus leaves. Double roughness structure was essential for water-drop-bouncing. This ability was not observed on a single roughness microcrystalline surface showing the lotus effect of the same diarylethene derivative. The double roughness structure was reversibly controlled by alternating irradiation with UV and visible light.

How do we recognize water and oil through our tactile sense

We can distinguish water and oil through our sense of feel, because the frictional properties of a water film are characteristic. However, we found that it was difficult to distinguish water and silicone oil on a glass substrate only by its feel. Friction evaluation showed that we recognize the liquid as water when the frictional resistance is large and changeable. On a glass substrate, water and silicone oil were not distinguishable, since both had a large frictional resistance. Statistical analysis suggested the contribution of the wettability of solid substrates to their tactile feel. This finding shows that we distinguish water from oil based on the significant friction properties; it is applicable to virtual reality systems, as well as cosmetics, food, and textiles.

Anomalous Spreading with Marangoni Flow on Agar Gel Surfaces

We have experimentally observed anomalous spreading of aqueous alcohol solutions on flat and rough fractal agar gel surfaces. On flat agar gel surfaces, extremely fast spreading [θ(D)(t) ∝ t(-0.92)] that differs from Tanners law [θ(D)(t) ∝ t(-0.3)] was observed when the liquid contained over 9 wt % of 1-propanol in which strong Marangoni flow was observed as a fluctuation on the liquid surface. However, on fractal gel surfaces, different spreading dynamics [θ(D)(t) ∝ t(-0.58)] were observed, although Marangoni flow still occurred. We found the surface-dependent spreading can be discussed in terms of competition between Marangoni flow and the pinning effect due to surface roughness.

How to identify water from thickener aqueous solutions by touch

Water detection is one of the most crucial psychological processes for many animals. However, nobody knows the perception mechanism of water through our tactile sense. In the present study, we found that a characteristic frictional stimulus with large acceleration is one of the cues to differentiate water from water contaminated with thickener. When subjects applied small amounts of water to a glass plate, strong stick-slip phenomena with a friction force of 0.46 ± 0.30 N and a vertical force of 0.57 ± 0.36 N were observed at the skin surface, as shown in previous studies. Surprisingly, periodic shears with acceleration seven times greater than gravitational acceleration occurred during the application process. Finite-element analyses predicted that these strong stimuli could activate tactile receptors: Meissners corpuscle and Pacinians. When such stimuli were applied to the fingertips by an ultrasonic vibrator, a water-like tactile texture was perceived by some subjects, even though no liquid was present between the fingertip and the vibrator surface. These findings could potentially be applied in the following areas: materials science, information technology, medical treatment and entertainment.

Non-Engineered Nanoparticles of C 60

We discovered that rubbing bulk solids of C60 between fingertips generates nanoparticles including the ones smaller than 20 nm. Considering the difficulties usually associated with nanoparticle production by pulverisation, formation of nanoparticles by such a mundane method is unprecedented and noteworthy. We also found that nanoparticles of C60 could be generated from bulk solids incidentally without deliberate engineering of any sort. Our findings imply that there exist highly unusual human exposure routes to nanoparticles of C60, and elucidating formation mechanisms of nanoparticles is crucial in assessing their environmental impacts.

How do we recognize biological materials by touch

Biological materials are often used as industrial sources; however, the features of their tactile texture have not been examined. Here, we show that the features of biological materials are warm, silky, and non-slippery sensations, which are governed by thermal conductivity, surface energy, and surface roughness. Interestingly, surface roughness is the most important factor in determining these three tactile sensations. This finding is valuable for developing virtual reality systems and humanoids as well as for understanding the cognitive mechanism of biological materials.